Binder composition for electrode of electric storage device
A binder composition for an electrode of an electric storage device is provided. The binder composition comprises (A) at least one polymer selected from the group consisting of polyamic acids and imidized polymers thereof having an imidization rate of 50% or less and (B) water. The ratio Ma/Mb of the content of the polymer (A), Ma (parts by mass), to the content of the water (B), Mb (parts by mass), ranges from 500 to 5,000. The binder composition for an electrode of the present invention provides an electric storage device having a large charge/discharge capacity and a low degree of capacity degradation due to repetition of a charge/discharge cycle.
1. A binder composition comprising:
(A) at least one polymer selected from the group consisting of a polyamic acid and an imidized polymer of a polyamic acid having an imidization rate of 50% or less; and
(B) water,
wherein a ratio Ma/Mb of a mass of the polymer (A), Ma, to a mass of the water (B), Mb, is in a range of 500 to 5,000.
2. The binder composition of claim 1 , further comprising (C) at least one compound selected from the group consisting of a compound having two or more carboxy groups and an anhydride of a compound having two or more carboxy groups.
3. The binder composition of claim 2 , wherein a ratio Ma/Mc of the mass of the polymer (A), Ma, to a mass of the compound (C), Mc, is in a range of 50 to 400.
4. A slurry comprising:
the binder composition of claim 1 ; and
an electrode active material.
5. The slurry of claim 4 , wherein the electrode active material comprises at least one selected from the group consisting of elemental silicon, a silicon oxide, and a silicon alloy.
6. An electric storage device having an electrode comprising:
a current collector; and
an active material layer disposed on the current collector,
wherein the active material layer is formed from the slurry of claim 4 .
7. An electric storage device having an electrode comprising:
a current collector; and
an active material layer disposed on the current collector,
wherein the active material layer is formed from the slurry of claim 5 .
8. The binder composition of claim 1 , which is suitable for an electrode of an electric storage device.
9. The binder composition of claim 1 , comprising (A) the polyamic acid.
10. The binder composition of claim 1 , comprising (A) the imidized polymer of a polyamic acid.
11. The binder composition of claim 1 , comprising (A) both the polyamic acid and the imidized polymer of a polyamic acid.
12. The binder composition of claim 2 , comprising (C) the compound having two or more carboxy groups.
13. The binder composition of claim 2 , comprising (C) the anhydride of a compound having two or more carboxy groups.
14. The binder composition of claim 2 , comprising (C) both the compound having two or more carboxy groups and the anhydride of a compound having two or more carboxy groups.
15. The binder composition of claim 12 , wherein a ratio Ma/Mc of the mass of the polymer (A), Ma, to a mass of the compound (C), Mc, is in a range of 50 to 400.
16. The binder composition of claim 13 , wherein a ratio Ma/Mc of the mass of the polymer (A), Ma, to a mass of the compound (C), Mc, is in a range of 50 to 400.
17. The binder composition of claim 14 , wherein a ratio Ma/Mc of the mass of the polymer (A), Ma, to a mass of the compound (C), Mc, is in a range of 50 to 400.
18. The slurry of claim 4 , wherein the electrode active material comprises elemental silicon.
19. The slurry of claim 4 , wherein the electrode active material comprises a silicon oxide.
20. The slurry of claim 4 , wherein the electrode active material comprises a silicon alloy.
21. The binder composition of claim 1 ,
wherein a ratio Ma/Mb of a mass of the polymer (A), Ma, to a mass of the water (B), Mb, is in a range of 1,000 to 5,000.
22. The binder composition of claim 1 ,
wherein a ratio Ma/Mb of a mass of the polymer (A), Ma, to a mass of the water (B), Mb, is in a range of 1,300 to 3,500.
23. The binder composition of claim 1 ,
wherein a ratio Ma/Mb of a mass of the polymer (A), Ma, to a mass of the water (B), Mb, is in a range of 2,222 to 4,762.