Ceramic glaze having antimicrobial property
View Patent ↗An antimicrobial ceramic glazing composition contains one or more antimicrobial agents disposed therein. Methods for making and using the glazing composition are disclosed, as well as substrates having a fired antimicrobial glaze thereon. The antimicrobial agents comprise metallic oxides, with a subset of the disclosed combinations exhibiting synergistic effect in fired glazes.
1. An antimicrobial ceramic glazing composition, comprising:
a ceramic glaze base adapted to be fired at a firing temperature of from at least about 1062° C.; and
a synergistic antimicrobial composition including a first antimicrobial agent and a second antimicrobial agent, the antimicrobial composition being one of:
2% Ag 2 CO 3 +2% Bi 2 O 3 ,
2% Ag 2 CO 3 +2% CuO,
2% Ag 2 CO 3 +2% SnO 2 ,
2% Ag 2 CO 3 +2% ZnO,
2% Ag 2 CO 3 +4% ZnO,
2% Bi 2 O 3 +2% CuO,
2% Bi 2 O 3 +4% CuO,
2% CuO+4% Ag 2 CO 3 ,
2% CuO+4% SnO 2 ,
2% CuO+2% TiO 2 ,
2% CuO+4% TiO 2 ,
2% CuO+4% ZnO,
2% SnO 2 +4% Ag 2 CO 3 ,
2% SnO 2 +4% CuO,
2% TiO 2 +4% Ag 2 CO 3 ,
2% TiO 2 +4% CuO,
2% ZnO+4% Ag 2 CO 3 , or
2% ZnO+4% CuO;
wherein percentages are based on weight, and
wherein the glazing composition is adapted to possess an antimicrobial property after a conventional firing process at the firing temperature.
2. The antimicrobial ceramic glazing composition of claim 1 wherein the synergistic antimicrobial combination is 2% Ag 2 CO 3 +2% ZnO.
3. A glazed ceramic substrate, comprising:
a ceramic substrate having a first substrate surface; and
a fired synergistic antimicrobial composition disposed on the first substrate surface;
wherein the synergistic antimicrobial composition is a post-fired state of a ceramic glazing composition including one of:
2% Ag 2 CO 3 +2% Bi 2 O 3 ,
2% Ag 2 CO 3 +2% CuO,
2% Ag 2 CO 3 +2% SnO 2 ,
2% Ag 2 CO 3 +2% ZnO,
2% Ag 2 CO 3 +4% ZnO,
2% Bi 2 O 3 +2% CuO,
2% Bi 2 O 3 +4% CuO,
2% CuO+4% Ag 2 CO 3 ,
2% CuO+4% SnO 2 ,
2% CuO+2% TiO 2 ,
2% CuO+4% TiO 2 ,
2% CuO+4% ZnO,
2% SnO 2 +4% Ag 2 CO 3 ,
2% SnO 2 +4% CuO,
2% TiO 2 +4% Ag 2 CO 3 ,
2% TiO 2 +4% CuO,
2% ZnO+4% Ag 2 CO 3 , or
2% ZnO+4% CuO,
wherein percentages are based on weight.