Flame retardant polycarbonate compositions, methods of manufacture, and articles formed therefrom
View Patent ↗A composition comprising: a first polycarbonate comprising a poly(siloxane-carbonate); a second polycarbonate different from the first polycarbonate; and optionally, a third polycarbonate different from the first and second polycarbonate; wherein the first polycarbonate is present in an amount effective to provide the siloxane units of in the first polycarbonate in an amount of at least 0.3 wt %, and the second polycarbonate is present in an amount effective to provide the bromine of the second polycarbonate in an amount of at least 7.8 wt %; and further wherein an article molded from the composition has an OSU integrated 2 minute heat release test value of less than 65 kW-min/m 2 and a peak heat release rate of less than 65 kW/m 2 , and an E662 smoke test Dmax value of less than 200.
1. A composition comprising:
a first polycarbonate comprising a poly(siloxane-carbonate) derived from at least one dihydroxy aromatic compound of formula (5)
and at least one polysiloxane bisphenol of formula (1) or formula (2)
wherein
each of R a and R b is independently a halogen atom or a monovalent hydrocarbon group,
p and q are each independently integers of 0 to 4,
X a represents a single bond or one of the groups of formulas (6) or (7),
wherein each R c and R d is independently hydrogen, C 1-12 alkyl, C 1-12 cycloalkyl, C 7-12 arylalkyl, C 1-12 heteroalkyl, or cyclic C 7-12 heteroarylalkyl, and R e is a divalent C 1-12 hydrocarbon group,
R is each independently a C 1 -C 30 hydrocarbon group,
R 2 is each independently a C 7 -C 30 hydrocarbon group,
Ar is a C 6 -C 30 aromatic group, and
E has an average value of 5 to 200;
a second polycarbonate different from the first polycarbonate, the second polycarbonate comprising
brominated carbonate units derived from 2,2′,6,6′-tetrabromo-4,4′-isopropylidenediphenol and
carbonate units derived from at least one dihydroxy aromatic compound that is not 2,2′,6,6′-tetrabromo-4,4′-isopropylidenediphenol; and
optionally, a third polycarbonate different from the first and second polycarbonate;
wherein the composition is free of copolymers comprising carbonate units and ester units; and wherein
the wt % of the first polycarbonate, second polycarbonate, and optional third polycarbonate sum to 100 wt %,
the first polycarbonate is present in an amount effective to provide the siloxane units in an amount of at least 0.3 wt %, based on the sum of the wt % of the first, second, and optional third polycarbonate, and
the second polycarbonate is present in an amount effective to provide the bromine of the second polycarbonate in an amount of at least 7.8 wt %, based on the sum of the wt % of the first, second, and optional third polycarbonate; and
further wherein an article molded from the composition has
an OSU integrated 2 minute heat release test value of less than 65 kW-min/m 2 and a peak heat release rate of less than 65 kW/m 2 as measured using the method of FAR F25.4, in accordance with Federal Aviation Regulation FAR 25.853 (d), and
an E662 smoke test Dmax value of less than 200 when measured at a thickness of 1.6 mm.
2. The composition of claim 1 , wherein the first polycarbonate is present in an amount of at least 10 wt %, and the second polycarbonate is present in an amount of at least 20 wt %, each based on the sum of the wt % of the first, second, and optional third polycarbonate.
3. The composition of claim 1 , wherein
E in formula (1) and formula (2) has an average value of 25 to 75,
the siloxane units of the first polycarbonate are present in an amount of at least 2.0 wt %, based on the sum of the wt % of the first, second, and optional third polycarbonate, and
an article molded from the composition further has a room temperature notched Izod impact of greater than 500 J/m as measured according to ASTM D 256-10 at a 0.125 inch (3.2 mm) thickness.
4. The composition of claim 3 wherein the first polycarbonate is derived from bisphenol A and formula 2 and wherein formula 2 has the formula
wherein
E has an average value of between 40 to 50, and
the siloxane units of the first polycarbonate are present in an amount of 2 to 30 wt % based on the total weight of the first polycarbonate.
5. The composition of claim 1 , wherein
E in formula 1 and formula 2 has an average value of 25 to 50,
the siloxane units of the first polycarbonate are present in an amount of at least 2.0 wt %, based on the sum of the wt % of the first, second, and optional third polycarbonate,
the second polycarbonate is present in an amount of 35 to 50 wt %, based on the sum of the wt % of the first, second, and optional third polycarbonate, and
an article molded from the composition further has a haze less of less than 10% and a transmission greater than 70%, each measured using the color space CIE1931 (Illuminant C and a 2° observer) at a 0.125 inch (3.2 mm) thickness.
6. The composition of claim 5 wherein the first polycarbonate is derived from bisphenol A and formula 2 and wherein formula 2 has the formula
wherein
E has an average value of between 40 to 50, and
the siloxane units of the first polycarbonate are present in an amount of 4 to 8 wt % based on the total weight of the first polycarbonate.
7. An article selected from a molded article, a thermoformed article, an extruded film, an extruded sheet, one or more layers of a multi-layer article, a substrate for a coated article or a substrate for a metallized article made from the composition of claim 5 .
8. The article of claim 7 , wherein the article is selected from a balcony component, baluster, ceiling panel, cover for a life vest, cover for a storage bin, dust cover for a window, layer of an electrochromic device, lens for a television, electronic display, gauge, instrument panel, light cover, light diffuser, light tube, light pipes, mirror, partition, railing, refrigerator door, shower door, sink bowl, trolley cart container, trolley cart side panel, or window.
9. The composition of claim 1 , wherein the polysiloxane bisphenol (1) has the formula:
10. The composition of claim 1 , wherein the polysiloxane bisphenol (2) has the formula:
11. The composition of claim 10 wherein the dihydroxy aromatic compound of the first polycarbonate is Bisphenol-A.
12. The composition of claim 1 , wherein
the siloxane units of the first polycarbonate are present in an amount of between 1.5 and 3.5 wt % based on the sum of the wt % of the first, second, and third polycarbonate,
the bromine of the second polycarbonate is present in an amount of between 7.8 and 13 wt % based on the sum of the wt % of the first, second, and third polycarbonate; and
the third polycarbonate is present in an amount of 8 to 50 wt % based on the sum of the first, second, and third polycarbonate.
13. The composition of claim 1 , wherein the at least one dihydroxy aromatic compound of the second polycarbonate is Bisphenol-A.
14. The composition of claim 13 , wherein the second polycarbonate comprises 25 to 35 mol % of units derived from 2,2′6,6′ tetrabromo-4,4′-isopropylidenediphenol and 65 to 75 mole % of units derived from Bisphenol-A.
15. The composition of claim 1 wherein the first polycarbonate is derived from bisphenol A and formula 2 and wherein formula 2 has the formula
wherein
E has an average value of 8 to 100,
the siloxane units of the first polycarbonate are present in an amount of 0.5 to 25 wt % based on the total weight of the first polycarbonate.
16. The composition of claim 1 , wherein the composition has a density of less than 1.31 g/cc.
17. The composition of claim 16 , wherein the composition has a density of less than 1.30 g/cc.
18. The composition of claim 1 , wherein the E662 smoke test Dmax has a value of less than 100 when tested at a thickness of 1.6 mm.
19. The composition of claim 1 , wherein an article molded from the composition has a room temperature notched Izod impact of greater than 500 J/m as measured according to ASTM D 256-10 at a 3.2 mm thickness.
20. The composition of claim 19 , wherein the E662 smoke test Dmax has a value of less than 100 when tested at a thickness of 1.6 mm.
21. The composition of claim 1 , wherein an article molded from the composition has a haze less of less than 15% and a transmission greater than 75%, each measured using the color space CIE1931 (Illuminant C and a 2° observer) at a 3.2 mm thickness.
22. The composition of claim 21 , wherein an article molded from the composition has a room temperature notched Izod impact of greater than 500 J/m as measured according to ASTM D 256-10 at a 3.2 mm thickness.
23. The composition of claim 1 , further comprising 0.5 to 3 parts by weight of titanium dioxide per hundred parts by weight of the combination of the wt % of the first, second, and optional third polycarbonate.
24. The composition of claim 1 , wherein the composition is substantially free of a fluorinated polyolefin encapsulated by poly(styrene-acrylonitrile).
25. The composition of claim 1 , further comprising an additional polymer comprising bromine, wherein the additional polymer is not the same as the first polycarbonate, the second polycarbonate, or the optional third polycarbonate; and wherein the additional polymer is present at 0.01 to 25 parts per hundred parts by weight of the combination of the first polycarbonate, the second polycarbonate, and the optional third polycarbonate.
26. An article selected from a molded article, a thermoformed article, a foamed article, an extruded film, an extruded sheet, one or more layers of a multi-layer article, a substrate for a coated article or a substrate for a metallized article made from the composition of claim 1 .
27. The article of claim 26 , wherein the article is a component of an aircraft interior or a train interior.
28. The article of claim 27 , wherein the article is selected from an access panel, access door, air flow regulator, air gasper, air grille, arm rest, baggage storage door, balcony component, cabinet wall, ceiling panel, door pull, door handle, duct housing, enclosure for an electronic device, equipment housing, equipment panel, floor panel, food cart, food tray, galley surface, handle, housing for television, light panel, magazine rack, telephone housing, partition, part for trolley cart, seat back, seat component, railing component, seat housing, shelve, side wall, speaker housing, storage compartment, storage housing, toilet seat, tray table, tray, trim panel, window molding, window slide, or window.
29. The composition of claim 1 , wherein the first polycarbonate is a blend of a first poly(siloxane-carbonate) and a second poly(siloxane-carbonate) different from the first poly(siloxane-carbonate), wherein the first and the second poly(siloxane-carbonate)s are independently derived from at least one dihydroxy aromatic compound of formula (5) and at least one polysiloxane bisphenol of formula (1) or formula (2).
30. The composition of claim 1 , wherein the third polycarbonate is a homopolymer with bisphenol A carbonate units.
31. A composition comprising:
a first polycarbonate comprising a poly(siloxane-carbonate) derived from at least one dihydroxy aromatic compound of formula (5)
and at least one polysiloxane bisphenol of formula (1) or formula (2)
where
each of R a and R b is independently a halogen atom or a monovalent hydrocarbon group,
p and q are each independently integers of 0 to 4,
X a represents a single bond or one of the groups of formulas (6) or (7),
wherein each R c and R d is independently hydrogen, C 1-12 alkyl, C 1-12 cycloalkyl, C 7-12 arylalkyl, C 1-12 heteroalkyl, or cyclic C 7-12 heteroarylalkyl, and R e is a divalent C 1-12 hydrocarbon group,
R is each independently a C 1 -C 30 hydrocarbon group,
Ar is a C 6 -C 30 aromatic group, and
R 2 is each independently a C 7 -C 30 hydrocarbon group, and
E has an average value of 5 to 75;
a second polycarbonate different from the first polycarbonate, the second polycarbonate comprising
brominated carbonate units derived from 2,2′,6,6′-tetrabromo-4,4′-isopropylidenediphenol and
carbonate units derived from at least one dihydroxy aromatic compound that is not 2,2′,6,6′-tetrabromo-4,4′-isopropylidenediphenol; and
optionally, a third polycarbonate different from the first and second polycarbonate;
wherein the composition is free of copolymers comprising carbonate units and ester units; and
wherein
the wt % of the first polycarbonate, second polycarbonate, and optional third polycarbonate sum to 100 wt %,
the first polycarbonate is present in an amount effective to provide the siloxane units of the first polycarbonate in an amount of at least 0.3 wt %, based on the sum of the wt % of the first, second, and optional third polycarbonate, and
the second polycarbonate is present in an amount effective to provide bromine in the second polycarbonate in an amount of at least 5.0 wt %, based on the sum of the wt % of the first, second, and optional third polycarbonate; and
further wherein an article molded from the composition has
an OSU integrated 2 minute heat release test value of less than 65 kW-min/m 2 and a peak heat release rate of less than 65 kW/m 2 as measured using the method of FAR F25.4, in accordance with Federal Aviation Regulation FAR 25.853 (d),
an E662 smoke test Dmax value of less than 200 when tested at a thickness of 1.6 mm; and
a haze less of less than 3% and a transmission greater than 85%, each measured using the color space CIE1931 (Illuminant C and a 2° observer) at a 1.5 mm thickness.
32. The composition of claim 31 , wherein the first polycarbonate is present in an amount of at least 30 wt %, and the second polycarbonate is present in an amount of at least 20 wt %, each based on the sum of the wt % of the first, second, and optional third polycarbonate.
33. The composition of claim 31 wherein the first polycarbonate is derived from bisphenol A and formula 2 and wherein formula 2 has the formula
wherein
E has an average value of 8 to 12, and
the siloxane units of the first polycarbonate are present in an amount of 0.5 to 7 wt % based on the total weight of the first polycarbonate.
34. The composition of claim 31 , wherein the third polycarbonate is a homopolymer with bisphenol A carbonate units.