Glycerol levulinate ketals and their use in the manufacture of polyurethanes, and polyurethanes formed therefrom
The present disclosure relates to the preparation of ketal compounds from glycerol and levulinic acid and esters, and uses thereof, in particular the manufacture of polyurethanes.
1. A plasticizer composition comprising:
i) a first plasticizer having the formula:
wherein R 3 is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, or alkyloxyalkyl, and R 6 is hydrogen, or is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, alkyloxyalkyl, or oxoalkyl; and
ii) a second plasticizer selected from aromatic dicarboxylic esters, aliphatic dicarboxylic esters, epoxidized triglycerides, or a combination thereof.
2. The plasticizer composition of claim 1 , wherein R 3 and R 6 are each independently selected from linear or branched alkyls having between 1 and 23 carbons.
3. The plasticizer composition of claim 1 , wherein R 3 and R 6 are each independently selected from linear or branched alkyls having between 1 and 12 carbons.
4. A polymer composition comprising:
i) a base polymer; and
ii) a plasticizer composition comprising:
1) a first plasticizer having the formula:
wherein R 3 is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, or alkyloxyalkyl, and R 6 is hydrogen, or is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, alkyloxyalkyl, or oxoalkyl; and
2) a second plasticizer selected from aromatic dicarboxylic esters, aliphatic dicarboxylic esters, epoxidized triglycerides, or a combination thereof.
5. The polymer composition of claim 4 , wherein the base polymer is selected from vinyl chloride polymer, poly(3-hydroxyalkanoate) polymer, poly(lactate) polymer, or polysaccharide polymer.
6. The polymer composition of claim 4 , wherein R 3 and R 6 are each independently selected from linear or branched alkyls having between 1 and 23 carbons.
7. The polymer composition of claim 4 , wherein R 3 and R 6 are each independently selected from linear or branched alkyls having between 1 and 12 carbons.
8. The polymer composition of claim 4 , wherein the base polymer is a vinyl chloride polymer.
9. The polymer composition of claim 4 , wherein the first plasticizer having the formula:
comprises between 5 and 80% by weight of the polymer composition.
10. The polymer composition of claim 9 , wherein the plasticizer having the formula:
comprises between 5 and 25% by weight of the polymer composition.
11. The polymer composition of claim 4 , wherein the base polymer comprises poly(vinyl chloride) homopolymer or copolymer, a poly(3-hydroxyalkanoate) homopolymer or copolymer, poly(3-hydroxybutyrate), poly(lactate), or polysaccharide homopolymer or copolymer.
12. The polymer composition of claim 4 , further comprising one or more additives comprising a stabilizer, an inorganic or organic filler, reinforcing fibers, pigments, and dyes.
13. The polymer composition of claim 4 , wherein the composition is cast, molded, or extruded into a shape.
14. The polymer composition of claim 13 , wherein the shape comprises film, fiber, tubing, or pipe.
15. A fragrance formulation comprising:
i) a fragrance; and
ii) a compound having the formula:
wherein R 3 is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, or alkyloxyalkyl, and R 6 is hydrogen, or is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, alkyloxyalkyl, or oxoalkyl.
16. The fragrance formulation of claim 15 , wherein R 3 and R 6 are each independently selected from linear or branched alkyls having between 1 and 23 carbons.
17. The fragrance formulation of claim 15 , wherein R 3 and R 6 are each independently selected from linear or branched alkyls having between 1 and 12 carbons.
18. A biologically active formulation comprising:
i) a biologically active agent; and
ii) a compound having the formula:
wherein R 3 is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, or alkyloxyalkyl, and R 6 is hydrogen, or is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, alkyloxyalkyl, or oxoalkyl.
19. The biologically active formulation of claim 18 , wherein R 3 and R 6 are each independently selected from linear or branched alkyls having between 1 and 23carbons.
20. The biologically active formulation of claim 18 , wherein R 3 and R 6 are each independently selected from linear or branched alkyls having between 1 and 12carbons.
21. A plasticizer composition comprising:
i) a first plasticizer having the formula:
wherein R 3 is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, or alkyloxyalkyl, and R 6 is hydrogen, or is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, alkyloxyalkyl, or oxoalkyl; and
ii) a second plasticizer different from the first plasticizer.
22. A polymer composition comprising:
i) a base polymer; and
ii) a plasticizer composition comprising:
1) a first plasticizer having the formula:
wherein R 3 is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, or alkyloxyalkyl, and R 6 is hydrogen, or is a linear, branched, or cyclic alkyl or alkenyl, aryl, aralkyl, alkyloxyalkyl, or oxoalkyl; and
2) a second plasticizer different from the first plasticizer.