Electrolytic solution, secondary battery, battery pack, electric vehicle, electric power storage system, electric power tool, and electronic apparatus

1. A secondary battery, comprising:

a cathode;

an anode; and

an electrolytic solution including a cyano compound, the cyano compound including a compound represented by a following Formula (1),

where R1 and R2 are each one of a saturated hydrocarbon group, an unsaturated hydrocarbon group, an oxygen-containing saturated hydrocarbon group, a cyano-group-containing group, halogenated groups of the foregoing groups, or groups each obtained by bonding two or more of the foregoing groups to one another, and at least one of the R1, or the R2 include the cyano-group-containing group; a cyano group in the cyano-group-containing group is bonded to an oxygen atom (O) at a terminal of a —O—C(═O)—O— bond with one or more carbon atoms (C) in between; (A) in an event one of the R1 or the R2 exclude the cyano-group-containing group but includes an unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group, number of the cyano group in the other of the R1 or the R2 is one or larger; (B) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group and the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is one or larger; and (C) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group but exclude the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is two or larger.

2. The secondary battery according to claim 1 , wherein the cyano-group-containing group is one of a group obtained by substituting each of part or all of hydrogen groups in a saturated hydrocarbon group by a cyano group and a group obtained by substituting each of part or all of hydrogen groups in an unsaturated hydrocarbon group by a cyano group.

3. The secondary battery according to claim 2 , wherein the saturated hydrocarbon group is an alkyl group with carbon number from 1 to 12 both inclusive, and the unsaturated hydrocarbon group is an aryl group with carbon number from 6 to 18 both inclusive.

4. The secondary battery according to claim 1 , wherein the saturated hydrocarbon group is one of an alkyl group with carbon number from 1 to 12 both inclusive or a cycloalkyl group with carbon number from 3 to 18 both inclusive,

the unsaturated hydrocarbon group is one of an alkenyl group with carbon number from 2 to 12 both inclusive, an alkynyl group with carbon number from 2 to 12 both inclusive, or an aryl group with carbon number from 6 to 18 both inclusive,

the oxygen-containing saturated hydrocarbon group is an alkoxy group with carbon number from 1 to 12 both inclusive, and

the halogenated groups each include, as a halogen group, one or more of a fluorine group, a chlorine group, a bromine group, and an iodine group.

5. The secondary battery according to claim 1 , wherein the compound represented by the Formula (1) is a compound represented by following Formula (1-1)

6. The secondary battery according to claim 1 , wherein a content of the cyano compound in the electrolytic solution is from about 0.01 weight percent to about 20 weight percent both inclusive.

7. The secondary battery according to claim 1 , wherein the electrolytic solution includes a non-cyano compound, and

the non-cyano compound includes one or more of a compound represented by a following Formula (3)

where R11 and R13 are each one of a monovalent hydrocarbon group, a monovalent oxygen-containing hydrocarbon group, halogenated groups of the foregoing groups, or groups each obtained by bonding two or more of the foregoing groups to one another; and R12 is one of a divalent hydrocarbon group or halogenated groups thereof.

8. The secondary battery according to claim 7 , wherein the monovalent hydrocarbon group and the monovalent oxygen-containing hydrocarbon group encompass an alkyl group with carbon number from 1 to 12 both inclusive, an alkenyl group with carbon number from 2 to 12 both inclusive, an alkynyl group with carbon number from 2 to 12 both inclusive, an aryl group with carbon number from 6 to 18 both inclusive, a cycloalkyl group with carbon number from 3 to 18 both inclusive, and an alkoxy group with carbon number from 1 to 12 both inclusive,

the divalent hydrocarbon group is one of an alkylene group with carbon number from 1 to 12 both inclusive, an alkenylene group with carbon number from 2 to 12 both inclusive, an alkynylene group with carbon number from 2 to 12 both inclusive, an arylene group with carbon number from 6 to 18 both inclusive, a cycloalkylene group with carbon number from 3 to 18 both inclusive, groups each obtained by bonding two or more of the foregoing groups to one another, or groups each including at least one of the foregoing groups or an ether bond (—O—), and

the halogenated group includes, as a halogen group, at least one of a fluorine group, a chlorine group, a bromine group, or an iodine group.

9. The secondary battery according to claim 7 , wherein the compound represented by the Formula (3) is a compound represented by following Formula (3-1)

10. The secondary battery according to claim 7 , wherein a content of the non-cyano compound in the electrolytic solution is from about 0.001 weight percent to about 2 weight percent both inclusive.

11. The secondary battery according to claim 1 , wherein the secondary battery is a lithium secondary battery.

12. An electrolytic solution, comprising:

a cyano compound including a compound represented by a following Formula (1),

where R1 and R2 are each one of a saturated hydrocarbon group, an unsaturated hydrocarbon group, an oxygen-containing saturated hydrocarbon group, a cyano-group-containing group, halogenated groups of the foregoing groups, or groups each obtained by bonding two or more of the foregoing groups to one another, and at least one of the R1, or the R2 include the cyano-group-containing group; a cyano group in the cyano-group-containing group is bonded to an oxygen atom (O) at a terminal of a —O—C(═O)—O— bond with one or more carbon atoms (C) in between; (A) in an event one of the R1 or the R2 does not include exclude the cyano-group-containing group but includes an unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group, number of the cyano group in the other of the R1 or the R2 is one or larger; (B) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group and the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is one or larger; and (C) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group but exclude the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is two or larger.

13. A battery pack, comprising:

a secondary battery;

a control section configured to control a used state of the secondary battery; and

a switch section configured to switch the used state of the secondary battery according to an instruction of the control section, wherein the used state of the secondary battery corresponds to a state in which the secondary battery is connected to an external device, and wherein the secondary battery includes

a cathode,

an anode, and

an electrolytic solution including a cyano compound, the cyano compound including a compound represented by a following Formula (1),

where R1 and R2 are each one of a saturated hydrocarbon group, an unsaturated hydrocarbon group, an oxygen-containing saturated hydrocarbon group, a cyano-group-containing group, halogenated groups of the foregoing groups, or groups each obtained by bonding two or more of the foregoing groups to one another, and at least one of the R1, or the R2 include the cyano-group-containing group; a cyano group in the cyano-group-containing group is bonded to an oxygen atom (O) at a terminal of a —O—C(═O)—O— bond with one or more carbon atoms (C) in between; (A) in an event one of the R1 or the R2 exclude the cyano-group-containing group but includes an unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group, number of the cyano group in the other of the R1 or the R2 is one or larger; (B) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group and the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is one or larger; and (C) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group but exclude the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is two or larger.

14. An electric vehicle, comprising:

a secondary battery;

a conversion section configured to convert electric power supplied from the secondary battery into drive power;

a drive section configured to operate according to the drive power; and

a control section configured to control a used state of the secondary battery, wherein

the secondary battery includes

a cathode,

an anode, and

an electrolytic solution including a cyano compound, the cyano compound including a compound represented by a following Formula (1),

where R1 and R2 are each one of a saturated hydrocarbon group, an unsaturated hydrocarbon group, an oxygen-containing saturated hydrocarbon group, a cyano-group-containing group, halogenated groups of the foregoing groups, or groups each obtained by bonding two or more of the foregoing groups to one another, and at least one of the R1, or the R2 include the cyano-group-containing group; a cyano group in the cyano-group-containing group is bonded to an oxygen atom (O) at a terminal of a —O—C(═O)—O— bond with one or more carbon atoms (C) in between; (A) in an event one of the R1 or the R2 exclude the cyano-group-containing group but includes an unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group, number of the cyano group in the other of the R1 or the R2 is one or larger; (B) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group and the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is one or larger; and (C) in an event one of the R1 or the R2 exclude at least one or the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group but exclude the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is two or larger.

15. An electric power storage system, comprising:

a secondary battery;

one or more electric devices supplied with electric power from the secondary battery;

and

a control section configured to control the supply of the electric power from the secondary battery to the one or more electric devices, wherein the secondary battery includes

a cathode,

an anode, and

an electrolytic solution including a cyano compound, the cyano compound including a compound represented by a following Formula (1),

where R1 and R2 are each one of a saturated hydrocarbon group, an unsaturated hydrocarbon group, an oxygen-containing saturated hydrocarbon group, a cyano-group-containing group, halogenated groups of the foregoing groups, or groups each obtained by bonding two or more of the foregoing groups to one another, and at least one of the R1, or the R2 include the cyano-group-containing group; a cyano group in the cyano-group-containing group is bonded to an oxygen atom (O) at a terminal of a —O—C(═O)—O— bond with one or more carbon atoms (C) in between; (A) in an event one of the R1 or the R2 exclude the cyano-group-containing group but includes an unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group, number of the cyano group in the other of the R1 or the R2 is one or larger; (B) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group and the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is one or larger; and (C) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group but exclude the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is two or larger.

16. An electric power tool, comprising:

a secondary battery; and

a movable section supplied with electric power from the secondary battery, wherein the secondary battery includes

a cathode,

an anode, and

an electrolytic solution including a cyano compound, the cyano compound including a compound represented by a following Formula (1),

where R1 and R2 are each one of a saturated hydrocarbon group, an unsaturated hydrocarbon group, an oxygen-containing saturated hydrocarbon group, a cyano-group-containing group, halogenated groups of the foregoing groups, or groups each obtained by bonding two or more of the foregoing groups to one another, and at least one of the R1, or the R2 include the cyano-group-containing group; a cyano group in the cyano-group-containing group is bonded to an oxygen atom (O) at a terminal of a —O—C(═O)—O— bond with one or more carbon atoms (C) in between; (A) in an event one of the R1 or the R2 exclude the cyano-group-containing group but includes an unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group, number of the cyano group in the other of the R1 or the R2 is one or larger; (B) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group and the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is one or larger; and (C) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group but exclude the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is two or larger.

17. An electronic apparatus, comprising:

a secondary battery as an electric power supply source, wherein the secondary battery includes

a cathode,

an anode, and

an electrolytic solution including a cyano compound, the cyano compound including a compound represented by a following Formula (1),

where R1 and R2 are each one of a saturated hydrocarbon group, an unsaturated hydrocarbon group, an oxygen-containing saturated hydrocarbon group, a cyano-group-containing group, halogenated groups of the foregoing groups, or groups each obtained by bonding two or more of the foregoing groups to one another, and at least one of the R1, or the R2 include the cyano-group-containing group; a cyano group in the cyano-group-containing group is bonded to an oxygen atom (O) at a terminal of a —O—C(═O)—O— bond with one or more carbon atoms (C) in between; (A) in an event one of the R1 or the R2 exclude the cyano-group-containing group but includes an unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group, number of the cyano group in the other of the R1 or the R2 is one or larger; (B) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group and the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is one or larger; and (C) in an event one of the R1 or the R2 exclude at least one of the cyano-group-containing group or the unsaturated carbon bond and the other of the R1 or the R2 includes the cyano-group-containing group but exclude the unsaturated carbon bond, the number of the cyano group in the other of the R1 or the R2 is two or larger.