Flame retardant polycarbonate compositions, methods of manufacture thereof and articles comprising the same
View Patent ↗Disclosed herein is a flame retardant composition comprising a polycarbonate; 5 to 10 weight percent of a polysiloxane-polycarbonate copolymer; where the polysiloxane-polycarbonate copolymer comprises an amount of greater than 10 weigh percent of the polysiloxane and where the molecular weight of the polysiloxane-polycarbonate copolymer is greater than or equal to 25,000 grams per mole; 5 to 20 weight percent of a branched polycarbonate; 5 to 60 weight percent of a reinforcing filler; and 1 to 15 weight percent of a flame retarding compound. Disclosed herein too is a method comprising blending a polycarbonate; 5 to 10 weight percent of a polysiloxane-polycarbonate copolymer; 5 to 20 weight percent of a branched polycarbonate; 5 to 60 weight percent of a reinforcing filler; where the reinforcing filler is a glass fiber, a carbon fiber, a metal fiber, or a combination comprising at least one of the foregoing reinforcing fillers; and 1 to 15 weight percent of a flame retarding compound; and extruding the flame retardant composition.
1. A flame retardant composition comprising:
a polycarbonate;
5 to 10 weight percent of a polysiloxane-polycarbonate copolymer; where the polysiloxane-polycarbonate copolymer comprises an amount of greater than 10 weigh percent of the polysiloxane and where the weight average molecular weight of the polysiloxane-polycarbonate copolymer is greater than or equal to 25,000 grams per mole;
5 to 20 weight percent of a branched polycarbonate;
5 to 60 weight percent of a reinforcing filler; and
1 to 15 weight percent of a flame retardant compound; where all weight percents are based on the total weight the flame retardant composition; flame retardant composition has notched Izod impact strength of 100 to 140 Joules/meter.
2. The composition of claim 1 , where the flame retardant compound is a phosphazene compound and/or a phosphate.
3. The composition of claim 2 , where the phosphate is resorcinol diphosphate or bisphenol A diphosphate.
4. The composition of claim 1 , where the polycarbonate is a linear polymer having a weight average molecular weight or 15,000 to 60,000 grams per mole.
5. The composition of claim 1 , where the polycarbonate is a copolyestercarbonate.
6. The flame retardant composition of claim 5 , where the copolyestercarbonate copolymer comprises a first polycarbonate copolymer and a second polycarbonate copolymer; where the first polycarbonate copolymer and the second polycarbonate copolymer are each separately present in amounts of about 15 to about 70 wt %, based on the total weight of the flame retardant composition.
7. The flame retardant composition of claim 6 , where the first polycarbonate copolymer comprises 3 to 8 mole percent of the polyester derived from sebacic acid and where the first polycarbonate copolymer has a weight average molecular weight of 15,000 to 28,000 Daltons and is present in an amount of 20 to 55 weight percent based on the total weight of the flame retardant composition.
8. The flame retardant composition of claim 6 , where the second polycarbonate copolymer comprises 7 to 12 mole percent of the polyester derived from sebacic acid and where the first polycarbonate copolymer has a weight average molecular weight of 30,000 to 45,000 Daltons and is present in an amount of 10 to 35 weight percent based on the total weight of the flame retardant composition.
9. The flame retardant composition of claim 1 , polysiloxane-carbonate copolymer is present in an amount of 15 to 25 weight percent based on the total weight of the flame retardant composition and where the weight average molecular weight of the polysiloxane is 25,000 to 30,000 Daltons using gel permeation chromatography with a bisphenol A polycarbonate absolute molecular weight standard.
10. The flame retardant composition of claim 2 , comprising 3 to 10 weight percent of the phosphazene compound.
11. The composition of claim 1 , where the reinforcing filler is glass fiber, carbon fiber, metal fiber, whiskers, glass flake, mineral filler, or a combination comprising at least one of the foregoing reinforcing filler.
12. The composition of claim 1 , further comprising a mineral filler.
13. The composition of claim 12 , where the mineral filler is talc.
14. The composition of claim 2 , where the phosphazene compound has the structure of formula (30)
where m represents an integer of 3 to 25, R 1 and R 2 are the same or different and are independently a hydrogen, a halogen, a C 1-12 alkoxy, a C 1-12 alkyl, an aralkyl or an aralkyl.
15. The composition of claim 2 , where the phosphazene compound has the structure of formula (31):
where X 1 represents a —N═P(OPh) 3 group or a —N═P(O)OPh group, Y 1 represents a P(OPh) 4 group or a —P(O)(OPh) 2 group, n represents an integer from 3 to 10000, Ph represents a phenyl group, R1 and R2 are the same or different and are independently a hydrogen, a halogen, a C 1-12 alkoxy, an aralkyl or a C 1-12 alkyl.
16. The composition of claim 2 , where the phosphazene compound has the structure of formula (33)
where R1 to R6 can be the same of different and can be an aryl group, a fused aryl group, an aralkyl group, a C 1-12 alkoxy, a C 1-12 alkyl, or a combination thereof.
17. The composition of claim 2 , where the phosphazene compound has the structure of formula (34)
18. The composition of claim 2 , where the phosphazene compound is phenoxy cyclotriphosphazene, octaphenoxy cyclotetraphosphazene, decaphenoxy cyclopentaphosphazene, or a combination comprising at least one of the foregoing phenoxyphosphazene compounds.
19. The composition of claim 2 , where the phosphazene compound is a crosslinked phenoxyphosphazene.
20. The composition of claim 1 , where the composition displays a melt viscosity of 6 to 30 cubic centimeters per 10 minutes when measured as per ASTM D1238 at a temperature of 300° C. and a force of 2.16 kilograms.
21. The composition claim 2 , where the composition displays a flame out time of less than 60 seconds at a thickness of 1.0 millimeter when tested as per UL-94.
22. A method comprising:
blending a polycarbonate; 5 to 10 weight percent of a polysiloxane-polycarbonate copolymer; 5 to 20 weight percent of a branched polycarbonate; 5 to 60 weight percent of a reinforcing filler; where the reinforcing filler is a glass fiber, a carbon fiber, a metal fiber, or a combination comprising at least one of the foregoing reinforcing fillers; and 1 to 15 weight percent of a flame retardant compound to form a flame retardant composition; and
extruding the flame retardant composition; where the flame retardant composition has a notched Izod impact strength of 100 to 140 Joules/meter.
23. The method of claim 22 , further comprising molding the flame retardant composition.
24. The articles made of the composition of claim 1 .
25. The composition of claim 1 , where the flame retardant composition displays a flame retardancy of V-0 at a sample thickness of 0.8 millimeter or less when tested as per UL-94 protocol.
26. The composition of claim 1 , where the flame retardant composition displays a flame retardancy of V-1 at a sample thickness of 0.8 millimeter or less when tested as per UL-94 protocol.
27. The composition of claim 1 , where the flame retardant composition displays a flame retardancy of V-2 or 5VA at a sample thickness of 0.8 millimeter or less when tested as per UL-94 protocol.