IP Library Granted Patent US 9,287,494
Granted Patent B1
US 9,287,494 · App. 13/954,766 · Granted Mar 15, 2016

Magnetic tunnel junction (MTJ) with a magnesium oxide tunnel barrier

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Quick Facts
Patent No.
US 9,287,494
App. No.
13/954,766
Granted
Mar 15, 2016
Kind
B1
Abstract

A method for fabricating a magnetic tunnel junction (MTJ) is disclosed. The process involves annealing a stack that includes a tunnel barrier layer and cooling the stack under vacuum immediately after annealing. At least one overlayer is deposited on the tunnel barrier layer to form the MTJ.

Claims (30)

1. A method for fabricating a magnetic tunnel junction (MTJ) comprising:

forming a stack that includes a tunnel barrier layer;

annealing the stack immediately after the tunnel barrier layer is deposited;

cooling the stack under vacuum; and

then depositing at least one overlayer on the tunnel barrier layer to form the MTJ after the step of cooling the stack under vacuum.

2. The method of claim 1 , further comprising depositing a free layer on the tunnel barrier followed by a capping layer on the free layer.

3. The method of claim 1 , wherein the tunnel barrier layer has an approximate thickness of between four and seven angstroms.

4. The method of claim 1 , wherein the stack is annealed at a temperature between 155° C. and 200° C.

5. The method of claim 1 , wherein annealing occurs in the absence of a magnetic field in a pre-heated chamber.

6. The method of claim 1 , wherein the stack is cooled for approximately 5-35 minutes in a holding chamber that is maintained at room temperature.

7. The method of claim 1 , wherein the MTJ has an MR ratio that increases as the cooling period increases.

8. The product formed by the process of claim 1 .

9. A method for fabricating a magnetic tunnel junction (MTJ) comprising:

providing a stack of layers;

depositing a tunnel barrier layer on the stack of layers to form an intermediate structure;

annealing the intermediate structure after the tunnel barrier layer is deposited and in the absence of a magnetic field; and

cooling the tunnel barrier layer under vacuum prior to depositing at least one overlayer to form the MTJ.

10. The method of claim 9 , further comprising providing a free layer on the tunnel barrier layer, and a capping layer on the free layer.

11. The method of claim 9 , wherein the tunnel barrier layer has an approximate thickness of between four and seven angstroms.

12. The method of claim 9 , wherein the intermediate structure is annealed at a temperature between 155° C. to 200° C. prior to deposition of the at least one overlayer.

13. The method of claim 9 , wherein annealing occurs in a pre-heated chamber.

14. The method of claim 9 , wherein the intermediate structure is placed in a holding chamber for a period of 5-35 minutes to cool to a temperature between 24° C.-190° C.

15. The method of claim 14 , wherein the holding chamber is maintained at a temperature of between 24° C.-30° C.

16. The method of claim 9 , wherein the MTJ has an MR ratio that increases as the cooling period increases.

17. The method of claim 9 , wherein the MTJ has an MR ratio between 60% and 90% at resistance-area product values between 0.55 and 0.85 Ωμm 2 .

18. A method for fabricating a magnetic tunnel junction (MTJ) comprising:

forming a stack of layers;

depositing a tunnel barrier layer on the stack of layers to form an intermediate structure

annealing the intermediate structure after the tunnel barrier layer is deposited; and

cooling the tunnel barrier layer under vacuum prior to depositing at least one overlayer to form an MTJ, wherein the MTJ has an MR ration between 60% and 90% at resistance-area product values between 0.55 and 085 Ωμm 2 .

Assignments (9)
PATENT COLLATERAL AGREEMENT - DDTL LOAN AGREEMENT Recorded Aug 21, 2023
From: WESTERN DIGITAL TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 067045/0156 →
PATENT COLLATERAL AGREEMENT - A&R LOAN AGREEMENT Recorded Aug 21, 2023
From: WESTERN DIGITAL TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 064715/0001 →
RELEASE OF SECURITY INTEREST AT REEL 038710 FRAME 0845 Recorded Feb 8, 2022
From: JPMORGAN CHASE BANK, N.A.
To: WESTERN DIGITAL (FREMONT), LLC; WESTERN DIGITAL TECHNOLOGIES, INC.
Reel/Frame 058965/0445 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 19, 2019
From: WESTERN DIGITAL (FREMONT), LLC
To: WESTERN DIGITAL TECHNOLOGIES, INC.
Reel/Frame 050450/0582 →
RELEASE OF SECURITY INTEREST Recorded Mar 5, 2018
From: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
To: WESTERN DIGITAL (FREMONT), LLC
Reel/Frame 045501/0158 →
SECURITY AGREEMENT Recorded May 16, 2016
From: WESTERN DIGITAL (FREMONT), LLC
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 038744/0755 →
SECURITY AGREEMENT Recorded May 16, 2016
From: WESTERN DIGITAL (FREMONT), LLC
To: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 038744/0675 →
SECURITY AGREEMENT Recorded May 16, 2016
From: WESTERN DIGITAL (FREMONT), LLC
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 038710/0845 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 30, 2013
From: YAN, MINGLANG; HUANG, XIAOBO; SHEN, JIAN X.
To: WESTERN DIGITAL (FREMONT), LLC
Reel/Frame 030908/0927 →