Bituminous composition with thermoreversible properties
View Patent ↗The invention relates to a method of making a theremorevsible bituminous composition. The method includes transferring an additive to a bitumen to form a mixture, and stirring the mixture until its appearance is homogenous. The additive can be an organogelator with general formula R″—(COOH) z , where R″ is a linear or branched, saturated or unsaturated chain having 4 to 68 carbon atoms and z is an integer varying from 2 to 4. The bituminous composition is hard at the temperature of use without increasing its viscosity when hot.
1. A method for obtaining a thermoreversible bituminous composition which is hard at the temperature of use without increasing its viscosity measured at a temperature of 140° C., the method comprising introducing a minor proportion of at least one chemical additive to a major proportion of at least one bitumen, wherein the additive is a diacid chosen from the group consisting of pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, 1,2-dodecanedioic acid or tetradecanedioic acid.
2. The method according to claim 1 , wherein the additive is an organogelator.
3. The method according to claim 2 , wherein the organogelator creates a network of hydrogen bonds between organogelling molecules.
4. The method according to claim 3 , wherein the organogelator molecules have a molar mass of less than or equal to 2000 gmol −1 .
5. The method according to claim 3 , wherein the organogelling molecules have a molar mass of less than or equal to 1000 gmol −1 .
6. The method according to claim 1 , wherein the additive is present at 0.1 to 5% by mass with respect to the bitumen.
7. The method according to claim 1 , wherein the bitumen also comprises at least one polymer and/or one flux.
8. The method according to claim 1 , wherein the bitumen is chosen from the group consisting of atmospheric distillation residues, vacuum distillation residues, visbroken residues, blown residues, and mixtures and combinations thereof.
9. The method according to claim 1 , wherein the bituminous composition is a bituminous binder selected from the group consisting of an anhydrous binder, a bituminous emulsion, a polymer bitumen, and a fluxed bitumen.
10. The method according to claim 9 , wherein the major proportion of at least one bitumen includes a mixture with aggregates and the bituminous composition is for manufacturing a surface dressing, a hot mix, a cold mix, a cold-cast mix, a gravel emulsion or a wearing course.
11. A method for making a bituminous composition, comprising:
a. transferring a bitumen and an organogelator to a reactor to generate a mixture, wherein the organogelator is a diacid chosen from the group consisting of pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, 1,2-dodecanedioic acid or tetradecanedioic acid;
b. heating the mixture at 140 to 180° C. with stirring until the mixture has a homogenous appearance; and
c. cooling the mixture to ambient temperature to generate the bituminous composition,
wherein the bituminous composition is thermoreversible and hard at the temperature of use without increasing its viscosity measured at a temperature of 140° C.
12. The method according to claim 11 , wherein the organogelator is transferred when at temperatures from 140 to 180° C., either into the bitumen alone, into the bitumen modified or not modified by polymers, into the bitumen in the form of a bituminous binder, or into the bitumen when the bitumen is an anhydrous binder, bituminous mix, or surface dressing.
13. A method for making a bituminous composition, comprising
a. transferring a bitumen to a reactor, the bitumen selected form the group consisting of a polymer bitumen, a non-polymer bitumen, a bituminous binder, an anhydrous bituminous binder, and a bituminous mix;
b. transferring an organogelator heated to 140 to 180° C. to the bitumen to form a mixture, wherein the organogelator is chosen from the group consisting of pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, 1,2-dodecanedioic acid or tetradecanedioic acid;
d. stirring the mixture for approximately 60 minutes or until the mixture appears homogenous; and
e. cooling the mixture to ambient temperature to generate the bituminous composition, wherein the bituminous composition is theremoreversible and hard or the temperature of use without increasing its viscosity at a temperature of 140° C.
14. A thermoreversible bituminous composition which is hard at the temperature of use without increasing its viscosity measured at a temperature of 140° C. comprising a minor proportion of a least one chemical additive chosen from the group consisting of pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, 1,2-dodecanedioic acid or tetradecanedioic acid and a major proportion of a least one bitumen.
15. The thermorevesible bituminous composition of claim 11 wherein the bituminous binder is selected from the group consisting of an anhydrous binder, a bituminous emulsion, a polymer bitumen and a fluxed bitumen.