Filter media including polymer compositions and blends
Polymer compositions that may be used to form fibers for a fiber web are generally described. In some embodiments, certain properties of the polymer compositions (e.g., molecular weight distribution, melt flow index, melt elasticity, and/or melt toughness) may allow the formation of fiber webs having fine fibers and a relatively low amount of process defects. In some instances, these properties of the polymer composition may be achieved by combining two or more polymer components. Fiber webs formed using the polymer composition may have increased performance and/or better structural characteristics compared to fibers webs formed using a single polymer component.
1. A fiber web, comprising:
a plurality of fibers comprising a polypropylene composition comprising a first polypropylene component and a second polypropylene component, wherein the polypropylene composition has a M z of greater than or equal to about 100,000, a M n of less than or equal to about 55,000, a M z to M w ratio of greater than or equal to about 1.8 and less than about 3.2, and a melt flow index of greater than or equal to about 400 grams per 10 minutes.
2. A method, comprising:
providing a polypropylene composition comprising a first polypropylene component and a second polypropylene component, wherein the polypropylene composition has a Mz of greater than or equal to about 100,000, a Mn of less than or equal to about 55,000, a M z to M w ratio of greater than or equal to about 1.8 and less than about 3.2, and a melt flow index of greater than or equal to about 400 grams per 10 minutes; and
forming a plurality of fibers from the polypropylene composition.
3. The fiber web of claim 1 , wherein the polymer composition comprises a third polypropylene component.
4. The fiber web of claim 1 , wherein the first polypropylene component has a melt flow index of greater than or equal to about 300 g/10 minutes and less than 700 g/10 minutes.
5. The fiber web of claim 1 , wherein the second polymer component has a melt flow index of greater than or equal to about 800 g/10 minutes and less than 1,600 g/10 minutes.
6. The fiber web of claim 3 , wherein the third polymer component has a melt flow index of greater than or equal to about 1,300 g/10 minutes and less than 2,500 g/10 minutes.
7. The fiber web of claim 1 , wherein the polypropylene composition has a melt flow index of less than 1,500 g/10 minutes.
8. The fiber web of claim 1 , wherein the polypropylene composition has a M n of greater than or equal to about 25,000 g/mol.
9. The fiber web of claim 1 , wherein the polypropylene composition has a M z of greater than or equal to about 130,000 g/mol and less than about 300,000 g/mol.
10. The fiber web of claim 1 , wherein the polypropylene composition has a M w of greater than or equal to about 50,000 g/mol and less than about 125,000 g/mol.
11. The fiber web of claim 1 , wherein the polypropylene composition has a polydispersity index of greater than or equal to about 1.8 and less than about 4.0.
12. The fiber web of claim 1 , wherein the polypropylene composition has a Mz to Mw ratio of greater than or equal to about 1.9 and less than about 3.
13. The fiber web of claim 1 , wherein the average diameter of the plurality of fibers is less than or equal to about 1 micron.
14. The fiber web of claim 1 , wherein the fiber web has a surface density of particles formed of the polymeric material of less than about 1.0 particles/in 2 , wherein each of the particles has a largest cross-sectional dimension of about 1.0 mm or greater.
15. The fiber web of claim 1 , wherein the fiber web has a surface density of particles formed of the polymeric material of less than about 0.5 particles/in 2 , wherein each of the particles has a largest cross-sectional dimension of about 1.0 mm or greater.
16. The method of claim 2 , comprising pre-compounding the polypropylene composition.
17. The fiber web of claim 1 , wherein the fiber web is made via a meltblown process.
18. The fiber web of claim 1 , wherein the fiber web is made via a centrifugal spinning process.
19. An article, comprising:
a fiber web comprising a plurality of fibers comprising a polypropylene composition comprising a first polypropylene component and a second polypropylene component, wherein the polypropylene composition has a M z of greater than or equal to about 100,000, a M n of less than or equal to about 55,000, a M z to M w ratio of greater than or equal to about 1.9 and less than about 3, and a melt flow index of greater than or equal to about 400 grams per 10 minutes, and wherein the fiber web is attached to a substrate.
20. The article of claim 17 , wherein the substrate comprises glass fibers.
21. The article of claim 19 , wherein the substrate comprises cellulose fibers.
22. The article of claim 19 , wherein the substrate comprises synthetic fibers.
23. The fiber web of claim 1 , wherein the fiber web has a BET surface area of greater than or equal to 0.1 m 2 /g and less than or equal to about 6.0 m 2 /g.
24. The fiber web of claim 1 , wherein the fiber web has a BET surface area of greater than or equal to 1.5 m 2 /g and less than or equal to about 6.0 m 2 /g.
25. A filter element comprising a fiber web comprising a plurality of fibers comprising a polypropylene composition comprising a first polypropylene component and a second polypropylene component, wherein the polypropylene composition has a M z of greater than or equal to about 100,000, a M n of less than or equal to about 55,000, a M z to M w ratio of greater than or equal to about 1.9 and less than about 3, and a melt flow index of greater than or equal to about 400 grams per 10 minutes.
26. The fiber web of claim 1 , wherein each polypropylene component in the composition has a melt flow rate greater than about 25 grams per 10 minutes.