TAMPER EVIDENT DOCUMENTS AND INKS
A tamper evident document, a process of preparing the tamper evident document, and a tamper evident ink. The tamper evident document includes a paper substrate having a face for providing information, and a tamper evident ink applied on the face of the paper substrate. The tamper evident ink includes (i) microcapsules having a cross-linked polymer shell and a core surrounded by the shell; and (ii) developer particles. The cores of the microcapsules include at least one color former dissolved in a carrier oil. If information on the tamper evident document is altered by force or pressure (e.g., by scraping with a knife), the microcapsules rupture and the color former reacts with the developer particles to provide a visual indication of tampering (e.g., appearance of color or color change) on the face of the document.
1 . A tamper evident document comprising:
a paper substrate having a face for providing information; and
a tamper evident ink comprising: (i) microcapsules having a cross-linked polymer shell and a core surrounded by the shell, wherein the core comprises at least one color former dissolved in a carrier oil; and (ii) developer particles, wherein the tamper evident ink is applied on the face of the paper substrate.
2 . The tamper evident document of claim 1 , wherein the cross-linked polymer shell comprises polyurea.
3 . The tamper evident document of claim 1 , wherein the microcapsules have a diameter of about 2-8 microns.
4 . The tamper evident document of claim 1 , wherein the microcapsules have a diameter of about 5 microns.
5 . The tamper evident document of claim 1 , wherein the microcapsules have a wall thickness of about 110-120 nanometers.
6 . The tamper evident document of claim 1 , wherein the at least one color former comprises at least one leuco dye.
7 . The tamper evident document of claim 1 , wherein the carrier oil comprises vegetable oil, soybean oil, or mixtures thereof.
8 . The tamper evident document of claim 1 , wherein the developer particles comprise a zinc phenolic resin.
9 . The tamper evident document of claim 1 , wherein the tamper evident ink comprises:
about 15-25% by weight of the microcapsules; and
about 15-20% by weight of the developer particles.
10 . The tamper evident document of claim 1 , wherein the tamper evident ink further comprises:
about 20-40% by weight ester resin; and
about 20-30% by weight oil.
11 . The tamper evident document of claim 1 , wherein the tamper evident ink is colorless so long as the at least one color former is not in contact with the developer particles.
12 . The tamper evident document of claim 1 , wherein if the variable or sensitive information is altered by force or pressure, the microcapsules rupture and the at least one color former reacts with the developer particles to provide a visual indication of tampering.
13 . The tamper evident document of claim 12 , wherein the visual indication is a color change or appearance of color where the force or pressure was applied.
14 . The tamper evident document of claim 1 , wherein the tamper evident document is a security document selected from the group consisting of a check, lottery ticket, passport, gaming document, and casino document.
15 . A process of preparing a tamper evident document comprising:
(a) providing a paper substrate having a face for providing information; and
(b) applying a tamper evident ink on the face of the paper substrate, the tamper evident ink comprising: (i) microcapsules having a cross-linked polymer shell and a core surrounded by the shell, wherein the core comprises at least one color former dissolved in a carrier oil; and (ii) developer particles.
16 . The process of claim 15 , wherein the tamper evident ink is applied to portions of the paper substrate which will contain variable or sensitive information.
17 . The process of claim 16 further comprising printing the variable or sensitive information on the face of the paper substrate.
18 . The process of claim 15 , wherein the tamper evident ink is applied by coating or printing the tamper evident ink on the face of the paper substrate.
19 . The process of claim 18 , wherein the tamper evident ink is applied by dry offset printing.
20 . A tamper evident ink comprising:
about 15-25% by weight microcapsules having a cross-linked polyurea shell and a core surrounded by the shell, wherein the core comprises at least one color former dissolved in a carrier oil;
about 15-20% by weight developer particles;
about 20-40% by weight ester resin; and
about 20-30% by weight oil.
21 . The tamper evident ink of claim 20 , wherein the microcapsules have a diameter of about 5 microns and a wall thickness of about 110-120 nanometers.