Oxycarbonitride phosphors and light emitting devices using the same
View Patent ↗Disclosed herein is a novel family of oxycarbonitride phosphor compositions and light emitting devices incorporating the same. Within the sextant system of M—Al—Si—O—N—C—Ln and quintuplet system of M—Si—O—N—C—Ln (M=alkaline earth element, Ln=rare earth element), the phosphors are composed of either one single crystalline phase or two crystalline phases with high chemical and thermal stability. In certain embodiments, the disclosed phosphor of silicon oxycarbonitrides emits green light at wavelength between 530-550 nm. In further embodiments, the disclosed phosphor compositions emit blue-green to yellow light in a wavelength range of 450-650 nm under near-UV and blue light excitation.
1. A composition comprising a phosphor having a formula selected from the group consisting of:
M(II) 7−y M(I) y M(III) 12−x−y−z Si x+y+z O 25−x±δ/2 N x±δ−z C z :A, wherein 0<x<12, 0≦y<x, 0<z<x, 0<x+y+z≦12, z<x+δ, and 0<δ≦3; (a)
M(II) 7−y M(I) y M(III) 12−x−y−z Si x+y+z O 25−x±δ/2 N x±δ−z C 25δ/2 :A, wherein 0<x<12, 0≦y<x, 0<z<x, 0<x+y+z≦12, z<x+δ, and 0<δ≦3; (b)
M(II) 7−y M(I) y M(III) 12−x−y−z Si x+y+z O 25−x−y/2±3δ/2 N x±δ−z C z D v :A, wherein 0<x<12, 0≦y<1, 0<z<x, z<x+δ, 0<δ≦3, 0≦v<1, and 0<x+y+z≦12; (c) and
M(II) 7−y M(I) y M(III) 12−x−y−z Si x+y+z O 25−x−v/2±δ/2 N x±δ−z C z±δ/2 D v :A, wherein 0<x<12, 0≦y<1, 0<z<x, z<x+δ, 0<δ≦3, 0≦v<1, and 0<x+y+z≦12; (d)
wherein:
M(II) comprises at least one divalent cation;
M(I) comprises at least one monovalent cation;
M(III) comprises at least one trivalent cation;
D comprises at least one monovalent anion; and
A comprises a luminescence activator doped in the crystal structure.
2. The composition of claim 1 , wherein
M(II) comprises at least one divalent cation selected from the group consisting of Be, Mg, Ca, Sr, Ba, Cu, Co, Ni, Pd, Zn, and Cd;
M(I) comprises at least one monovalent cation selected from the group consisting of Li, Na, K, Rb, Cu, Ag and Au;
M(III) comprises at least one trivalent cation selected from the group consisting of B, Al, Ga, In, Sc, Y, La and Gd;
D comprises at least one anion selected from the group consisting of F, Cl, Br and I; and
A comprises at least one luminescence activator selected from the group consisting of Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Mn, Bi, and Sb.
3. A light emitting device comprising:
a light source emitting a first luminescence spectrum;
a phosphor composition, which, when irradiated with light from the light source, emits light having a second luminescence spectrum;
wherein a phosphor composition comprises at least one phosphor selected from the group consisting of:
M(II) 7 Al 12−x−y Si x+y O 25−x N x−y C y :A, wherein 0<x≦12, 0<y<x, and 0<x+y≦12; (a)
M(II) 7 M(III) 12−x−y Si x+y O 25−x N x−y C y :A, wherein 0<x≦12, 0<x+y≦12, and 0<y<x; (b)
M(II) 7 M(III) 12−x−y Si x+y O 25−x±3δ/2 N x±δ−y C y :A, wherein 0<x<12, 0≦y<x, 0<x+y≦12, 0<δ≦3, and δ<x+y; (c)
M(II) 7 M(III) 12−x−y Si x+y O 25−x±δ/2 N x±δ−y C y±δ/2 :A, wherein 0≦x<12, 0≦y<x, 0<x+y≦12, 0<δ≦3, and δ<x+y; (d)
M(II) 7−y M(I) y M(III) 12−x−y−z Si x+y+z O 25−x±3δ/2 N x±δ−z C z :A, wherein 0<x<12, 0≦y<x, 0<z<x, 0<x+y+z±12, z<x+δ, and 0<δ≦3; (e)
M(II) 7−y M(I) y M(III) 12−x−y−z Si x+y+z O 25−x±δ/2 N x±δ−z C z±δ/2 :A, wherein 0<x<12, 0≦y<x, 0<z<x, 0<x+y+z≦12, z<x+δ, and 0<δ≦3; (f)
M(II) 7−y M(I) y M(III) 12−x−y−z Si x+y+z O 25−x−v/2±3δ/2 N x±δ−z C z D v :A, wherein 0<x<12, 0≦y<1, 0<z<x, z<x+δ, 0<δ≦3, 0≦v<1, and 0<x+y+z≦12; (g) and
M(II) 7−y M(I) y M(III) 12−x−y−z Si x+y+z O 25−x−v/2±δ/2 N x±δ/2 D v :A, wherein 0<x<12, 0≦y<1, 0<z<x, z<x+δ, 0<δ≦3, 0≦v<1, and 0<x+y+z≦12; (h)
wherein:
M(II) comprises at least one divalent cation selected from the group consisting of Be, Mg, Ca, Sr, Ba, Cu, Co, Ni, Pd, Zn, and Cd;
M(I) comprises at least one monovalent cation selected from the group consisting of Li, Na, K, Rb, Cu, Ag and Au;
M(III) comprises at least one trivalent cation selected from the group consisting of B, Al, Ga, In, Sc, Y, La and Gd;
D comprises at least one monovalent anion selected from the group consisting of F, Cl, Br and I; and
A comprises a luminescence activator doped in the crystal structure, wherein the luminescence activator is selected from the group consisting of Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Mn, Bi, and Sb.
4. The light emitting device of claim 3 , further comprising a second phosphor having a formula selected from the group consisting of:
Ca 1−x Al x−xy Si 1−x+xy N 2−x−xy C xy :A; (a)
Ca 1−x−z Na z M(III) x−xy−z Si 1−x+xy+z N 2 2−x−xy C xy :A; (b)
M(II) 1−x−z M(I) z M(III) x−xy−z Si 1−x+xy+z N 2−x−xy C xy :A; (c)
M(II) 1−x−z M(I) z M(III) x−xy−z Si 1−x+xy+z N 2−x−xy−2w/3 C xy O 2−v/2 D v :A; (d) and
M(II) 1−x−z M(I) z M(III) x−xy−z Si 1−x+xy+z N 2−x−xy−2w/3−v/3 C xy O w D v :A; (e)
wherein:
0<x<1, 0<y<1, 0≦z<1, 0<w<1, x+z<1, x>xy+z, v/2≦w, x−xy−2w/3−v/3<2, and 0<x−xy−z<1;
M(II) is at least one divalent cation;
M(I) is at least one monovalent cation;
M(II) is at least one trivalent cation;
D is at least one monovalent anion; and
A is a luminescence activator.
5. The light emitting device of claim 3 , further comprising at least two additional phosphors.
6. The light emitting device of claim 3 , wherein the device emits white light.
7. The light emitting device of claim 3 , further comprising at least one phosphor selected from the group consisting of Ca 1−x Sr x S:Eu 2+ (0≦x≦1), 3.5 MgO.0.5 MgF 2 .GeO 2 :Mn 4+ , Y 2 O 2 S:Eu 3+, M 2 Si 5 N 8 :Eu 2+ (M=Ca, Sr, Ba), MAlSiN 3 :Eu 2+ (M=Ca, Sr), Y 2 Si 4 N 6 C:Eu 2+ , CaSiN 2 :Eu 2+ , Ca 1−x Sr x Ga 2 S 4 :Eu 2+ (0≦x≦1), Ca 1−x−y−z Mg x Sr y Ba z SiO 4 :Eu 2+ (0≦x≦1, 0≦y≦1, 0≦z≦1, x+y+z≦1), BaMgAl 10 O 17 :Eu 2+ , Mn 2+ , MYSi 4 N 7 :Eu 2+ (M=Ca, Sr, Ba), β-sialon:Eu 2+ , MSi 2 O 2 N 2 :Eu 2+ (M=Ca, Sr, Ba), Ba 3 Si 6 O 12 N 2 :Eu 2+ , M 2 Si 5 N 8 :Ce 3+ (M=Ca, Sr, Ba), Y 2 Si 4 N 6 C:Ce 3+ , α-sialon:Yb 2+ , (MSiO 3 ) m .(SiO 2 ) n :Eu 2+ , X(M=Mg, Ca, Sr, Ba; X=F, Cl, Br, I; m is 0 or 0, and either (i) n>3 if M=1 or (ii) n=1 if m=0), MAl 2 O 4 :Eu 2+ (M=Mg, Ca, Sr), BaMgAl 10 O 17 :Eu 2+ , Y 3 Al 5 O 12 :Ce 3+ (cerium-doped garnet type phosphor), and α-sialon:Eu 2+ .