Method for preparing a latex from a chlorinated vinylic polymer
View Patent ↗Process for preparing a seed latex of a methyl methacrylate polymer (PMMA) by radical polymerization in aqueous emulsion of methyl methacrylate and optionally at least one comonomer. Process for preparing a chlorinated vinyl polymer latex by radical polymerization in aqueous emulsion of at least one chlorinated vinyl monomer, according to which the polymerization takes place in the presence of at most 3% by weight, expressed relative to the total weight of the monomers, of the PMMA seed latex.
1. A chlorinated vinyl polymer latex, comprising:
particles, dispersed in water, of an interpolymer of (i) base particles of a methyl methacrylate polymer seed latex, and of (ii) a chlorinated vinyl polymer formed on the base seed;
wherein an average diameter of the particles of the interpolymer, measured by hydrodynamic fractionation, is greater than or equal to 120 nm, and
an average diameter of the particles of the methyl methacrylate polymer seed latex, measured by hydrodynamic fractionation, is less than or equal to 60 nm,
wherein the particles of the interpolymer have a content of at most 2.0% by weight of the methyl methacrylate polymer seed latex, relative to a total weight of the chlorinated vinyl polymer formed on the base seed, and
a particle size distribution of the particles of the interpolymer, as determined by hydrodynamical fractionation is monomodal.
2. The chlorinated vinyl polymer latex of claim 1 , wherein the chlorinated vinyl polymer is a vinylidene chloride polymer.
3. The chlorinated vinyl polymer latex according to claim 1 , wherein the particles of the methyl methacrylate polymer seed latex have an average diameter, measured by hydrodynamic fractionation, less than or equal to 40 nm.
4. The chlorinated vinyl polymer latex according to claim 1 , wherein the particles of the methyl methacrylate polymer seed latex have a monomodal particle diameter distribution, determined by hydrodynamic fractionation, wherein a standard deviation is less than or equal to 20 nm.
5. The chlorinated vinyl polymer latex according to claim 1 , wherein the particles of the methyl methacrylate polymer seed latex have a monomodal particle diameter distribution, determined by hydrodynamic fractionation, wherein a standard deviation is less than or equal to 10 nm.
6. The chlorinated vinyl polymer latex according to claim 1 , wherein the particles of the interpolymer have an average diameter, measured by hydrodynamic fractionation, of at most 200 nm.
7. The chlorinated vinyl polymer latex according to claim 1 , wherein the content of the methyl methacrylate polymer seed latex is at most 1.5% by weight relative to the total weight of the chlorinated vinyl polymer formed on the base seed.
8. The chlorinated vinyl polymer latex according to claim 2 , wherein the vinylidene chloride polymer is a copolymer of vinylidene chloride and at least one monomer selected from the group consisting of maleic anhydride, itaconic acid, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, glycidyl methacrylate, glycidyl acrylate, acrylonitrile, methacrylonitrile, acrylic acid, methacrylic acid, acrylamide, N-methylolacrylamide, 2-acrylamido-2-methylpropanesulphonic acid (AMPS), a salt of AMPS, 2-sulphoethylmethacrylic acid (2-SEM), a salt of 2-SEM, a phosphate ester of methacrylate-terminated polypropylene glycol, and a salt of a phosphate ester of methacrylate-terminated polypropylene glycol.
9. The chlorinated vinyl polymer latex according to claim 2 , wherein the vinylidene chloride polymer comprises from 50 to 95% by weight of vinylidene chloride.