Polycrystalline compacts including crushed diamond nanoparticles, cutting elements and earth boring tools including such compacts, and methods of forming same
View Patent ↗A polycrystalline compact comprises a plurality of diamond grains of micron size, submicron size, or both, and a plurality of crushed diamond nanoparticles disposed in interstitial spaces between the plurality of diamond grains. A method of forming a polycrystalline compact comprises combining a plurality of micron and/or submicron-sized diamond grains and a plurality of crushed diamond nanoparticles to form a mixture and sintering the mixture in a presence of a binder to form a polycrystalline hard material comprising a plurality of inter-bonded diamond grains and diamond nanoparticles. Cutting elements comprising a polycrystalline compact and earth-boring tools bearing such compacts are also disclosed.
1. A method of fabricating a cutting element, comprising:
crushing diamond grains to form crushed diamond nanoparticles consisting essentially of diamond carbon, the crushed diamond nanoparticles having an average particle diameter of about 500 nm or less;
after crushing the diamond grains to form the crushed diamond nanoparticles, mixing the crushed diamond nanoparticles with micron-sized diamond grains having an average particle diameter of about 1 μm to about 250 μm and encapsulating the crushed diamond nanoparticles with the micron-sized diamond grains in a canister; and
subjecting the crushed diamond nanoparticles and micron-sized diamond grains to a pressure of at least 5.0 GPa and a temperature of at least 1000° C. in the presence of a binder to form a polycrystalline diamond compact having inter-granular bonds between the micron-sized diamond grains and the crushed diamond nanoparticles.
2. The method of claim 1 , wherein encapsulating the crushed diamond nanoparticles with the micron-sized diamond grains in a canister comprises mixing the binder with the crushed diamond nanoparticles with the micron-sized diamond grains in the canister.
3. The method of claim 1 , further comprising at least partially filling a volume between the micron-sized diamond grains with the binder.
4. The method of claim 1 , wherein encapsulating the crushed diamond nanoparticles with the micron-sized diamond grains in a canister comprises encapsulating crushed diamond nanoparticles having an average particle diameter from about 5 nm to about 150 nm with the micron-sized diamond grains in the canister.
5. The method of claim 1 , wherein encapsulating the crushed diamond nanoparticles with the micron-sized diamond grains in a canister comprises encapsulating the micron-sized diamond grains with a plurality of single-crystal crushed diamond nanoparticles in the canister.
6. The method of claim 1 , wherein encapsulating the crushed diamond nanoparticles with the micron-sized diamond grains in a canister comprises encapsulating the micron-sized diamond grains with functionalized crushed diamond nanoparticles in the canister.
7. The method of claim 1 , further comprising leaching at least a portion of the binder from the polycrystalline diamond compact.
8. The method of claim 1 , wherein subjecting the crushed diamond nanoparticles and micron-sized diamond grains in the presence of a binder to a pressure of at least 5.0 GPa and a temperature of at least 1000° C. comprises forming inter-granular bonds between the micron-sized diamond grains and the crushed diamond nanoparticles without consuming the crushed diamond nanoparticles.
9. The method of claim 1 , further comprising providing the polycrystalline diamond compact on a support substrate.
10. The method of claim 1 , further comprising after crushing the diamond grains to form the crushed diamond nanoparticles, mixing the crushed diamond nanoparticles and the micron-sized diamond grains with submicron-sized diamond particles having an average particle diameter from about 500 nm to about 1 μm and encapsulating the crushed diamond nanoparticles, the micron-sized diamond grains, and the submicron-sized diamond particles in the canister.
11. A method of fabricating a cutting element, comprising:
mixing previously crushed diamond nanoparticles with micron-sized diamond grains to form a particulate mixture, the previously crushed diamond nanoparticles consisting essentially of diamond carbon and having an average particle diameter of about 500 nm or less before mixing, the micron-sized diamond grains having an average particle diameter of about 1 μm to about 250 μm before mixing;
encapsulating the particulate mixture in a canister such that the micron-sized diamond grains have a packing fraction from about 80% to about 99% with a void space defined by the micron-sized diamond grains, and wherein the previously crushed diamond nanoparticles substantially fill the void space defined by the micron-sized diamond grains;
subjecting the particulate mixture to a pressure of at least 5.0 GPa and a temperature of at least 1000° C. in the presence of a binder to form a polycrystalline diamond compact having inter-granular bonds between the micron-sized diamond grains and the previously crushed diamond nanoparticles; and
providing the polycrystalline diamond compact on a support substrate.
12. The method of claim 11 , further comprising mixing the binder with the micron-sized diamond grains and the previously crushed diamond nanoparticles.
13. The method of claim 11 , further comprising at least partially filling a volume between the micron-sized diamond grains with the binder.
14. The method of claim 11 , wherein the previously crushed diamond nanoparticles have an average particle diameter from about 5 nm to about 150 nm before mixing.
15. The method of claim 11 , wherein the previously crushed diamond nanoparticles comprise a plurality of single-crystal previously crushed diamond nanoparticles before mixing.
16. The method of claim 11 , wherein the previously crushed diamond nanoparticles comprise functionalized previously crushed diamond nanoparticles before mixing.
17. The method of claim 11 , further comprising leaching at least a portion of the binder from the polycrystalline diamond compact.
18. The method of claim 11 , wherein subjecting the particulate mixture to a pressure of at least 5.0 GPa and a temperature of at least 1000° C. in the presence of a binder comprises forming inter-granular bonds between the micron-sized diamond grains and the previously crushed diamond nanoparticles without consuming the previously crushed diamond nanoparticles.