Retardation compensators of negative C-type for liquid crystal display
Disclosed is a negative C-type retardation compensator for a liquid crystal display. The negative C-type retardation compensator for the liquid crystal display includes polyarlate having a thio group or a sulfur oxide group in a polymer main chain thereof. Accordingly, the retardation compensator has an absolute value of negative retardation that is larger in a thickness direction that a retardation compensator which includes polyarylate having no thio group or sulfur oxide group in a polymer main chain thereof even though the retardation compensator having the thio group or sulfur oxide group and the retardation compensator having no thio group or sulfur oxide group are the same as each other in thickness. Thereby, the negative C-type retardation compensator for liquid crystal displays is capable of being desirably applied to the liquid crystal displays.
1. A method of producing a negative C-type retardation compensator for a liquid crystal display, comprising the steps of:
1) preparing a transparent base layer; and
2) forming a polyarylate coating layer by coating a polyarylate solution having a thio group or a sulfur oxide group in a polymer main chain thereof on the transparent base layer of step 1,
wherein the polyarylate which has the thio group or the sulfur oxide group in the polymer main chain of step 2 is represented by Formula 1;
wherein,
a, b, c, and d are each independently an integer of 0, or 1 to 4,
m and n are molar fractions, m+n=1, 0≦m≦1, and 0.001≦n≦0.4,
R 1 and R 2 are each independently a halogen, a nitrile group, a C 1 to C 12 alkoxy group, a C 6 to C 12 arylalkyl group, a C 6 to C 12 aryl group, or a C 1 to C 12 acyl group,
R 3 and R 4 are each independently a halogen, a nitrile group, a C 1 to C 12 alkyl group, a C 1 to C 12 alkoxy group, a C 6 to C 12 arylalkyl group, a C 6 to C 12 aryl group, or a C 1 to C 12 acyl group,
W 1 is a direct bond, a C 1 to C 30 alkylidene group, a C 2 to C 30 alkylene group, a C 3 to C 30 cycloalkylidene group, a C 3 to C 30 cycloalkylene group, a C 2 to C 30 phenyl-substituted alkylene group, a carbonyl group, NR, PO 2 , or an oxygen, wherein R is a hydrogen, a C 1 to C 12 alkyl group, a C 6 to C 12 arylalkyl group, or a C 6 to C 12 aryl group, and
W 2 is a thio group or a sulfur oxide group.
2. The method according to claim 1 , wherein the transparent base layer of step 1 is reformed using a primer, a corona, plasma at a normal pressure, acid/base treatment, UV treatment, or reactive gas treatment.
3. The method according to claim 2 , wherein the primer is produced by dissolving an organic silane compound which is represented by Formula 2 in a solvent:
wherein,
r and s are integers of 0 to 4, and r+s=4,
R 7 is a C 1 to C 9 alkyl group having one or more selected from the group consisting of an amine group, a hydroxyl group, and a thiol group; a C 6 to C 12 arylalkyl group having one or more selected from the group consisting of an amine group, a hydroxyl group, and a thiol group; or a C 6 to C 12 aryl group having one or more selected from the group consisting of an amine group, a hydroxyl group, and a thiol group, and
R 8 is a C 1 to C 9 alkyl group, a C 6 to C 12 arylalkyl group, or a C 6 to C 12 aryl group.
4. The method according to claim 3 , wherein the organic silane compound which is represented by Formula 2 is one or more selected from the group consisting of 3-aminopropyl trimethoxy silane, 3-aminopropyl triethoxy silane, 3-thiopropyl trimethoxysilane, 3-thiopropyltriethoxy silane, 3-hydroxypropyltrimethoxysilane, and 3-hydroxypropyltriethoxysilane.
5. The method according to claim 1 , wherein the coating method in step 2 is selected from the group consisting of a spin coating process, a roll coating process, a flow coating process, a print process, a dip coat process, a gravure coating process, and a bar coating process.
6. The method according to claim 1 , wherein the polyarylate solution of step 2 further includes one or more additives of a UV stabilizer, a heat stabilizer, a plasticizer, an adhesion strength improving agent, and a filler.
7. The method according to claim 6 , wherein the adhesion strength improving agent is an organic silane compound represented by Formula 3:
wherein,
p and q are integers of 0 to 4, and p+q=4, and
R 5 and R 6 are each independently a C 1 to C 9 alkyl group, a C 6 to C 12 arylalkyl group, or a C 6 to C 12 aryl group.
8. The method according to claim 7 , wherein the organic silane compound represented by Formula 3 is one or more selected from the group consisting of methylpropyl trimethoxy silane, methyltriethoxy silane, ethyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-hydroxypropyltrimethoxysilane, and 3-hydroxypropyltriethoxysilane.
9. The method according to claim 1 , wherein the polyarylate coating layer of step 2 is additionally subjected to one or more treatments of hard coating treatment, reflection prevention treatment, and a predetermined treatment process to prevent sticking and to ensure desirable diffusion and anti-glare.
10. The method according to claim 1 , wherein a thickness of the polyarylate coating layer of step 2 is 0.1 to 100 on.
11. A negative C-type retardation compensator for a liquid crystal display, which is produced using the method of claim 1 and in which a retardation in a thickness direction is negative and an absolute value of the retardation is 10 nm or more.