Austenitic heat resistant alloy, heat resistant pressure member comprising the alloy, and method for manufacturing the same member
View Patent ↗An austenitic heat resistant alloy, which comprises by mass percent, C: over 0.02 to 0.15%, Si≦2%, Mn≦3%, P≦0.03%, S≦0.01%, Cr: 28 to 38%, Ni: over 40 to 60%, Co≦20% (including 0%), W over 3 to 15%, Ti: 0.05 to 1.0%, Zr: 0.005 to 0.2%, Al: 0.01 to 0.3%, N≦0.02%, and Mo<0.5%, with the balance being Fe and impurities, in which the following formulas (1) to (3) are satisfied has high creep rupture strength and high toughness after a long period of use at a high temperature, and further it is excellent in hot workability. This austenitic heat resistant alloy may contain a specific amount of one or more elements selected from Nb, V, Hf, B, Mg, Ca, Y, La, Ce, Nd, Sc, Ta, Re, Ir, Pd, Pt and Ag. P≦3/{200(Ti+8.5×Zr)} . . . (1), 1.35×Cr≦Ni+Co≦1.85×Cr . . . (2), Al≧1.5×Zr . . . (3).
1. A method for manufacturing a heat resistant pressure member excellent in creep resistance and structural stability in a high temperature range which is made from an austenitic heat resistant alloy comprising, by mass percent, C: more than 0.02% to not more than 0.15%, Si: 2% or less, Mn: 3% or less, P: 0.03% or less, S: 0.01% or less, Cr: more than 30% to 38%, Ni: more than 40% to not more than 60%, Co: 7.2 to 20%, W: more than 3% to not more than 15%, Ti: 0.53 to 1.0%, Zr: 0.005 to 0.2%, Al: 0.01 to 0.3%, N: 0.02% or less, and Mo: less than 0.5%, with the balance being Fe and impurities, in which the following formulas (1), (3) and (4) are satisfied:
P≦3/{200(Ti+8.5×Zr)} (1),
Al≧1.5×Zr (3),
1.35×Cr≦Ni+Co≦1.85×Cr (4);
wherein each element symbol in the formulas (1), (3) and (4) represents the content by mass % of the element concerned, and
wherein the austenitic heat resistant alloy is treated in sequence by the following steps (i), (ii) and (iii):
step (i): heating to 1050 to 1250° C. at least once before final hot or cold working;
step (ii): carrying out a final hot or cold plastic working such that a reduction of area is 10% or more;
step (iii): carrying out a final heat treatment in which cooling is performed after heating and holding at a temperature in the range of 1100 to 1250° C.
2. A method for manufacturing the heat resistant pressure member excellent in creep resistance and structural stability in a high temperature range according to claim 1 , wherein the austenitic heat resistant alloy further contains, by mass percent, one or more elements of one or more groups selected from the 1 to 3 groups listed below in lieu of a part of Fe:
1 Nb: 1.0% or less, V: 1.5% or less, Hf: 1% or less and B: 0.05% or less;
2 Mg: 0.05% or less, Ca: 0.05% or less, Y: 0.5% or less, La: 0.5% or less, Ce: 0.5% or less, Nd: 0.5% or less and Sc: 0.5% or less;
3 Ta: 8% or less, Re: 8% or less, Ir: 5% or less, Pd: 5% or less, Pt: 5% or less and Ag: 5% or less.