Production of paper, card and board
View Patent ↗The present invention relates to a process for production of paper, card and board comprising draining a filler-containing paper stock comprising at least one water-soluble polymer with sheet formation in the wire section and then pressing the paper in the press section, wherein a paper stock having a fibrous concentration in the range from 20 to 40 g/l has the at least one water-soluble polymer added to it, then the paper stock is diluted to a fibrous concentration in the range from 5 to 15 g/l, the diluted paper stock is drained to form a sheet and the sheet is pressed in the press section to a solids content G(x) wt % or greater and G(x) computes according to G ( x )=48+( x −15)·0.4 where x is the numerical value of the filler content of the dry paper, card or board (in wt %) and G(x) is the numerical value of the minimum solids content (in wt %) to which the sheet is pressed, wherein the water-soluble polymer is obtainable by Hofmann degradation of an acrylamide- and/or methacrylamide-containing polymer with or without subsequent postcrosslinking.
1. A process for producing paper, card and board, the process comprising:
diluting a filler-containing paper stock to a fibrous concentration of from 5 to 15 g/l, thereby forming a diluted paper stock,
draining the diluted paper stock in a wire section, thereby forming a sheet,
pressing the sheet in a press section to a solids content G(x) wt % or greater,
wherein G(x) is defined by:
G ( x )=48+0.4( x− 15)
where x is a numerical value of a filler content of dry paper, card or board in wt % and
G(x) is a numerical value of a minimum solids content to which the sheet is pressed, and
wherein the filler-containing paper stock comprises a water-soluble polymer,
the filler-containing paper stock has a fibrous concentration of from 20 to 40 g/l, and
the water-soluble polymer is obtained by Hofmann degradation of an acrylamide-containing polymer, a methacrylamide-containing polymer, or both with or without subsequent postcrosslinking and the water-soluble polymer is added to the paper stock before adding a filler.
2. A process for producing paper, card and board, the process comprising:
diluting a filler-containing paper stock to a fibrous concentration of from 5 to 15 g/l, thereby forming a diluted paper stock,
draining the diluted paper stock in a wire section, thereby forming a sheet, and
pressing the sheet in a press section to a solids content ≧48 wt %,
wherein the filler-containing paper stock comprises a water-soluble polymer,
the filler-containing paper stock has a fibrous concentration of from 20 to 40 g/l, and
the water-soluble polymer is obtained by Hofmann degradation of an acrylamide-containing polymer, a methacrylamide-containing polymer, or both and subsequent postcrosslinking.
3. The process according to claim 1 ,
wherein the filler-containing paper stock comprises a fibrous material having a freeness of ≦30° SR.
4. The process according to claim 1 , further comprising:
adding the water-soluble polymer in an amount of 0.05 to 5.00 wt %, based on fibrous material.
5. The process according to claim 1 ,
wherein the acrylamide-containing polymer, methacrylamide-containing polymer, or both are obtained by free-radically polymerizing a monomer mixture comprising:
a) acrylamide, methacrylamide, or both,
b) optionally a monoethylenically unsaturated monomer, a diallyldimethylammonium chloride, or both, and
c) optionally a compound having two or more ethylenically unsaturated moieties, wherein corresponding structural units of the monoethylenically unsaturated monomer, or the compound having two or more ethylenically unsaturated moieties, or both in the monomer mixture are stable under a reaction condition of Hofmann degradation.
6. The process according to claim 1 ,
wherein the acrylamide-containing polymer methacrylamide-containing polymer, or both are obtained by free-radically polymerizing a monomer mixture, comprising:
a) 50 to 90 mol % of acrylamide, methacrylamide, or both,
b) 10 to 50 mol % of a monoethylenically unsaturated monomer, diallyldimethylammonium chloride, or both, and
c) up to 1.0 wt %, based on a total weight of monomers a) and b), of a compound having two or more ethylenically unsaturated moieties,
wherein corresponding structural units of the monoethylenically unsaturated monomer, or the compound having two or more ethylenically unsaturated moieties, or both in the monomer mixture are stable under a reaction condition of Hofmann degradation.
7. The process according to claim 1 ,
wherein the water-soluble polymer is obtained by Hofmann degradation of an acrylamide-containing polymer, methacrylamide-containing polymer, or both and subsequent postcrosslinking with a crosslinker selected from the group consisting of a multifunctional epoxide, a multifunctional carboxylic ester, a multifunctional isocyanate, a multifunctional acrylic or methacrylic ester, a multifunctional acrylic or methacrylic amide, epichlorohydrin, a multifunctional acyl halide, a multifunctional nitrile, an α,ω-chlorohydrin ester of an oligoethylene or polyethylene oxide or of other multifunctional alcohol, divinyl sulfone, a maleic anhydride or co-halocarbonyl chloride, a multifunctional haloalkane, and a carbonate.
8. The process according to claim 2 ,
wherein the paper, card and board has a filler content of from 17 to 32 wt %, and
the pressing is pressing to at least a solids content of from 49 to 55 wt %.
9. The process according to claim 2 ,
wherein the paper, card and board has a filler content of 15 wt % or less, and
the pressing is pressing to at least a solids content of 48 wt %.
10. The process according to claim 2 ,
wherein the filler-containing paper stock comprises a fibrous material having a freeness of ≦30° SR.
11. The process according to claim 2 , further comprising:
adding the water-soluble polymer to the paper stock before adding a filler.
12. The process according to claim 2 , further comprising:
adding the water-soluble polymer in an amount of 0.05 to 5.00 wt %, based on fibrous material.
13. The process according to claim 2 ,
wherein the acrylamide-containing polymer, methacrylamide-containing polymer, or both are obtained by free-radically polymerizing a monomer mixture comprising:
a) acrylamide, methacrylamide, or both,
b) optionally a monoethylenically unsaturated monomer, a diallyldimethylammonium chloride, or both, and
c) optionally a compound having two or more ethylenically unsaturated moieties, wherein corresponding structural units of the monoethylenically unsaturated monomer, or the compound having two or more ethylenically unsaturated moieties, or both in the monomer mixture are stable under a reaction condition of Hofmann degradation.
14. The process according to claim 2 ,
wherein the acrylamide-containing polymer, methacrylamide-containing polymer, or both are obtained by free-radically polymerizing a monomer mixture, comprising:
a) 50 to 90 mol % of acrylamide, methacrylamide, or both,
b) 10 to 50 mol % of a monoethylenically unsaturated monomer, diallyldimethylammonium chloride, or both, and
c) up to 1.0 wt %, based on a total weight of monomers a) and b), of a compound having two or more ethylenically unsaturated moieties,
wherein corresponding structural units of the monoethylenically unsaturated monomer, or the compound having two or more ethylenically unsaturated moieties, or both in the monomer mixture are stable under a reaction condition of Hofmann degradation.
15. The process according to claim 2 ,
wherein the water-soluble polymer is obtained by Hofmann degradation of an acrylamide-containing polymer, methacrylamide-containing polymer, or both and subsequent postcrosslinking with a crosslinker selected from the group consisting of a multifunctional epoxide, a multifunctional carboxylic ester, a multifunctional isocyanate, a multifunctional acrylic or methacrylic ester, a multifunctional acrylic or methacrylic amide, epichlorohydrin, a multifunctional acyl halide, a multifunctional nitrile, an α,ω-chlorohydrin ester of an oligoethylene or polyethylene oxide or of other multifunctional alcohol, divinyl sulfone, a maleic anhydride or co-halocarbonyl chloride, a multifunctional haloalkane, and a carbonate.
16. A process for producing paper, card and board, the process comprising:
diluting a filler-containing paper stock to a fibrous concentration of from 5 to 15 g/l, thereby forming a diluted paper stock,
draining the diluted paper stock in a wire section, thereby forming a sheet, and
pressing the sheet in a press section to a solids content G(x) wt % or greater,
wherein G(x) is defined by:
G ( x )=48+0.4( x− 15)
where x is a numerical value of a filler content of dry paper, card or board in wt % and
G(x) is a numerical value of a minimum solids content to which the sheet is pressed, and
wherein the filler-containing paper stock comprises a water-soluble polymer,
the filler-containing paper stock has a fibrous concentration of from 20 to 40 g/l, and
wherein the water-soluble polymer is obtained by Hofmann degradation of an acrylamide-containing polymer, methacrylamide-containing polymer, or both and subsequent postcrosslinking with a crosslinker selected from the group consisting of a multifunctional epoxide, a multifunctional carboxylic ester, a multifunctional isocyanate, a multifunctional acrylic or methacrylic ester, a multifunctional acrylic or methacrylic amide, epichlorohydrin, a multifunctional acyl halide, a multifunctional nitrile, an α,ω-chlorohydrin ester of an oligoethylene or polyethylene oxide or of other multifunctional alcohol, divinyl sulfone, a maleic anhydride or ω-halocarbonyl chloride, a multifunctional haloalkane, and a carbonate.