Electrode material for a spark plug
View Patent ↗An electrode material for use with spark plugs and other ignition devices. The electrode material is a two-phase composite material that includes a matrix component and a dispersed component embedded in the matrix component. In a preferred embodiment, the matrix component is a precious-metal based material and the dispersed component includes a material that exhibits a high melting point and a low work function such as, for example, carbides, nitrides, and/or intermetallics. A process for forming the electrode material into a spark plug electrode is also provided.
1. A spark plug, comprising: a metallic shell having an axial bore; an insulator having an axial bore and being at least partially disposed within the axial bore of the metallic shell; a center electrode being at least partially disposed within the axial bore of the insulator; and a ground electrode being attached to a free end of the metallic shell; the center electrode, the ground electrode or both includes an electrode material that has a multi-phase composite material with a matrix component and a dispersed component, wherein the matrix component includes at least one precious metal, a transition metal, and a rare earth metal, and the dispersed component is an intermetallic embedded in the matrix component, and wherein the matrix component includes about 0.001 wt % to 0.3 wt % of the rare earth metal.
2. The spark plug of claim 1 , wherein the matrix component includes about 90 wt % to 99.9 wt % of the at least one precious metal.
3. The spark plug of claim 1 , wherein the matrix component includes at least one precious metal selected from the group consisting of: platinum (Pt), Iridium (Ir), palladium (Pd), rhodium (Rh) or ruthenium (Ru).
4. The spark plug of claim 3 , wherein the matrix is a platinum-based alloy and is selected from the group consisting of: Pt—Ni, Pt—W, Pt—Ir or Pt—Pd.
5. The spark plug of claim 1 , wherein the matrix component includes about 0.1 wt % to 10 wt % of the transition metal.
6. The spark plug of claim 1 , wherein the matrix component includes at least one transition metal selected from the group consisting of: rhenium (Re), tungsten (W), tantalum (Ta), molybdenum (Mo) or niobium (Nb).
7. The spark plug of claim 1 , wherein the multi-phase composite material includes about 70 vol % to about 99.9 vol % of the matrix component and about 0.1 vol % to about 30 vol % of the dispersed component.
8. The spark plug of claim 1 , wherein the matrix component includes at least one rare earth metal selected from the group consisting of: yttrium (Y), hafnium (Hf), scandium (Sc), lanthanum (La) or cerium (Ce).
9. The spark plug of claim 1 , wherein the dispersed component includes at least one intermetallic selected from the group consisting of: ruthenium aluminum (RuA 1 ), nickel aluminum (NiAl), platinum aluminum (Pt 3 Al), titanium aluminum (TiAl), iron aluminum (Fe 2 Al 5 ), niobium aluminum (NbAl 3 ), molybdenum silicon (MoSi 2 ), ruthenium titanium (RuTi) or niobium platinum (NbPt 3 ).
10. The spark plug of claim 1 , wherein the dispersed component has a melting point above about 1100° C. and a work function below about 6.0 eV.
11. The spark plug of claim 1 , wherein the dispersed component has a fibrous microstructure with elongated fibers or whiskers that are generally aligned parallel to each other and to grains of the precious metal-based matrix component and have an average diameter of about 20 μm or less.
12. The spark plug of claim 1 , wherein the multi-phase composite material includes at least one of the following matrix component-dispersed component combinations, where the materials are given in weight percentage ranges and Pt constitutes the balance: Pt-(0.1-2.0)RuAl, Pt-(0.1-2.0)MoSi 2 or Pt-(0.1-2.0)RuTi.
13. The spark plug of claim 1 , wherein the center electrode, the ground electrode or both includes a separate firing tip that is made from the multi-phase composite material and is attached to the center electrode, the ground electrode or both via welding.
14. An electrode material for a spark plug, the electrode material comprising:
a multi-phase composite material that includes a matrix component and a separate dispersed component embedded in the matrix component, the matrix component is a precious-metal based alloy that includes a precious metal as the single largest constituent of the matrix component, a transition metal as the second largest constituent of the matrix component, and a rare earth metal as the third largest constituent of the matrix component, and the dispersed component includes at least one of carbides, nitrides, or intermetallics.
15. A spark plug, comprising:
a metallic shell having an axial bore;
an insulator having an axial bore and being at least partially disposed within the axial bore of the metallic shell;
a center electrode being at least partially disposed within the axial bore of the insulator; and
a ground electrode being attached to a free end of the metallic shell;
the center electrode, the ground electrode or both includes an electrode material that has a multi-phase composite material with a matrix component and a dispersed component, wherein the matrix component includes at least one precious metal and the dispersed component includes a carbide or a nitride that is embedded in the matrix component so that the matrix component and the dispersed component are separate materials that exhibit an interface or transitional boundary therebetween.
16. The spark plug of claim 15 , wherein the dispersed component includes at least one carbide selected from the group consisting of: hafnium carbide (HfC), tungsten carbide (WC), zirconium carbide (ZrC), molybdenum carbide (MoC), chromium carbide (Cr 3 C 2 , Cr 7 C 3 , Cr 23 C 6 ), niobium carbide (NbC), tantalum carbide (TaC), vanadium carbide (VC) or titanium carbide (TiC).
17. The spark plug of claim 15 , wherein the dispersed component includes at least one nitride selected from the group consisting of: hafnium nitride (HfN), tungsten nitride (WN), zirconium nitride (ZrN), molybdenum nitride (MoN), chromium nitride (CrN), niobium nitride (NbN), tantalum nitride (TaN), vanadium nitride (VN), titanium nitride (TiN), titanium carbo-nitride (TiCN), titanium aluminum nitride (TiAlN) or titanium aluminum carbo-nitride (TiAlCN).
18. The spark plug of claim 15 , wherein the matrix component includes platinum or a platinum alloy, at least one transition metal, and at least one rare earth metal, and the platinum or the platinum alloy is the single largest constituent of the matrix component.
19. The spark plug of claim 15 , wherein the multi-phase composite material includes at least one of the following matrix component-dispersed component combinations, where the materials are given in weight percentage ranges and Pt constitutes the balance: Pt-(0.1-2.0)HfC, Pt-(0.1-2.0)WC, Pt-(0.1-2.0)NbC, Pt-(0.1-2.0)TaC, Pt-(0.1-2.0)HfN, Pt-(0.1-2.0)NbN, or Pt-(0.1-2.0)TaN.