Non-aqueous electrolyte solution and non-aqueous electrolyte secondary battery employing the same
The demand for improvements in lithium non-aqueous electrolyte secondary batteries has been constantly increasing in recent years, but the durability—most prominently the cycle characteristics—have resided in a trade off relationship with properties such as the capacity, resistance, and output characteristics. A problem has thus been a poor overall property balance. In order to solve this problem, the present invention uses a non-aqueous electrolyte solution including, in addition to an electrolyte and a non-aqueous solvent, (A) at least one compound selected from the group consisting of carbonates having a carbon-carbon unsaturated bond, compounds represented by the following general formula (1), sulfoxides, sulfites, sulfones, sulfonates, sultones, and sulfates; (B) a fluorine atom-containing cyclic carbonate; and (C) a compound that has at least two isocyanate groups in the molecule.
1. A non-aqueous electrolyte solution suitable for a non-aqueous electrolyte secondary battery having a positive electrode and a negative electrode that are capable of absorbing and releasing a metal ion, wherein
the non-aqueous electrolyte solution comprises, in addition to an electrolyte and a non-aqueous solvent,
(A) at least one compound selected from the group consisting of carbonates having a carbon-carbon unsaturated bond, compounds represented by the following formula (1), sulfoxides, sulfites, sulfones, sulfonates, sultones, and sulfates;
(B) a fluorine atom-containing cyclic carbonate; and
(C) 0.001 mass % to 10 mass % of a compound that has at least two isocyanate groups in the molecule:
wherein
M is —O— or —NR 2 —,
R 2 is hydrogen or a optionally branched hydrocarbon group having 10 or less carbons, and
R 1 is an optionally substituent-bearing and optionally branched hydrocarbon group having 10 or less carbons.
2. The non-aqueous electrolyte solution according to claim 1 , wherein the fluorine atom-containing cyclic carbonate (B) comprises at least one compound selected from the group consisting of fluoroethylene carbonate, 4,4-difluoroethylene carbonate, and 4,5-difluoroethylene carbonate.
3. The non-aqueous electrolyte solution according to claim 1 , wherein the compound (C) that has at least two isocyanate groups in the molecule comprises at least one compound selected from the group consisting of monomethylene diisocyanate, dimethylene diisocyanate, trimethylene diisocyanate, tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, heptamethylene diisocyanate, octamethylene diisocyanate, nonamethylene diisocyanate, decamethylene diisocyanate, dodecamethylene diisocyanate, 1,3-bis(isocyanatomethyl)cyclohexane, dicyclohexylmethane-4,4′-diisocyanate, bicyclo[2.2.1]heptan-2,5-diylbis(methyl isocyanate), bicyclo[2.2.1]heptan-2,6-diylbis(methyl isocyanate), isophorone diisocyanate, 2,2,4-trimethylhexamethylene diisocyanate, 2,4,4-trimethylhexamethylene diisocyanate, a trimer compound derived therefrom and polyisocyanate compounds provided by the addition of a polyhydric alcohol to the diisocyanate.
4. The non-aqueous electrolyte solution according to claim 1 , which contains the compound represented by formula (1) and wherein the compound represented by formula (1) comprises a compound in which R 1 is a hydrocarbon group selected from the group consisting of —CH 2 —CH 2 —, —CH 2 —CH 2 ═CH 2 —, —CH═C(CH 3 )—, —CH 2 —C(═CH 2 )—, and the hydrocarbon group represented by the following formula (2):
5. The non-aqueous electrolyte solution according to claim 1 , wherein (A) comprises at least one compound represented by formula (1) and wherein the compound represented by formula (1) comprises a compound in which M is an organic group selected from the group consisting of —O—, —NH—, and —N(—CH 1 )—.
6. The non-aqueous electrolyte solution according to claim 1 , wherein (A) comprises at least one compound represented by formula (1) and wherein the compound represented by formula (1) comprises succinic anhydride or maleic anhydride.
7. The non-aqueous electrolyte solution according to claim 1 , which contains a carbonate having a carbon-carbon unsaturated bond and wherein the carbonate having a carbon-carbon unsaturated bond comprises at least one compound selected from the group consisting of vinylene carbonate, vinylethylene carbonate, and ethynylethylene carbonate.
8. The non-aqueous electrolyte solution according to claim 1 , wherein the compound (A) is contained in the non-aqueous electrolyte solution in the amount of 0.001 mass % or more and 10 mass % or less.
9. The non-aqueous electrolyte solution according to claim 1 , wherein the fluorine atom-containing cyclic carbonate (B) is contained in the non-aqueous electrolyte solution in the amount of 0.001 mass % or more and 10 mass % or less.
10. A non-aqueous electrolyte secondary battery comprising a positive electrode capable of absorbing and releasing a lithium ion, a negative electrode capable of absorbing and releasing a lithium ion, and the non-aqueous electrolyte solution according to claim 1 .
11. The non-aqueous electrolyte solution according to claim 1 , wherein the compound (A) comprises at least one compound selected from the group consisting of carbonates having a carbon-carbon unsaturated bond, sulfoxides, sulfites, sulfones, sulfonates, sultones, and sulfates.
12. The non-aqueous electrolyte solution according to claim 1 , wherein the compound (A) comprises at, least one compound selected from the group consisting of carbonates having a carbon-carbon unsaturated bond, sulfites, and sultones.
13. The non-aqueous electrolyte solution according to claim 1 , comprising a sulfite wherein the sulfite is selected from the group consisting of dimethyl sulfite, diethyl sulfite, dipropyl sulfite, dibutyl sulfite, diphenyl sulfite, ethylene sulfite, and propylene sulfite.
14. The non-aqueous electrolyte solution according to claim 1 , comprising a sultone wherein the sultone is selected from the group consisting of 1,3-propane sultone, 1,3-propene sultone, 1,4-butane sultone, and 1,4-butene sultone.
15. The non-aqueous electrolyte solution according to claim 1 , wherein the compound (A) comprises at least one compound selected from the group consisting of succinic anhydride, vinylene carbonate, ethylene sulfite, 1,3-propane sultone, and 1,3-propene sultone.
16. The non-aqueous electrolyte solution according to claim 1 , wherein the compound (B) is an ethylene carbonate having from 1 to 8 fluorine atoms.
17. The non-aqueous electrolyte solution according to claim 1 , wherein the compound (C) that has at least two isocyanate groups in the molecule is a compound having a straight-chain or branched alkylene structure, or a compound having a cycloalkylene structure.
18. The non-aqueous electrolyte solution according to claim 1 , wherein the compound (C) that has at least two isocyanate groups in the molecule comprises at least one compound selected from the group consisting of tetramethylene diisocyanate, hexamethylene diisocyanate, octamethylene diisocyanate, 1,3-bis(isocyanatomethyl)cyclohexane, and dicyclohexylmethane-4,4′-diisocyanate.
19. The non-aqueous electrolyte solution according to claim 1 , wherein
the compound (A) comprises at least one compound selected from the group consisting of succinic anhydride, vinylene carbonate, ethylene sulfite, 1,3-propane sultone, and 1,3-propene sultone,
the compound (B) comprises at least one compound selected from the group consisting of fluoroethylene carbonate, 4,4-difluoroethylene carbonate, and 4,5-difluoroethylene carbonate, and
the compound (C) that has at least two isocyanate groups in the molecule comprises at least one compound selected from the group consisting of tetramethylene diisocyanate, hexamethylene diisocyanate, octamethylene diisocyanate, 1,3-bis(isocyanatomethyl)cyclohexane, and dicyclohexylmethane-4,4′-diisocyanate.
20. The non-aqueous electrolyte solution according to claim 1 , wherein
the compound (A) comprises at least one compound selected from the group consisting of ethylene sulfite, 1,3-propane sultone, and 1,3-propene sultone,
the compound (B) comprises at least one compound selected from the group consisting of fluoroethylene carbonate, 4,4-difluoroethylene carbonate, and 4,5-difluoroethylene carbonate, and
the compound (C) that has at least two isocyanate groups in the molecule comprises at least one compound selected from the group consisting of tetramethylene diisocyanate, hexamethylene diisocyanate, octamethylene diisocyanate, 1,3-bis(isocyanatomethyl)cyclohexane, and dicyclohexylmethane-4,4′-diisocyanate.
21. The non-aqueous electrolyte solution according to claim 1 , wherein
the compound (A) comprises at least one compound selected from the group consisting of ethylene sulfite, 1,3-propane sultone, and 1,3-propene sultone,
the compound (B) comprises at least one compound selected from the group consisting of fluoroethylene carbonate, and
the compound (C) that has at least two isocyanate groups in the molecule comprises at least one compound selected from the group consisting of tetramethylene diisocyanate, hexamethylene diisocyanate, octamethylene diisocyanate, 1,3-bis(isocyanatomethyl)cyclohexane, and dicyclohexylmethane-4,4′-diisocyanate.