IP Library Granted Patent US 9,125,427
Granted Patent B2
US 9,125,427 · App. 13/915,594 · Granted Sep 8, 2015

Method for sanitizing fresh produce

Inventors: Bob J. Dull (Akron, OH); Roger Dale Billingsley (Laguna Niguel, CA); Abizer Moiz Khairullah (Morgan Hill, CA); Amanda Jane Deering (Lafayette, IN); Jessica Okane Kawabata (Salinas, CA); Jonna Marie Thomas (Hollister, CA)
Assignee: Dole Fresh Vegetables, Inc.
A23L1/0157A23B7/157A23L1/0011A23B7/153A23B9/24A23L3/3454B08B3/00B08B3/04
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Quick Facts
Patent No.
US 9,125,427
App. No.
13/915,594
Granted
Sep 8, 2015
Kind
B2
Abstract

A method for sanitizing produce, by: treating the produce with a chlorine dioxide solution for a period of time sufficient to sanitize the produce; treating the produce with a solution containing chlorine for a period of time sufficient to further sanitize the produce; and treating the produce with a solution containing peroxyacetic acid for a period of time sufficient to further sanitize the produce, where treating with the chlorine dioxide solution, the solution containing chlorine, and the solution containing peroxyacetic acid yields at least an additional 1 log unit reduction in microbial load, as compared to produce treated with a single solution selected from the chlorine dioxide solution, the solution containing chlorine, and the solution containing peroxyacetic acid.

Claims (25)

1. A method for sanitizing produce, the method comprising:

(a) treating the produce with a chlorine dioxide solution for a period of time sufficient to sanitize the produce;

(b) treating the produce with a solution comprising free available chlorine for a period of time sufficient to sanitize the produce; and

(c) treating the chlorine dioxide treated and chlorine treated produce with a solution comprising peroxyacetic acid for a period of time sufficient to further sanitize the produce,

wherein treating with the chlorine dioxide solution, the solution comprising free available chlorine, and the solution comprising peroxyacetic acid yields at least an additional 1 log unit reduction in microbial load, as compared to produce treated with a single solution selected from the chlorine dioxide solution, the solution comprising free available chlorine, and the solution comprising peroxyacetic acid,

wherein treating the produce with the chlorine dioxide solution and treating the produce with the solution comprising free available chlorine occur before treating the produce with the solution comprising peroxyacetic acid,

wherein treating the produce with the solution comprising free available chlorine can occur before treating the produce with the chlorine dioxide solution,

wherein treating with the solution comprising peroxyacetic acid reduces concentration of the chlorine dioxide solution, and wherein the concentration of the chlorine dioxide solution after treatment with the solution comprising peroxyacetic acid is less than 2 ppm.

2. The method of claim 1 , wherein step (a) occurs prior to step (b).

3. The method of claim 1 , wherein treating with the chlorine dioxide solution dissolves biofilm on the surface of the produce.

4. The method of claim 1 , wherein treating with the chlorine dioxide solution, the solution comprising free available chlorine, and the solution comprising peroxyacetic acid yields an additional log unit reduction in microbial load that ranges from 1.5 to 6, as compared to produce treated with a single solution selected from the chlorine dioxide solution, the solution comprising free available chlorine, and the solution comprising peroxyacetic acid.

5. The method of claim 1 , further comprising sonicating the produce before, concurrently, or after treating with the chlorine dioxide solution, the solution comprising free available chlorine, and/or the solution comprising peroxyacetic acid.

6. The method of claim 1 , further comprising treating the produce with an electrolyzed ionic solution before, concurrently, or after treating with the chlorine dioxide solution, the solution comprising free available chlorine, and/or the solution comprising peroxyacetic acid.

7. The method of claim 1 , further comprising treating the produce with potable water after treating with the chlorine dioxide solution, the solution comprising free available chlorine, and the solution comprising peroxyacetic acid.

8. The method of claim 1 , wherein treating with the chlorine dioxide solution, the solution comprising free available chlorine, and the solution comprising peroxyacetic acid yields an increase in shelf-life of the produce, as compared to produce treated with a single solution selected from the chlorine dioxide solution, the solution comprising free available chlorine, and the solution comprising peroxyacetic acid.

9. The method of claim 1 , wherein the produce is selected from the group consisting of a vegetable, a leafy vegetable, lettuce, spinach, a ground plant, sprouts, a squash, a melon, a gourd, a fruit, a berry, a nut, and any combination thereof.

10. The method of claim 1 , wherein step (b) occurs prior to step (a).

11. The method of claim 1 , wherein steps (a) and (b) occur concurrently.

12. A method for sanitizing produce, the method comprising:

treating the produce with a chlorine dioxide solution to yield a chlorine dioxide treated produce;

treating the chlorine dioxide treated produce with a solution comprising free available chlorine to yield a chlorine treated produce; and

treating the chlorine treated produce with a solution comprising peroxyacetic acid to yield sanitized produce,

wherein treating with the chlorine dioxide solution, the solution comprising free available chlorine, and the solution comprising peroxyacetic acid yields at least an additional 1 log unit reduction in microbial load, as compared to produce treated with a single solution selected from the chlorine dioxide solution, the solution comprising free available chlorine, and the solution comprising peroxyacetic acid,

wherein treating the produce with the chlorine dioxide solution and treating the produce with the solution comprising free available chlorine occur before treating the produce with the solution comprising peroxyacetic acid,

wherein treating with the solution comprising peroxyacetic acid reduces concentration of the chlorine dioxide solution, and wherein the concentration of the chlorine dioxide solution after treatment with the solution comprising peroxyacetic acid is less than 2 ppm.

Assignments (20)
RELEASE OF SECURITY INTEREST Recorded Aug 8, 2025
From: COÖPERATIEVE RABOBANK U.A.
To: BUD ANTLE, LLC
Reel/Frame 071976/0516 →
CHANGE OF NAME Recorded Aug 8, 2025
From: BUD ANTLE, INC.
To: BUD ANTLE, LLC
Reel/Frame 072388/0634 →
SECURITY INTEREST Recorded Aug 6, 2025
From: BUD ANTLE, LLC (F/K/A BUD ANTLE, INC.); ORGANICGIRL, LLC
To: COÖPERATIEVE RABOBANK U.A., NEW YORK BRANCH
Reel/Frame 071944/0797 →
PARTIAL RELEASE OF SECURITY INTEREST (57108/0639) Recorded Aug 5, 2025
From: COÖPERATIEVE RABOBANK U.A., NEW YORK BRANCH
To: BUD ANTLE, LLC (AS SUCCESSOR-BY-CONVERSION TO BUD ANTLE, INC. AND AS SUCCESSOR-BY-ASSIGNMENT TO DOLE FRESH VEGETABLES, INC.)
Reel/Frame 072394/0208 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 27, 2023
From: DOLE FRESH VEGETABLES, INC.
To: BUD ANTLE, INC.
Reel/Frame 062506/0201 →
SECURITY AGREEMENT Recorded Aug 6, 2021
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: COÖPERATIEVE RABOBANK U.A., NEW YORK BRANCH, AS COLLATERAL AGENT
Reel/Frame 057108/0639 →
RELEASE OF SECURITY INTEREST Recorded Aug 6, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.; BUD ANTLE, INC.; DOLE DIVERSIFIED NORTH AMERICA, INC. (F/K/A DOLE BERRY COMPANY AND SUNNYRIDGE FARM, INC.); RENAISSANCE CAPITAL CORPORATION; DFC HOLDINGS, LLC; DOLE FRESH FRUIT COMPANY; ROYAL PACKING LLC (F/K/A ROYAL PACKING CO.)
Reel/Frame 057108/0601 →
RELEASE (REEL 042197 / FRAME 0586) Recorded Aug 5, 2021
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
Reel/Frame 057089/0460 →
RELEASE (REEL 042232 / FRAME 0777) Recorded Aug 5, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
Reel/Frame 057089/0392 →
RELEASE (REEL 042206 / FRAME 0828) Recorded Aug 5, 2021
From: BANK OF AMERICA, N.A.
To: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
Reel/Frame 057089/0499 →
SECURITY AGREEMENT Recorded Apr 12, 2017
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 042232/0777 →
SECURITY AGREEMENT Recorded Apr 11, 2017
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 042206/0828 →
SECURITY AGREEMENT Recorded Apr 10, 2017
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC., AS ADMINISTRATIVE AGENT
Reel/Frame 042197/0586 →
RELEASE OF SECURITY INTEREST Recorded Apr 7, 2017
From: DEUTSCHE BANK TRUST COMPANY AMERICAS
To: DOLE FOOD COMPANY, INC.; BUD ANTLE, INC.; DOLE FRESH FRUIT COMPANY; ROYAL PACKING LLC; DOLE BERRY COMPANY; DOLE FRESH VEGETABLES, INC.
Reel/Frame 041927/0361 →
RELEASE OF SECURITY INTEREST Recorded Apr 7, 2017
From: DEUTSCHE BANK AG NEW YORK BRANCH
To: DOLE FOOD COMPANY, INC.; BUD ANTLE, INC.; DOLE FRESH FRUIT COMPANY; ROYAL PACKING CO.; DOLE BERRY COMPANY; DOLE FRESH VEGETABLES, INC.
Reel/Frame 041929/0297 →
RELEASE OF SECURITY INTEREST Recorded Apr 7, 2017
From: DEUTSCHE BANK AG NEW YORK BRANCH
To: DOLE FOOD COMPANY, INC.; BUD ANTLE, INC.; DOLE FRESH FRUIT COMPANY; ROYAL PACKING CO.; DOLE BERRY COMPANY; DOLE FRESH VEGETABLES, INC.
Reel/Frame 041932/0215 →
SECURITY AGREEMENT Recorded Nov 7, 2013
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
Reel/Frame 031597/0857 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS ADMINISTRATIVE AGENT
Reel/Frame 031588/0825 →
SECURITY AGREEMENT Recorded Nov 5, 2013
From: DOLE FOOD COMPANY, INC.; DOLE FRESH VEGETABLES, INC.
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS ADMINISTRATIVE AGENT
Reel/Frame 031580/0121 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 17, 2013
From: DULL, BOB J.; BILLINGSLEY, ROGER DALE; KHAIRULLAH, ABIZER MOIZ; DEERING, AMANDA JANE; KAWABATA, JESSICA OKANE; THOMAS, JONNA MARIE
To: DOLE FRESH VEGETABLES, INC.
Reel/Frame 031425/0312 →
Continuity (2)
Provisional Application 61752663 · Jan 15, 2013
Related Publication 20140196751A1 · Jul 17, 2014