Non-aqueous electrolyte solution for lithium secondary battery and lithium secondary battery including the same
View Patent ↗A non-aqueous electrolyte solution for a lithium secondary battery and a lithium secondary battery including the same are provided. The non-aqueous electrolyte solution includes an organic solvent, an ionizable lithium salt, a dinitrile compound including an ether bond represented by Chemical Formula 1, and an aliphatic dinitrile compound represented by Chemical Formula 2. The lithium secondary battery including the non-aqueous electrolyte solution having the possibility of generating a swelling phenomenon while storing or charging/discharging at a high temperature may be restrained. In addition, a cycle life of the charging/discharging may be improved.
1. A non-aqueous electrolyte solution for a lithium secondary battery, comprising:
an organic solvent;
an ionizable lithium salt;
a dinitrile compound including an ether bond; and
an aliphatic dinitrile compound,
wherein the dinitrile compound including an ether bond is ethylene glycol bis(2-cyanoethyl)ether, and the aliphatic dinitrile compound is succinonitrile;
wherein the ethylene glycol bis(2-cyanoethyl)ether is included in an amount of 0.1 to 10% by weight based on a total amount of the electrolyte solution; and
the succinonitrile is included in an amount of 0.1 to 10% by weight based on a total amount of the electrolyte solution.
2. The non-aqueous electrolyte solution for a lithium secondary battery of claim 1 , further comprising a compound including a vinylene group or a vinyl group,
the compound including the vinylene group or the vinyl group being at least one selected from the group consisting of a vinylene carbonate compound, an acrylate compound including the vinyl group, a sulfonate compound including the vinyl group, and an ethylene carbonate compound including the vinyl group.
3. The non-aqueous electrolyte solution for a lithium secondary battery of claim 1 , further comprising fluoroethylene carbonate (FEC).
4. The non-aqueous electrolyte solution for a lithium secondary battery of claim 1 , wherein the ionizable lithium salt is at least one selected from the group consisting of LiPF 6 , LiBF 4 , LiSbF 6 , LiAsF 6 , LiClO 4 , LiN(C 2 F 5 SO 2 ) 2 , LiN(CF 3 SO 2 ) 2 , CF 3 SO 3 Li, LiC(CF 3 SO 2 ) 3 and LiC 4 BO 8 .
5. The non-aqueous electrolyte solution for a lithium secondary battery of claim 1 , wherein the organic solvent includes a linear carbonate, a cyclic carbonate or a combination thereof.
6. The non-aqueous electrolyte solution for a lithium secondary battery of claim 5 , wherein the linear carbonate is at least one selected from the group consisting of dimethyl carbonate, diethyl carbonate, dipropyl carbonate, ethyl methyl carbonate, methyl propyl carbonate, and ethyl propyl carbonate.
7. The non-aqueous electrolyte solution for a lithium secondary battery of claim 5 , wherein the cyclic carbonate is at least one selected from the group consisting of ethylene carbonate, propylene carbonate, 1,2-butylene carbonate, 2,3-butylene carbonate, 1,2-pentylene carbonate, 2,3-pentylene carbonate, vinylene carbonate and a halogenated compound thereof.
8. A lithium secondary battery, comprising:
an electrode assembly including a cathode including a cathode active material, an anode and a separator interposed between the cathode and the anode;
a battery container receiving the electrode assembly; and
a non-aqueous electrolyte solution injected into the battery container,
the non-aqueous electrolyte solution being the non-aqueous electrolyte solution according to claim 1 .
9. The lithium secondary battery of claim 8 , wherein the anode includes an aqueous binder.
10. The lithium secondary battery of claim 8 , wherein the cathode active material is selected from the group consisting of a lithium-manganese oxide, a lithium-nickel-manganese oxide, a lithium-manganese-cobalt oxide and a lithium-nickel-manganese-cobalt oxide.