Method for manufacturing of slurry for production of battery film
The present invention relates to a method for manufacturing slurry for coating of electrodes for use in lithium ion batteries, wherein the method comprises mixing active materials with a binder into a binder solution, and adding an organic carbonate to the binder solution to generate the slurry. The present invention also relates to a method for manufacturing electrodes for a lithium battery cell, wherein the method comprises mixing active materials with a binder into a binder solution, adding an organic carbonate to the binder solution to generate slurry, wherein the above adding step is carried out at temperature above melting temperature of the organic carbonate, coating electrode material with the slurry, drying the coating on the electrode material by drying the organic carbonate, and surface treatment of the slurry so that the electrode is prepared for use in a lithium ion battery cell. Further, the invention also relates to a method for manufacturing a lithium ion battery cell.
1. A method for the manufacturing of an electrode for a lithium battery cell, wherein the method comprises the steps of:
(a) mixing an active material with a binder to obtain a mixture, wherein the active material is selected from a group consisting of LiCoO 2 , LiFePO 4 , LiMn 2 O 4 , LiNiO 2 , Li 2 FePO 4 F, LiCo 1/3 Ni 1/3 Mn 1/3 O 2 , Li(Li a Ni x Mn y Co z ), LiC 6 , Li 4 Ti 5 O 12 , Si(Li 4,4 Si) and Ge(Li 4,4 Ge);
(b) adding an organic carbonate to the mixture to generate a slurry, wherein step b) is carried out at a temperature above the melting temperature of the organic carbonate and wherein the slurry does not contain a solvent other than the organic carbonate;
(c) coating an electrode material with the slurry;
(d) drying the coating on the electrode material by drying the organic carbonate; and
(e) treating the surface of the slurry so that the electrode is prepared for use in a lithium battery cell;
wherein step (d) comprises a parallel recycling step wherein the organic carbonate is collected for re-use.
2. The method as claimed in claim 1 , wherein the collected organic carbonate is condensed, filtered and cleaned before re-use.
3. The method as claimed in claim 1 , wherein step (e) comprises one or several sub-steps of:
(i) rolling the electrode material;
(ii) baking the electrode material; and
(iii) finishing the electrode material for use in the lithium battery cell.
4. The method as claimed in claim 1 , wherein the binder is polyvinylidene fluoride.
5. The method as claimed in claim 1 , wherein the organic carbonate is selected from a group consisting of ethylene carbonate, diethyl carbonate and dimethyl carbonate.
6. The method of claim 1 , wherein the electrode is a cathode and wherein the active material is selected from the group consisting of LiCoO 2 , LiFePO 4 , LiMn 2 O 4 , LiNiO 2 , Li 2 FePO 4 F, LiCo 1/3 Ni 1/3 Mn 1/3 O 2 and Li(Li a Ni x Mn y Co z ).
7. The method of claim 1 , wherein the electrode is an anode and wherein the active material is selected from the group consisting of LiC 6 , Li 4 Ti 5 O 12 , Si(Li 4,4 Si) and Ge(Li 4,4 Ge).
8. A method for manufacturing a lithium ion battery cell, wherein the method comprises the steps of:
(a) manufacturing at least two electrodes by the method as claimed in claim 4 , wherein one electrode is a cathode and one electrode is an anode,
wherein the cathode comprises an active cathode material selected from a group consisting of LiCoO 2 , LiFePO 4 , LiMn 2 O 4 , LiNiO 2 , Li 2 FePO 4 F, LiCo 1/3 Ni 1/3 Mn 1/3 O 2 and Li(Li a Ni x Mn y Co z ), and
wherein the anode comprises an active anode material selected from a group consisting of LiC 6 , Li 4 Ti 5 O 12 , Si(Li 4,4 Si) and Ge(Li 4,4 Ge);
(b) arranging the cathode and the anode in layers with lithium ion permeable membranes in between;
(c) arranging the cathode, the anode and the lithium ion permeable membranes in a house with openings; and
(d) filling the house with an electrolyte comprising lithium containing salts and an organic carbonate.
9. The method of claim 8 , wherein step (b) further comprises arranging more than one cathode and more than one anode in layers with lithium ion permeable membranes in between and step (c) further comprises arranging the cathodes, the anodes, and the lithium ion permeable membranes in a house with openings.