Black silane primer for improving the adhesion of adhesive tapes to glass surfaces
View Patent ↗The invention relates to a primer, comprising a mixture dissolved or dispersed in one or more solvents, the mixture composed of a copolymer obtained through copolymerization, preferably free-radical copolymerization, of vinylcaprolactam and/or vinylpyrrolidone, and one or more of the following monomers: a) an acrylic acid ester of a linear primary alcohol containing 2 to 10 carbon atoms in the alkyl group of the alcohol, b) an acrylic acid ester of a branched, non-cyclic alcohol having 4 to 12 carbon atoms in the alkyl group of the alcohol, and c) acrylic acid; one or more organofunctional silanes; a dye or a pigment based on a metal complex or a metal oxide, wherein the metal oxide is of a spinel-type. Such primer provide reliable and excellent adhesion between pressure-sensitive adhesive tapes and hydrophilic surfaces, in particular glass, and ensures at the same time a good coloration of the primer, thereby producing an opaque primer layer.
1. Primer, comprising a mixture dissolved or dispersed in one or more solvents, the mixture comprising:
a copolymer obtained through copolymerization of vinylcaprolactam and/or vinylpyrrolidone monomers, and one or more of the following monomers:
a) an acrylic acid ester of a linear primary alcohol containing 2 to 10 carbon atoms in the alkyl group of the alcohol,
b) an acrylic acid ester of a branched, non-cyclic alcohol having 4 to 12 carbon atoms in the alkyl group of the alcohol, and
c) acrylic acid,
the mixture further comprising one or more organofunctional silanes, and,
a dye or a pigment which is black and which is selected from the group consisting of a copper chromite black spinel having the CAS No. 68186-91-4 and a chromium complex dye having the CAS-No. 117527-94-3.
2. Primer according to claim 1 wherein the copolymer is a pressure-sensitive adhesive.
3. Primer according to claim 1 wherein the copolymer further contains d) one or more additional copolymerizable monomers.
4. Primer according to claim 1 wherein the copolymer contains a maximum of 50 weight-percent of vinylcaprolactam and/or vinylpyrrolidone monomers based on the sum of all monomers of the copolymer.
5. Primer according to claim 1 wherein the copolymer contains at least 10 weight-percent of vinylcaprolactam and/or vinylpyrrolidone monomers based on the sum of all monomers of the copolymer.
6. Primer according to claim 1 wherein the copolymer contains a maximum of 20 weight-percent of acrylic acid monomer based on the sum of all monomers of the copolymer.
7. Primer according to claim 1 wherein one of the monomers is butyl acrylate.
8. Primer according to claim 1 wherein the one or more organofunctional silanes is glycidoxy-functional or amino-functional or vinyl-functional.
9. Primer according to 1 wherein the one or more solvents is isopropanol, another alcohol, or solvents contain isopropanol or another alcohol.
10. Primer according to claim 1 wherein the concentration of the copolymer of the mixture dissolved or dispersed in the one or more solvents is higher than the concentration of the one or more organofunctional silanes.
11. Primer according to claim 1 wherein the concentration of the copolymer of the mixture dissolved or dispersed in the one or more solvents is between and including 1.0 weight-percent and including 30.0 weight-percent.
12. Primer according to claim 1 wherein the concentration of the dye or pigment of the mixture dissolved or dispersed in the one or more solvents is higher than the concentration of the one or more organofunctional silanes.
13. Primer according to claim 4 wherein the copolymer contains a maximum of 40 weight-percent of vinylcaprolactam and/or vinylpyrrolidone monomers based on the sum of all monomers of the copolymer.
14. Primer according to claim 6 wherein the copolymer contains a maximum of 10 weight-percent of acrylic acid monomer based on the sum of all monomers of the copolymer.
15. Primer according to claim 14 wherein the copolymer contains 0 weight-percent of acrylic acid monomer based on the sum of all monomers of the copolymer.
16. Primer according to claim 1 , wherein the copolymer is the sole copolymer present in the mixture.
17. A method of preparing an adhesion-promoting material comprising the step of:
including the primer according to claim 1 within the material.