Anthracene derivative and organic electroluminescence device using the same
Provided are a novel anthracene derivative of a specific structure in which benzofuran or benzothiophene is bonded to anthracene through an arylene group, a material for an organic electroluminescence device and a light emitting material for an organic electroluminescence device each containing the anthracene derivative, and an organic electroluminescence device including an organic thin film layer formed of one or plural layers including at least a light emitting layer, the organic thin film layer being interposed between a cathode and an anode, in which at least one layer of the organic thin film layer contains the anthracene derivative alone or as a component of a mixture. The organic electroluminescence device has high luminous efficiency and is capable of emitting light with a long lifetime, and the device can be realized by the anthracene derivative.
1. An anthracene derivative represented by the following general formula (2):
where L represents an unsubstituted naphthylene group, a methyl group substituted or unsubstituted fluorenylene group, or an unsubstituted biphenylene group, R a to R c each represent a hydrogen atom, Ar 1 represents a naphthyl group or phenanthryl group, X represents an oxygen atom (O) or a sulfur atom (S), p represents an integer of 4, q represents an integer of 8, and r represents an integer of 7.
2. The anthracene derivative according to claim 1 , wherein the anthracene derivative is represented by the following general formula (4):
where Ra to Rd each represent a hydrogen atom, Ar 1 represents a naphthyl group or phenauthryl group, X represents an oxygen atom (O) or a sulfur atom (S), p represents an integer of 4, q represents an integer of 8, r represents an integer of 7, and s represents an integer of 6.
3. The anthracene derivative according to claim 1 , wherein the anthracene derivative is represented by the following general formula (5):
where R a to R e each represent a hydrogen atom, Ar 1 represents a naphthyl group or phenanthryl group, X represents an oxygen atom (O) or a sulfur atom (S), p represents an integer of 4, q represents an integer of 8, r represents an integer of 7, s represents an integer of 4, and u represents an integer of 4.
4. The anthracene derivative according to claim 1 , the anthracene derivative is represented by the following general formula (6):
where R a to R d each represent a hydrogen atom, R d represents a hydrogen atom or methyl group, Ar 1 represents a naphthyl group or phenanthryl group, X represents an oxygen atom (O) or a sulfur atom (S), p represents an integer of 4, q represents an integer of 8, r represents an integer of 7, and s represents an integer of 1 to 8.
5. The anthracene derivative according to claim 1 , wherein the L is bonded to 2-position or 4-position in the following structure or the general formula (2):
6. The anthracene derivative according to claim 1 , wherein Ar 1 represents a 1-naphthyl group or a 2-naphthyl group.
7. The anthracene derivative according to claim 1 , wherein Ar 1 represents a 9-phenanthyl group.
8. The anthracene derivative according to claim 1 , wherein X represents an oxygen atom.
9. A material for an organic electroluminescence device, comprising the anthracene derivative according to claim 1 .
10. A light emitting material for an organic electroluminescence device, comprising the anthracene derivative according to claim 1 .
11. An organic electroluminescence device comprising an organic thin film layer formed of one or plural layers including at least a light emitting layer, the organic thin film layer being interposed between a cathode and an anode, wherein at least one layer of the organic thin film layer contains the anthracene derivative according to claim 1 alone or as a component of a mixture.
12. An organic electroluminescence device according to claim 11 , wherein the light emitting layer contains the anthracene derivative as a light emitting material.
13. An organic electroluminescence device according to claim 11 , wherein the light emitting layer contains the anthracene derivative as a host material.
14. An organic electroluminescence device according to claim 11 , wherein the light emitting layer further contains a fluorescent or phosphorescent dopant.
15. An organic electroluminescence device according to claim 14 , wherein the fluorescent dopant comprises an arylamine compound and/or an aryldiamine compound.
16. An organic electroluminescence device according to claim 14 , wherein the fluorescent dopant comprises a styrylamine compound and/or a styryldiamine compound.
17. An organic electroluminescence device according to claim 14 , wherein the fluorescent dopant comprises an aromatic amine compound and/or an aromatic diamine compound.
18. An organic electroluminescence device according to claim 14 , wherein the fluorescent dopant comprises a fused polycyclic aromatic compound (except amine compounds).
19. An organic electroluminescence device according to claim 14 , wherein the phosphorescent dopant comprises a metal complex compound.