Mesostructured zeolitic materials, and methods of making and using the same
View Patent ↗One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.
1. A composition comprising:
a biological catalyst selected from the group consisting of enzymes, biomolecules, proteins, supramolecular species, and combinations thereof; and
a crystalline inorganic mesostructured material selected from the group consisting of metal oxides, zeolites, zeotypes, aluminophosphates, gallophosphates, zincophosphates, titanophosphates, and combinations thereof, wherein the crystalline inorganic material comprises a crystalline mesostructure that defines a plurality of mesopores within the volume of the crystalline mesostructure, and wherein the crystalline inorganic material is present in the composition in an amount in the range of from about 0.05 to about 100 weight percent, based on the combined weight of the crystalline inorganic material and the biological catalyst.
2. The composition of claim 1 , wherein the biological catalyst comprises an enzyme.
3. The composition of claim 1 , wherein the crystalline inorganic material is present in the composition in an amount in the range of from about 1 to about 10 weight percent, based on the combined weight of the crystalline inorganic material and the biological catalyst.
4. The composition of claim 3 , wherein the crystalline inorganic material is present in the composition in an amount in the range of from about 2 to about 3 weight percent, based on the combined weight of the crystalline inorganic material and the biological catalyst.
5. The composition of claim 1 , wherein the plurality of mesopores have a hexagonal pore arrangement of MCM-41, a cubic pore arrangement of MCM-48, a lamellar pore arrangement of MCM-50, or a hexagonal pore arrangement of SBA-015.
6. The method of claim 1 , wherein the plurality of mesopores are organized in a foam arrangement.
7. The composition of claim 1 , wherein the pore volume of the crystalline mesostructure is in the range of from about 0.05 cc/g to about 2 cc/g.
8. The composition of claim 1 , wherein the mean pore diameter within the crystalline mesostructure is in the range of from about 2 nm to about 5 nm.
9. The composition of claim 1 , wherein the wall thickness of the crystalline mesostructure is in the range of from about 1 nm to about 5 nm.