Flame retardant polycarbonate compositions, methods of manufacture thereof and articles comprising the same
View Patent ↗Disclosed herein is a flame retardant composition comprising 20 to 80 weight percent of a polycarbonate; 1 to 20 weight percent of a laser activatable additive; the laser activatable additive being operative to plate the flame retardant composition upon being activated by a laser; and 1 to 20 weight percent of a phosphazene compound; where all weight percents are based on the total weight of the flame retardant composition. Disclosed herein too is a method comprising blending 20 to 80 weight percent of a polycarbonate; 1 to 20 weight percent of a laser activatable additive; the laser activatable additive being operative to plate the flame retardant composition upon being activated by a laser; and 1 to 20 weight percent of a phosphazene compound to produce a flame retardant composition; where all weight percents are based on the total weight of the flame retardant composition; and extruding the flame retardant composition.
1. A flame retardant composition comprising:
20 to 80 weight percent of a polycarbonate composition; where the polycarbonate composition is selected from the group consisting of a linear polycarbonate, a branched polycarbonate, a combination of a linear and a branched polycarbonate, a blend of two polycarbonate homopolymers; a copolyestercarbonate, and a polysiloxane-polycarbonate polymer;
1 to 20 weight percent of a laser activatable additive; the laser activatable additive being operative to plate the flame retardant composition upon being activated by a laser; where the laser direct structuring additive is a copper chromium oxide spinel, a copper salt, a copper hydroxide phosphate, a copper phosphate, a copper sulfate, a cuprous thiocyanate, a spinel based metal oxide, a copper chromium oxide, an organic metal complex, a palladium/palladium-containing heavy metal complex, a metal oxide, a metal oxide-coated filler, antimony doped tin oxide coated on mica, a zinc containing metal oxide, a tin containing metal oxide, a magnesium containing metal oxide, an aluminum containing metal oxide, a gold containing metal oxide, a silver containing metal oxide, or a combination comprising at least one of the foregoing laser direct structuring additives; and
3 to 20 weight percent of a phosphazene compound; where all weight percents are based on the total weight of the flame retardant composition, where the composition when molded displays a flame retardancy of V-0 at a sample thickness of 0.6 millimeters when tested per a UL-94 protocol.
2. The flame retardant composition of claim 1 , further comprising a mineral filler in an amount of 1 to 10 weight percent based on the total weight of the flame retardant composition.
3. The flame retardant composition of claim 1 , comprising 3 to 5 weight percent of the phosphazene compound.
4. The flame retardant composition of claim 1 , where the polycarbonate composition comprises a polycarbonate having a weight average molecular weight of 15,000 to 40,000 Daltons.
5. The flame retardant composition of claim 4 , where the polycarbonate composition comprises a blend of two polycarbonate homopolymers one of which has a higher molecular weight than the other.
6. The flame retardant composition of claim 1 , further comprising 1 to 15 wt % of a pigment.
7. The flame retardant polycarbonate composition of claim 1 , where the phosphazene compound has the structure of formula (23)
where in the formula (23), m represents an integer of 3 to 25, R 1 and R 2 are the same or different and are independently a hydrogen, a hydroxyl, a C 7-30 aryl group, a C 1-12 alkoxy, or a C 1-12 alkyl.
8. The flame retardant polycarbonate composition of claim 1 , where the phosphazene compound is hexaphenoxy cyclotriphosphazene, octaphenoxy cyclotetraphosphazene, decaphenoxy cyclopentaphosphazene, or a combination comprising at least one of the foregoing phosphazene compounds.
9. The flame retardant polycarbonate composition of claim 1 , where the phosphazene compound has the structure of formula (24) below:
where in the formula (24), X 1 represents a —N═P(OPh) 3 group or a —N═P(O)OPh group, Y 1 represents a —P(OPh) 4 group or a —P(O)(OPh) 2 group, Ph represents a phenyl group, n represents an integer from 3 to 10000, R 1 and R 2 are the same or different and are independently a hydrogen, a hydroxyl, a C 7-30 aryl, a C 1-12 alkoxy, or a C 1-12 alkyl.
10. The flame retardant polycarbonate composition of claim 1 , where the phosphazene compound is a crosslinked phenoxyphosphazene.
11. The flame retardant polycarbonate composition of claim 1 , where the phosphazene compound has a structure represented by the formula (26)
where R 1 to R 6 can be the same of different and can be an aryl group, an aralkyl group, a C 1-12 alkoxy, a C 1-12 alkyl, or a combination thereof.
12. The flame retardant polycarbonate composition of claim 1 , where the phosphazene compound has a structure represented by the formula (27)
13. The flame retardant polycarbonate composition of claim 1 , further comprising a glass fiber; where the glass fiber is a flat glass fiber.
14. The flame retardant polycarbonate composition of claim 2 , where the mineral filler is mica, talc, calcium carbonate, dolomite, wollastonite, barium sulfate, silica, kaolin, feldspar, or a combination comprising at least one of the foregoing mineral fillers.
15. The flame retardant polycarbonate composition of claim 1 , further comprising a flame retardant synergist; where the flame retardant synergist is talc having an average particle size of 1 to 3 micrometers.
16. The flame retardant polycarbonate composition of claim 1 , displaying an impact strength of greater than or equal to 900 joules per meter, when tested as per ASTM D 256 at 23° C.
17. A method comprising:
blending 20 to 80 weight percent of a polycarbonate; 1 to 20 weight percent of a laser activatable additive; the laser activatable additive being operative to plate the flame retardant composition upon being activated by a laser; where the laser direct structuring additive is a copper chromium oxide spinel, a copper salt, a copper hydroxide phosphate, a copper phosphate, a copper sulfate, a cuprous thiocyanate, a spinel based metal oxide, a copper chromium oxide, an organic metal complex, a palladium/palladium-containing heavy metal complex, a metal oxide, a metal oxide-coated filler, antimony doped tin oxide coated on mica, a zinc containing metal oxide, a tin containing metal oxide, a magnesium containing metal oxide, an aluminum containing metal oxide, a gold containing metal oxide, a silver containing metal oxide, or a combination comprising at least one of the foregoing laser direct structuring additives; and 3 to 20 weight percent of a phosphazene compound to produce a flame retardant composition; where all weight percents are based on the total weight of the flame retardant composition; and
extruding the flame retardant composition, where the composition displays a flame retardancy of V-0 at a sample thickness of 0.6 millimeters when tested per a UL-94 protocol.
18. The method of claim 17 , further comprising blending a mineral filler.
19. The method of claim 17 , further comprising molding the composition.
20. An article manufactured from the composition of claim 1 .