FOAMED ADHESIVE TAPE FOR BONDING TO NON-POLAR SURFACES
An adhesive tape, with a carrier material, has an acrylate-based foam layer bearing at least one layer of pressure-sensitive adhesive. The pressure-sensitive adhesive (a) being composed of a mixture of at least two different synthetic rubbers, more particularly based on vinylaromatic block copolymers, (b) comprising a resin which is not soluble in the acrylates forming the foam layer, and (c) being chemically uncrosslinked.
1 . Adhesive tape, with a carrier material, comprising an acrylate-based foam layer bearing at least one layer of pressure-sensitive adhesive, the pressure-sensitive adhesive
(a) being composed of a mixture of at least two different synthetic rubbers;
(b) comprising a resin that is not soluble in the acrylates forming the foam layer; and
(c) being chemically uncrosslinked.
2 . Adhesive tape according to claim 1 , wherein the foam layer is a viscoelastic foam layer.
3 . Adhesive tape according to claim 1 , wherein the acrylate forming the foam layer is a polyacrylate obtained by free or controlled radical polymerization of one or more acrylates and alkylacrylates.
4 . Adhesive tape according to claim 1 , wherein the acrylate forming the foam layer is a thermally crosslinked polyacrylate.
5 . Adhesive tape according to at least one of claim 1 , wherein the acrylate forming the foam layer is a poly(meth)acrylate comprising
(a1)) 70 to 100 wt % of acrylic esters and/or methacrylic esters and/or the free acids thereof, of the following structural formula
where R 1 is H or CH 3 and R 2 is H or alkyl chains having 1 to 14 C atoms,
(a2) 0 to 30 wt % of olefinically unsaturated monomers having functional groups, and
(a3) optionally, further acrylates and/or methacrylates and/or olefinically unsaturated monomers, with a fraction between 0 to 5 wt %, which are copolymerizable with component (a1)) and have a functional group which by means of the coupling reagent leads to covalent crosslinking.
6 . Adhesive tape according to claim 4 , wherein use is made
as monomers (a1) of acrylic monomers comprising acrylic and methacrylic esters with alkyl groups consisting of 1 to 14 C atoms, selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, n-pentyl acrylate, n-hexyl acrylate, n-hexyl methacrylate, n-heptyl acrylate, n-octyl acrylate, n-nonyl acrylate, lauryl acrylate, stearyl acrylate, stearyl methacrylate, behenyl acrylate and branched isomers thereof;
as monomers (a2) of maleic anhydride, itaconic anhydride, glycidyl methacrylate, benzyl acrylate, benzyl methacrylate, phenyl acrylate, phenyl methacrylate, tert-butylphenyl acrylate, tert-butylphenyl methacrylate, phenoxyethyl acrylate, phenoxyethyl methacrylate, 2-butoxyethyl methacrylate, 2-butoxyethyl acrylate, dimethylaminoethyl methacrylate, dimethylaminoethyl acrylate, diethylaminoethyl methacrylate, diethylaminoethyl acrylate and tetrahydrofurfuryl acrylate; and/or
as monomers (a3) of hydroxyethyl acrylate, 3-hydroxypropyl acrylate, hydroxyethyl methacrylate, 3-hydroxypropyl methacrylate, 4-hydroxybutyl acrylate, 4-hydroxybutyl methacrylate, allyl alcohol, itaconic acid, acrylamide and cyanoethyl methacrylate, cyanoethyl acrylate, 6-hydroxyhexyl methacrylate, N-tert-butylacrylamide, N-methylolmethacrylamide, N-(butoxymethyl)methacrylamide, N-methylolacrylamide, N-(ethoxymethyl)acrylamide, N-isopropylacrylamide, vinylacetic acid, β-acryloyloxypropionic acid, trichloroacrylic acid, fumaric acid, crotonic acid, aconitic acid, dimethylacrylic acid and 4-vinylbenzoic acid.
7 . Adhesive tape according to claim 5 , wherein the comonomers are selected such that the glass transition temperature T g,A of the polymers is below the application temperature.
8 . Adhesive tape according to claim 1 , wherein the acrylate-based foam layer is admixed with at least one tackifying resin.
9 . Adhesive tape according to claim 1 , wherein the acrylate-based foam layer is foamed using microballoons.
10 . Adhesive tape according to claim 1 , wherein the acrylate-based foam layer is crosslinked.
11 . Adhesive tape according to claim 1 , wherein the acrylate-based foam layer has a layer thickness of between 0.3 mm and 5 mm.
12 . Adhesive tape according to claim 1 , wherein the pressure-sensitive adhesive comprises to an extent of at least 70 wt % a mixture of
(i) block copolymers comprising a mixture of block copolymers with the structures I and II
I) A′-B′
II) A-B-A, (A-B) n , (A-B) n X and/or (A-B) n X, where
X is the radical of a coupling reagent,
n is an integer between 2 and 10,
A and A′ is a polymer block of a vinylaromatic,
B and B′ is a polymer block formed from butadiene, a mixture of butadiene and isoprene and/or a mixture of butadiene and styrene, and
A and A′, and B and B′, may be identical or different,
(ii) at least one tackifier resin,
the fraction of the block copolymers I) being between 30 and 70 wt %, based on the total amount of block copolymers,
the fraction A in the case of the block copolymers II) being between 25 and 40 wt %,
and the A-B unit within at least one of the vinylaromatic block copolymers of the structure II having a molecular weight M w of greater than 65 000 g/mol, the molecular weight M w of the total block copolymer II being greater than 130 000 g/mol.
13 . Adhesive tape according to claim 12 , wherein the pressure-sensitive adhesive comprises as elastomers only a mixture of vinylaromatic block copolymers of structures I and II, it being possible for the mixture to consist of a vinylaromatic block copolymer of the structure I and a vinylaromatic block copolymer of the structure II or for the mixture to consist of a plurality of different vinylaromatic block copolymers of the structures I and II.
14 . Adhesive tape according to claim 12 , wherein, in addition to the structures I and II, a block copolymer is used which is a multi-arm block copolymer described by the general formula Q n -Y.
15 . Adhesive tape according to claim 12 , wherein the block A is a glasslike block having a glass transition temperature (T g ) above at least 40° C.
16 . Adhesive tape according to at least one of claim 12 , wherein the block B is rubberlike or is a soft block having a T g of less than room temperature.
17 . Adhesive tape according to claim 12 , wherein a fraction of the vinylaromatic block copolymer or of the vinylaromatic block copolymers of the structure I in the sum total of the vinylaromatic block copolymers of the structures I and II is between 30 and 70 wt %.
18 . Adhesive tape according to claim 12 , wherein a fraction or fractions of the vinylaromatic end block A in the block copolymer of the structure I, and/or the fraction or fractions of the vinylaromatic end blocks A and A′ in the block copolymer of the structure II, is or are between 20 and 40 wt %.
19 . Adhesive tape according to claim 12 , wherein the pressure-sensitive adhesive comprises a first resin having a T g of at least 60° C., which is compatible with the elastomer blocks of the block copolymers, and/or comprises a second resin having a T g of less than 60° C., which is compatible with the glasslike blocks of the linear block copolymers and/or of the multi-arm block copolymers.
20 . Adhesive tape according to claim 12 , wherein the pressure-sensitive adhesive comprises endblock reinforcer α-methylstyrene resins.
21 . Adhesive tape according to claim 12 , wherein the layer of pressure-sensitive adhesive is applied with a weight per unit area of 40 to 100 g/m 2 on the viscoelastic foam carrier layer.
22 . Adhesive tape according to claim 12 , wherein the adhesive tape consists of the viscoelastic foam carrier layer, that bears a layer of pressure-sensitive adhesive on one side.
23 . Adhesive tape according to claim 1 , wherein the adhesive tape has a thickness between 100 μm to 5000 mm.
24 . Method for producing an adhesive tape according to claim 1 , the method comprising:
(i) producing a viscoelastic foam carrier layer having a top face and a bottom face, by
(a) providing a mixture which is polymerizable by means of free or controlled radical polymerization and comprises one or more acrylate and alkylacrylate monomers,
(b) polymerizing the mixture specified under (a),
(c) carrying out thermal crosslinking, and
(d) foaming the polyacrylate, and
(ii) application by coating of one or more pressure-sensitive adhesives, of which at least one
(a) is chemically uncrosslinked and
(b) comprises a mixture of synthetic rubbers,
to at least one of the principal sides of said acrylate foam carrier, in order thus to produce a layer of pressure-sensitive adhesive.
25 . Method for producing an adhesive tape according to claim 1 , the method comprising:
(i) producing a viscoelastic foam carrier layer having a top face and a bottom face, by
(a) providing a mixture which is polymerizable by means of free or controlled radical polymerization and comprises one or more acrylate and alkylacrylate monomers,
(b) polymerizing the mixture specified under (a),
(c) removing the solvent,
(d) processing the polyacrylate in the melt
(e) in said melt, compounding and homogenizing chemical and/or physical blowing agents and thermal crosslinkers in an extruder,
(f) carrying out thermal crosslinking, and
(g) foaming the polyacrylate, and
(ii) application by coating of one or more pressure-sensitive adhesives, of which at least one in accordance with the invention
(a) is chemically uncrosslinked and
(b) comprises a mixture of vinylaromatic block copolymers, and also
(c) comprises resins which are not soluble in a polyacrylate and
therefore are unable to migrate into the acrylate foam carrier layer, to at least one of the principal sides of said acrylate foam carrier, in order thus to produce a layer of pressure-sensitive adhesive.
26 - 27 . (canceled)