Stain-resistant label adhered to product including one or more label-staining materials therein
In combination, a plastic label attached to an outer surface of a product by a pressure sensitive adhesive. The pressure sensitive adhesive is attached to an exposed surface of an inner surface layer of the label, and the product includes one or more materials capable of migrating through the label and providing visible stains therein. The inner surface layer of the label includes a hydroxyl functionalized polyether amine resin preventing the material exuded from the product from migrating through the label thickness to provide visible staining of said label. A single extruded film of the label or the core of a multilayer label including either high crystalline polypropylene homopolymer, with or without a hard resin, or a conventional polypropylene with a hard resin.
1. In combination, a plastic label attached to an outer surface of a rubber-based vehicular tire by a pressure sensitive adhesive, said pressure sensitive adhesive being attached to an exposed surface of an inner surface layer of said label, said tire including one or more materials capable of migrating through said label and providing visible stains on an outer exposed surface thereof, said inner surface layer of said label including a hydroxyl functionalized polyether amine resin preventing the material exuded from the tire from migrating through the label thickness to provide visible staining of said outer exposed surface of said label.
2. The combination of claim 1 , wherein a maleated polyolefin layer is included between a core layer of the label and said inner surface layer of said label comprising said hydroxyl functionalized polyether amine.
3. The combination of claim 1 , wherein said label is a single, extruded film layer including said inner surface layer coated thereon.
4. The combination of claim 1 , wherein said label is a multilayer structure including an interior core layer employing a polyolefin homopolymer or copolymer, said inner surface layer being on one side of said core layer and constituting an exposed surface of said label including the pressures sensitive adhesive thereon, and a second layer on the side of said core layer opposed to said inner surface layer.
5. The combination of claim 1 , wherein said outer exposed surface includes the plastic label includes a visible layer spaced outwardly from said inner layer and including printed indicia thereon.
6. The combination of claim 4 , wherein said second layer includes polyurethane resin.
7. The combination of claim 4 , wherein said core layer and said inner surface layer are biaxially oriented, said second layer being a urethane coating applied to the core layer between a machine direction orientation and a transverse direction orientation of a two-step tentering operation.
8. The combination of claim 4 , wherein said core layer is biaxially oriented and said inner surface layer of said hydroxyl functionalized polyether amine being applied to the core layer between a machine direction orientation and a transverse direction orientation of a two-step tentering operation.
9. The combination of claim 3 , wherein said single extruded film includes a homopolymer polypropylene and a hard resin.
10. The combination of claim 3 , wherein said single extruded film includes a conventional polypropylene and a hard resin, said hard resin being present in an amount of at least 2.5% by weight, based on the weight of the monolayer structure.
11. The combination of claim 4 , wherein said core layer includes a homopolymer polypropylene and a hard resin.
12. The combination of claim 4 , wherein said core layer includes a high crystalline polypropylene and hard resin therein.
13. The combination of claim 4 , wherein said core layer includes a conventional polypropylene and a hard resin, said hard resin being present in an amount of at least 2.5% by weight, based on the weight of the monolayer structure.