IP Library Granted Patent US 9,034,125
Granted Patent B2
US 9,034,125 · App. 13/917,951 · Granted May 19, 2015

Method for manufacturing Ni base alloy pipe stock

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Quick Facts
Patent No.
US 9,034,125
App. No.
13/917,951
Granted
May 19, 2015
Kind
B2
Abstract

A method for manufacturing an Ni base alloy pipe stock comprises piercing and rolling a billet by use of Mannesmann piercing and rolling mill. The pipe stock has controlled amounts of C, Si, Mn, P, S, Cr, Ni, Mo, W, Cu, Al, N, with the balance being Fe. With the method, the following equations are satisfied, wherein values of T GBm , P sr and P σ represented by the following equations (1) to (3) being not more than 1300, not more than 200 and not less than 0, respectively T GBm =1380−5000P−100S−4400C  (1), P sr Ni+10(Mo+0.5W)+100N  (2), P σ =(Ni−50)+10(N−0.1)−2(Cr−25)−5(Mo+0.5W−6)+12  (3), wherein each element symbol in the equations represents mass % of the element concerned.

Claims (21)

1. A method for manufacturing an Ni base alloy pipe stock, comprising piercing and rolling a billet, by use of a Mannesmann piercing and rolling mill, which satisfies the chemical compositions consisting of, by mass %, C: not more than 0.04%, Si: not more than 0.50%, Mn: 0.01 to 6.0%, P: not more than 0.03%, S: not more than 0.01%, Cr: 15 to 30%, Ni: more than 45% to not more than 60%, Mo: 0 to 18%, W: 0 to 36%, with Mo (%)+0.5W (%): more than 1.5% to not more than 18%, Cu: 0.01 to 1.5%, Al: not more than 0.10% and N: 0.005 to 0.20%, and the balance being substantially Fe, with values of T GBm , P sr and P σ represented by the following equations (1) to (3) being not more than 1300, not more than 200 and not less than 0, respectively, and moreover being subjected to piercing and rolling by a Mannesmann piercing and rolling mill:

T GBm =1380−5000P−100S−4400C  (1),

P sr Ni+10(Mo+0.5W)+100N  (2),

P σ =(Ni−50)+10(N−0.1)−2(Cr−25)−5(Mo+0.5W−6)+12  (3),

wherein each element symbol in the equations (1) to (3) represents the content by mass % of the element concerned.

2. The method for manufacturing an Ni base alloy pipe stock according to claim 1 , wherein the piercing and rolling by the Mannesmann piercing and rolling mill is performed in a condition where the value of fn represented by the following equation (4) is not more than 0.3:

fn ={P/(0.025H−0.01)} 2 +{S/(0.015H−0.01)} 2   (4),

wherein P and S represent contents, by mass %, of P and S in the pipe stock, respectively, and H represents the pipe expansion ratio represented by the ratio of the outer diameter of the pipe stock to the diameter of the steel stock billet.

3. A method for manufacturing an Ni base alloy pipe stock, comprising piercing and rolling a billet, by use of a Mannesmann piercing and rolling mill, which satisfies the chemical compositions consisting essentially of, by mass %, C: not more than 0.04%, Si: not more than 0.50%, Mn: 0.01 to 6.0%, P: not more than 0.03%, S: not more than 0.01%, Cr: 15 to 30%, Ni: more than 45% to not more than 60%, Mo: 0 to 18%, W: 0 to 36%, with Mo (%)+0.5W (%): more than 1.5% to not more than 18%, Cu: 0.01 to 1.5%, Al: not more than 0.10% and N: 0.005 to 0.20%, and the balance being substantially Fe, with values of T GBm , P sr and P σ represented by the following equations (1) to (3) being not more than 1300, not more than 200 and not less than 0, respectively, and moreover being subjected to piercing and rolling by a Mannesmann piercing and rolling mill:

T GBm =1380−5000P−100S−4400C  (1),

P sr Ni+10(Mo+0.5W)+100N  (2),

P σ =(Ni−50)+10(N−0.1)−2(Cr−25)−5(Mo+0.5W−6)+12  (3),

wherein each element symbol in the equations (1) to (3) represents the content by mass % of the element concerned, and

which further consists essentially of an element or elements of one or more groups selected from the groups (a) to (d) listed below in lieu of part of Fe:

(a): one or more selected from among V: 0.001 to 0.3%, Nb: 0.001 to 0.3%, Ta: 0.001 to 1.0%, Ti: 0.001 to 1.0%, Zr: 0.001 to 1.0% and Hf: 0.001 to 1.0% by mass %;

(b): B: 0.0001 to 0.015% by mass %;

(c): Co: 0.3 to 5.0% by mass %;

(d): one or more selected from among Mg: 0.0001 to 0.010%, Ca: 0.0001 to 0.010%, La: 0.0001 to 0.20%, Ce: 0.0001 to 0.20%, Y: 0.0001 to 0.40%, Sm: 0.0001 to 0.40%, Pr: 0.0001 to 0.40% and Nd: 0.0001 to 0.50% by mass %.

4. The method for manufacturing an Ni base alloy pipe stock according to claim 3 , wherein the piercing and rolling by the Mannesmann piercing and rolling mill is performed in a condition where the value of fn represented by the following equation (4) is not more than 0.3:

fn ={P/(0.025H−0.01)} 2 +{S/(0.015H−0.01)} 2   (4),

wherein P and S represent contents, by mass %, of P and S in the pipe stock, respectively, and H represents the pipe expansion ratio represented by the ratio of the outer diameter of the pipe stock to the diameter of the steel stock billet.

Assignments (1)
CHANGE OF NAME Recorded May 14, 2019
From: NIPPON STEEL & SUMITOMO METAL CORPORATION
To: NIPPON STEEL CORPORATION
Reel/Frame 049257/0828 →