IP Library Patent Application 13934316
Patent Application
App. No. 13/934,316

Mutual Solvent for Downhole Use

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Quick Facts
Patent No.
US None
App. No.
13/934,316
Abstract

A mutual solvent for use in oil and gas well operations comprising an ethoxylated alcohol surfactant, having a six carbon backbone chained to three ethylene oxide groups with a hydrophilic lipophilic balance between 11 and 12 but more preferably of about 11.3. Such a mutual solvent may be used in an oil and gas well as a spacer system, in acid treatments to remove the spent acid, and in solvent systems to remove asphaltenic or paraffinic compounds.

Claims (44)

1 . A chemical for use in oil and gas well operations comprising:

an ethoxylated alcohol surfactant, having a hydrophilic lipophilic balance between 11 and 12;

wherein the ethoxylated alcohol surfactant is used as a mutual solvent.

2 . The chemical for use in an oil and gas well operations of claim one 1 wherein the ethoxylated alcohol surfactant has a hydrophilic lipophilic balance of about 11.3.

3 . The chemical for use in an oil and gas well operations of claim one 1 wherein the ethoxylated alcohol surfactant has a six carbon backbone chained to three ethylene oxide groups.

4 . An acid system comprising:

an acid, and

a mutual solvent,

wherein the mutual solvent is an ethoxylated alcohol surfactant having a hydrophilic lipophilic balance between 11 and 12.

5 . The acid system of claim 4 wherein the ethoxylated alcohol surfactant has a hydrophilic lipophilic balance of about 11.3.

6 . The acid system of claim 4 where the ethoxylated alcohol surfactant has a six carbon backbone chained to three ethylene oxide groups.

7 . The acid system of claim 4 wherein the acid is hydrochloric acid.

8 . The acid system claim 4 wherein the mutual solvent is present in an amount from about 0.1 pounds per barrel to about 70 pounds per barrel.

9 . The acid system claim 4 wherein the mutual solvent is present in an amount from about 1.0 pounds per barrel to about 25 pounds per barrel.

10 . The acid system claim 4 wherein the mutual solvent is present in an amount from about 2.0 pounds per barrel to about 7 pounds per barrel.

11 . A spacer system for use in a wellbore comprising:

a water;

a water-soluble viscosifier:

a weighting agent;

a water wetting agent;

a sulfonic acid surfactant;

and a mutual solvent;

wherein the mutual solvent is an ethoxylated alcohol having a hydrophilic lipophilic balance between 11 and 12.

12 . The spacer system of claim 11 wherein the ethoxylated alcohol has a hydrophilic lipophilic balance of about 11.3.

13 . The spacer system of claim 11 wherein the ethoxylated alcohol has a six carbon backbone chained to three ethylene oxide groups,

14 . The spacer system of claim 11 wherein the water-soluble viscosifier is a polysaccharide.

15 . The spacer system of claim 11 wherein the water-soluble viscosifier is a polysaccharide derivative.

16 . The spacer system of claim 11 wherein the water-soluble viscosifier is a synthetic polymer.

17 . The spacer system of claim 11 wherein the water-soluble viscosifier is hydroxyethyl cellulose.

18 . The spacer system of claim 11 wherein the weighting agent is barite.

19 . The spacer system of claim 11 wherein the water wetting agent is tridecyl alcohol with six ethylene oxide groups.

20 . The spacer system of claim 11 wherein the sulfonic acid surfactant is neutralized dodecyl benzene sulfonic acid.

21 . The spacer system of claim 11 wherein the mutual solvent is present in an amount from about 0.1 pounds per barrel to about 70 pounds per barrel.

22 . The spacer system of claim 11 wherein the mutual solvent is present in an amount from about 1 pound per barrel to about 25 pounds per barrel.

23 . The spacer system of claim 11 wherein the mutual solvent is present in an amount from about 2 pounds per barrel to about 7 pounds per barrel.

24 . The spacer system of claim 11 wherein the viscosifying agent is present in an amount from about 0.01 pounds per barrel to about 10 pounds per barrel.

25 . The spacer system of claim 11 where the viscosifying agent is present in an amount from about 0.5 pounds per barrel to about 7 pounds per barrel.

26 . The spacer system of claim 11 wherein the viscosifying agent is present in an amount from about 1 pound per barrel to about 3 pounds per barrel.

27 . The spacer system of claim 11 wherein the water wetting agent is present in an amount from about 0.1 pounds per barrel to about 25 pounds per barrel.

28 . The spacer system of claim 11 wherein the water welting agent is present in an amount from about 0.5 pounds per barrel to about 5 pounds per barrel.

29 . The spacer system of claim 11 wherein the water wetting agent is present in an amount from about 1 pound per barrel to about 3.5 pounds per barrel.

30 . The spacer system of claim 11 wherein the sulfonic acid surfactant is present in an amount from about 0.1 pounds per barrel to about 25 pounds per barrel.

31 . The spacer system of claim 11 wherein the sulfonic acid surfactant is present in an amount from about 0.5 pounds per barrel to about 5 pounds per barrel.

32 . The spacer system of claim 11 wherein the sulfonic acid surfactant is present in an amount from about 1 pound per barrel to about 3.5 pounds per barrel.

Assignments (2)
SECURITY INTEREST Recorded Jan 13, 2016
From: TRICAN WELL SERVICE LTD.
To: COMPUTERSHARE TRUST COMPANY OF CANADA
Reel/Frame 037482/0702 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 25, 2013
From: KAKADJIAN, SARKIS; HUBER, STEPHEN; RAMOS, VIOLETA; ZAMORA, FRANK
To: TRICAN WELL SERVICE, LTD.
Reel/Frame 031076/0859 →