Non-aqueous electrolyte solution and non-aqueous electrolyte secondary battery employing the same
An object is to provide a non-aqueous electrolyte solution that can improve the capacity deterioration and gas generation associated with the high-temperature storage of non-aqueous electrolyte batteries. A further object is to provide a non-aqueous electrolyte battery that uses this non-aqueous electrolyte solution. These objects can be achieved by using a non-aqueous electrolyte solution that incorporates, in prescribed contents, (A) a compound having at least two isocyanate groups per molecule and a compound having at least two cyano groups per molecule.
1. A non-aqueous electrolyte solution, comprising:
an electrolyte;
a non-aqueous solvent;
from 0.001 to 10 mass % of a compound having at least two isocyanate groups per molecule; and
from 0.001 to 10 mass % of a compound having at least two cyano groups per molecule;
wherein a content ratio (mass ratio) of the compound having at least two isocyanate groups per molecule to the compound having at least two cyano groups per molecule is from 40:60 to 1:99.
2. The non-aqueous electrolyte solution according to claim 1 , wherein the compound having at least two cyano groups per molecule is a compound of formula (1):
wherein A is an organic group having from 1 to 10 carbons and at least one atom selected from the group consisting of a hydrogen atom, a nitrogen atom, an oxygen atom, a sulfur atom, a phosphorus atom, and a halogen atom.
3. The non-aqueous electrolyte solution according to claim 1 , wherein the compound having at least two isocyanate groups per molecule is at least one compound selected from the group consisting of hexamethylene diisocyanate, 1,3-bis(isocyanatomethyl)cyclohexane, dicyclohexylmethane-4,4′-diisocyanate, bicyclo[2.2.1]heptan-2,5-diylbis(methyl isocyanate), bicyclo[2.2.1]heptan-2,6-diylbis(methyl isocyanate), isophorone diisocyanate, 2,2,4-trimethylhexamethylene diisocyanate, 2,4,4-trimethylhexamethylene diisocyanate, and polyisocyanate compounds derived therefrom.
4. The non-aqueous electrolyte solution according to claim 1 , wherein the compound having at least two cyano groups per molecule is at least one compound selected from the group consisting of glutaronitrile, adiponitrile, pimelonitrile, and suberonitrile.
5. The non-aqueous electrolyte solution according to claim 1 , further comprising at least one compound selected from the group consisting of fluorine atom-containing cyclic carbonates, cyclic carbonates having a carbon-carbon unsaturated bond, monofluorophosphate salts, and difluorophosphate salts.
6. The non-aqueous electrolyte solution according to claim 5 , comprising the fluorine atom-containing cyclic carbonate wherein the fluorine atom-containing cyclic carbonate is at least one compound selected from the group consisting of monofluoroethylene carbonate, 4,4-difluoroethylene carbonate, and 4,5-difluoroethylene carbonate, and/or comprising the cyclic carbonate having a carbon-carbon unsaturated bond wherein the cyclic carbonate having a carbon-carbon unsaturated bond is at least one compound selected from the group consisting of vinylene carbonate, vinylethylene carbonate, and ethynylethylene carbonate.
7. Anon-aqueous electrolyte secondary battery,
comprising: the non-aqueous electrolyte solution of claim 1 ;
a positive electrode; and
a negative electrode;
wherein the positive and negative electrodes are each capable of absorbing and releasing a lithium ion.