Starch-biogum compositions
View Patent ↗A composition comprising starch, a biogum and water subjected to heat, shearing and optionally depolymerization is provided which is useful as a stable high solids dispersion useful in various applications including as wet-end additives for paper making.
1. A composition comprising a starch, a biogum and water subjected to heat and shearing sufficient to hydrate and disperse the starch and biogum molecules to produce a pumpable/flowable viscosity stable dispersion having a Brookfield viscosity of less than 20,000 cps (as measured on a Brookfield RVT at 75° F., #5 spindle, 10 rpm) and a starch and biogum solids level of at least 15% dry solids (ds) basis wherein the biogum is gellan.
2. The composition of claim 1 having a starch and biogum solids level of at least 20% (ds) basis.
3. The composition of claim 1 having a starch and biogum solids level of at least 30% (ds) basis.
4. The composition of claim 1 having a Brookfield viscosity of less than 12,000 cps (as measured on a Brookfield RVT at 75° F., #5 spindle, 10 rpm).
5. The composition of claim 1 having a Brookfield viscosity of less than 10,000 cps (as measured on a Brookfield RVT at 75° F., #5 spindle, 10 rpm).
6. The composition of claim 1 having a biogum content of from 0.1% to 2.5% of as is biogum to ds starch.
7. The composition of claim 1 wherein the starch is waxy corn starch.
8. A composition comprising a starch, a biogum and water subjected to heat and shearing sufficient to hydrate and disperse the starch and biogum molecules to produce a pumpable/flowable viscosity stable dispersion having a Brookfield viscosity of less than 20,000 cps (as measured on a Brookfield RVT at 75° F., #5 spindle, 10 rpm) and a starch and biogum solids level of at least 15% dry solids (ds) basis wherein the starch is depolymerized.
9. A wet-end paper making additive comprising a starch, a biogum and water subjected to heat and shearing sufficient to hydrate and disperse the starch and biogum molecules to produce a pumpable/flowable viscosity stable dispersion having a Brookfield viscosity of less than 20,000 cps (as measured on a Brookfield RVT at 75° F., #5 spindle, 10 rpm) and a starch and biogum solids level of at least 15% dry solids (ds) basis wherein the starch subjected to heating and shearing is a first cationic starch which composition is further combined with a second cationic starch.
10. A wet-end paper making additive according to claim 9 wherein the second cationic starch is a high charge, liquid cationic starch.
11. The wet-end paper making additive of claim 9 further comprising an uncooked starch.
12. The wet-end paper making additive of claim 11 wherein the uncooked starch is a modified starch.
13. The wet-end paper making additive of claim 12 wherein the modified starch is a cationic starch.
14. The wet-end paper making additive of claim 9 which further comprises a filler.
15. A method of manufacturing paper comprising adding the composition of claim 9 to the wet-end of a paper making machine.
16. The method of claim 15 wherein the composition is administered at a concentration of 0.5 to 40 lbs dry substance starch per ton of dry substance pulp fiber.
17. The composition of claim 8 having a starch and biogum solids level of at least 20% (ds) basis.
18. The composition of claim 8 having a starch and biogum solids level of at least 30% (ds) basis.
19. The composition of claim 8 having a Brookfield viscosity of less than 12,000 cps (as measured on a Brookfield RVT at 75° F., #5 spindle, 10 rpm).
20. The composition of claim 8 having a Brookfield viscosity of less than 10,000 cps (as measured on a Brookfield RVT at 75° F., #5 spindle, 10 rpm).
21. The composition of claim 8 wherein the biogum is selected from the group consisting of gellan, xanthan gum, locust bean gum, carrageenan, guar, alginate, carboxymethylcellulose, hydroxyethylcellulose, hemicellulose, gum Arabic and agar.
22. The composition of claim 8 having a biogum content of from 0.1% to 2.5% of as is biogum to ds starch.
23. The composition of claim 8 wherein the biogum is gellan.
24. The composition of claim 8 wherein the starch is waxy corn starch.