Organic acid-modified polymers for golf ball constructions and methods relating thereto
View Patent ↗The invention is directed to a method of making a neutralized polymer composition (“NPC”) suitable for a golf ball component comprising the steps of: providing an acid copolymer composition; soaking the acid copolymer composition in an organic acid to form a soaked polymeric composition wherein substantially all of the organic acid is absorbed within the acid copolymer composition; providing a cation source in an amount sufficient to neutralize the acid copolymer and organic acid; and melt processing the soaked polymeric composition and cation source to form a neutralized polymer composition. The invention also relates to a method of making a golf ball incorporating the NPC made according to the inventive method and to the resulting golf ball.
1. A method of making a neutralized polymer composition (NPC) suitable for use in a golf ball component comprising the steps of:
providing an acid copolymer composition;
soaking the acid copolymer composition in an organic acid to form a soaked polymeric composition;
providing a cation source in an amount sufficient to neutralize at least a portion of the acid copolymer composition and organic acid; and
melt processing the soaked polymeric composition and cation source to form the NPC; and
wherein the soaked polymer composition comprises the organic acid and acid copolymer composition in a weight ratio of from about 1:9 to about 1:1.
2. The method of claim 1 , wherein the acid copolymer composition comprises at least one acid-containing ethylene copolymer.
3. The method of claim 2 , wherein the acid-containing ethylene copolymer is selected from the group consisting of: ethylene/acrylic acid/n-butyl acrylate, ethylene/methacrylic acid/n-butyl acrylate, ethylene/methacrylic acid/iso-butyl acrylate, ethylene/acrylic acid/iso-butyl acrylate, ethylene/methacrylic acid/n-butyl methacrylate, ethylene/acrylic acid/methyl methacrylate, ethylene/acrylic acid/methyl acrylate, ethylene/methacrylic acid/methyl acrylate, ethylene/methacrylic acid/methyl methacrylate, and ethylene/acrylic acid/n-butyl methacrylate, ethylene/acrylic acid/ethyl acrylate, ethylene/methacrylic acid/ethyl acrylate, ethylene/acrylic acid, and ethylene/methacrylic acid.
4. The method of claim 1 , wherein the organic acid is selected from the group consisting of aliphatic organic acids, aromatic organic acids, saturated mono- or multi-functional organic acids, unsaturated mono- or multi-functional organic acids, and multi-unsaturated mono- or multi-functional organic acids.
5. The method of claim 1 , wherein the organic acid comprises stearic acid, behenic acid, erucic acid, oleic acid, linoleic acid, linolenic acid or dimerized derivatives thereof.
6. The method of claim 1 , wherein the soaking step is performed at a soaking temperature of from about 20° C. to about 100° C.
7. The method of claim 1 , wherein the soaked polymer composition comprises the organic acid and acid copolymer composition in a weight ratio of about 2:3.
8. The method of claim 1 , wherein the acid copolymer composition is formed from (a) a high acid ethylene/acrylic copolymer and (b) ethylene/acrylic acid/methyl acrylate copolymer, blended; wherein the organic acid is comprised of oleic acid; and wherein the cation source is comprised of magnesium hydroxide in an amount sufficient to neutralize from about 95% to about 125% of the acid copolymer composition and organic acid.
9. A method of making a golf ball having at least one component comprising a neutralized polymer composition (NPC), comprising the steps of:
providing a center;
forming a layer about the center; and
forming a cover about the layer;
wherein at least one of the center, the layer and the cover comprises an NPC formed by:
providing an acid copolymer composition;
soaking the acid copolymer composition in an organic acid to form a soaked polymeric composition;
providing a cation source in an amount sufficient to neutralize the acid copolymer composition and organic acid; and
melt processing the soaked polymeric composition and cation source; and
wherein the soaked polymeric composition comprises the organic acid and acid copolymer composition in a weight ratio of from about 1:9 to about 1:1.
10. The method of claim 9 , wherein the acid copolymer composition comprises an acid-containing ethylene copolymer selected from the group consisting of: ethylene/acrylic acid/n-butyl acrylate, ethylene/methacrylic acid/n-butyl acrylate, ethylene/methacrylic acid/iso-butyl acrylate, ethylene/acrylic acid/iso-butyl acrylate, ethylene/methacrylic acid/n-butyl methacrylate, ethylene/acrylic acid/methyl methacrylate, ethylene/acrylic acid/methyl acrylate, ethylene/methacrylic acid/methyl acrylate, ethylene/methacrylic acid/methyl methacrylate, and ethylene/acrylic acid/n-butyl methacrylate, ethylene/acrylic acid/ethyl acrylate, and ethylene/methacrylic acid/ethyl acrylate, ethylene/acrylic acid, and ethylene/methacrylic acid.
11. The method of claim 9 , wherein the organic acid is selected from the group consisting of aliphatic organic acids, aromatic organic acids, saturated mono- or multi-functional organic acids, unsaturated mono- or multi-functional organic acids, multi-unsaturated mono- or multi-functional organic acids, stearic acid, behenic acid, erucic acid, oleic acid, linoleic acid, linolenic acid or dimerized derivatives thereof.
12. The method of claim 9 , wherein the soaking step is performed at a soaking temperature of from about 20° C. to about 100° C.
13. The method of claim 9 , wherein the soaked polymeric composition comprises the organic acid and acid copolymer composition in a weight ratio of about 2:3.