IP Library Granted Patent US 9,899,606
Granted Patent B2
US 9,899,606 · App. 13/939,881 · Granted Feb 20, 2018

Composition for organic electroluminescent element, organic electroluminescent element, display and lighting

Inventors: Hideki Gorohmaru (Kanagawa, JP); Tomomi Okamoto (Kanagawa, JP); Wataru Shimizu (Kanagawa, JP); Kazuhiro Nagayama (Kanagawa, JP); Takashi Oya (Kanagawa, JP); Koichi Ishibashi (Kanagawa, JP); Ichiro Imada (Kanagawa, JP)
Assignee: MITSUBISHI CHEMICAL CORPORATION
H01L51/0072C09B1/00C09B3/02C09B57/00C09B57/001C09B57/008C09K11/06H01L27/3244H01L51/0004H01L51/006H01L51/0052H01L51/0054H01L51/0058H01L51/0061H01L51/0067H01L51/0073H01L51/0085H01L51/5024C09K2211/1007C09K2211/1011C09K2211/1014C09K2211/1029C09K2211/1044C09K2211/1059C09K2211/1088H01L51/005H01L51/5012H01L2251/5384
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Quick Facts
Patent No.
US 9,899,606
App. No.
13/939,881
Granted
Feb 20, 2018
Kind
B2
Abstract

The invention relates to a composition for organic electroluminescent element, which comprises: a solvent; and a compound group α for organic electroluminescent element that is constituted of at least two kinds of compounds which each have a molecular weight of 3,000 or less and have a structure comprising a plurality of aromatic ring groups linked to each other, wherein the compound group α comprises: a compound α1; and another compound αn satisfying a specific condition.

Claims (27)

1. A composition comprising a compound group α for organic electroluminescent element and a solvent, wherein:

the compound group α is constituted of at least two kinds of compounds which each have a molecular weight of 3,000 or less and have a structure comprising a plurality of aromatic ring groups linked to each other;

the compound group α comprises a first compound α1, which is the smallest in the number of aromatic ring groups, a second compound α2, optionally a third compound α3, and optionally a fourth compound α4;

when a structure which is the largest in the number of the aromatic ring groups, of partial structures that are common between the compound α1 and the compounds α2, α3, and α4, is taken as a basic framework, 60% or more of the structure of the compound α1 is identical with the basic framework;

the compounds which constitute the compound group α each is mixed in an amount of 1% by weight or larger; and

each of the compounds included in the compound group α is any of the compounds represented by formulae (A-5) and (A-6):

wherein R 20 to R 53 each independently represent a hydrogen atom, a nitrogen atom, an oxygen atom, a sulfur atom, an aromatic hydrocarbon ring group which has 6-30 carbon atoms and may have a substituent, or a heteroaromatic ring group which has 3-30 carbon atoms and may have a substituent, with the proviso that when R 20 to R 53 each are a nitrogen atom, an oxygen atom, or a sulfur atom, this atom combines with part of an adjoining substituent to form a ring.

2. The composition of claim 1 , wherein the proportion of the compound group α to all solid components of the composition is 0.1-100% by weight.

3. The composition of claim 1 , wherein the proportion of the solvent in the composition is 10% by weight or higher.

4. The composition of claim 1 , wherein the compounds included in the compound group α each are a charge transport material.

5. The composition of claim 1 , wherein the compounds included in the compound group α are represented by only one formula selected from the group consisting of formulae (A-5) and (A-6).

6. An organic electroluminescent element, comprising:

an anode;

a cathode; and

at least one organic layer interposed between the anode and the cathode,

wherein at least one of the organic layer(s) is a layer formed using the composition for organic electroluminescent element of claim 1 .

7. The organic electroluminescent element of claim 6 , wherein the layer formed using the composition for organic electroluminescent element is an emissive layer.

8. A display, comprising the organic electroluminescent element of claim 6 .

9. A lighting, comprising:

the organic electroluminescent element of claim 6 .

10. A composition comprising a compound group α for organic electroluminescent element and a solvent, wherein;

the compound group α is constituted of at least two kinds of compounds which each have a molecular weight of 3,000 or less and have a structure comprising a plurality of aromatic ring groups linked to each other;

the compound group α comprises a first compound α1, which is the smallest in the number of aromatic ring groups, a second compound α2, and optionally a third compound α3;

when a structure which is the largest in the number of the aromatic ring groups, of partial structures that are common between the compound α1 and the compounds α2 and α3, is taken as a basic framework, 60% or more of the structure of the compound α1 is identical with the basic framework;

the compounds which constitute the compound group α each is mixed in an amount of 1% by weight or larger; and

each of the compounds included in the compound group α is any of the compounds represented by formulae (A-5) and (A-6):

wherein R 20 to R 53 each independently represent a hydrogen atom, a nitrogen atom, an oxygen atom, a sulfur atom, an aromatic hydrocarbon ring group which has 6-30 carbon atoms and may have a substituent, or a heteroaromatic ring group which has 3-30 carbon atoms and may have a substituent, with the proviso that when R 20 to R 53 each are a nitrogen atom, an oxygen atom, or a sulfur atom, this atom combines with part of an adjoining substituent to form a ring.

Assignments (3)
CHANGE OF NAME Recorded Sep 5, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043750/0834 →
MERGER Recorded Sep 4, 2017
From: MITSUBISHI CHEMICAL CORPORATION
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 043750/0207 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 12, 2013
From: GOROHMARU, HIDEKI; OKAMOTO, TOMOMI; SHIMIZU, WATARU; NAGAYAMA, KAZUHIRO; OYA, TAKASHI; ISHIBASHI, KOICHI; IMADA, ICHIRO
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 030783/0930 →
Priority Claims (1)
JP 2011-003081 · Jan 11, 2011 · national
Continuity (2)
Continuation PCTJP2012050288 · Jan 10, 2012
Related Publication 20160043325A1 · Feb 11, 2016