Method for producing fluorinated copolymer latex, fluorinated copolymer latex, binder for producing electrode, electrode mixture for storage battery device, and electrode for storage battery device
View Patent ↗To produce a method for producing a fluorinated copolymer latex with a low content of metal components and with favorable stability of the latex even with a low content of an organic solvent. A method for producing a fluorinated copolymer latex, which comprises emulsion-polymerizing a monomer mixture containing tetrafluoroethylene and propylene in the presence of an aqueous medium, an anionic emulsifying agent and a thermally decomposable radical polymerization initiator at a polymerization temperature within a range of from 50° C. to 100° C., wherein the aqueous medium comprises water alone, or water and a water-soluble organic solvent, and the content of the water-soluble organic solvent is less than 1 part by mass per 100 parts by mass of water; and the amount of use of the anionic emulsifying agent is from 1.5 to 5.0 parts by mass per 100 parts by mass of the fluorinated copolymer to be formed.
1. A fluorinated copolymer latex, comprising:
an aqueous medium;
a fluorinated copolymer present in a particulate form in the aqueous medium; and
an anionic emulsifying agent contained in the aqueous medium,
wherein the aqueous medium comprises water alone, or water and a water-soluble organic solvent of such that the water-soluble organic solvent is included in an amount of less than 1 part by mass per 100 parts by mass of water,
the anionic emulsifying agent is included in an amount of from 1.5 to 5.0 parts by mass per 100 parts by mass of the fluorinated copolymer,
the fluorinated copolymer latex includes at least one metal component such that a total content of the at least one metal component is at most 0.2 mass % per 100 mass % of the fluorinated copolymer latex, and
the fluorinated copolymer is present in the particulate form having an average particle size of from 20 to 200 nm.
2. The fluorinated copolymer latex according to claim 1 , wherein the fluorinated copolymer latex has an iron content of at most 100 ppm per 100 mass % of the fluorinated copolymer latex.
3. The fluorinated copolymer latex according to claim 1 , wherein the fluorinated copolymer is included in an amount of from 5 to 40 mass % per 100 mass % of the fluorinated copolymer latex.
4. The fluorinated copolymer latex according to claim 1 , wherein the fluorinated copolymer has a mass average molecular weight of from 10,000 to 300,000.
5. The fluorinated copolymer latex according to claim 1 , wherein the average particle size is from 30 to 150 nm.
6. The fluorinated copolymer latex according to claim 1 , wherein the average particle size is from 50 to 150 nm.
7. The fluorinated copolymer latex according to claim 1 , wherein the average particle size is from 50 to 100 nm.
8. The fluorinated copolymer latex according to claim 1 , wherein the anionic emulsifying agent is included in an amount of from 1.5 to 3.8 parts by mass per 100 parts by mass of the fluorinated copolymer.
9. The fluorinated copolymer latex according to claim 1 , wherein the anionic emulsifying agent is included in an amount of from 1.7 to 3.2 parts by mass per 100 parts by mass of the fluorinated copolymer.
10. The fluorinated copolymer latex according to claim 1 , wherein the fluorinated copolymer is included in an amount of from 25 to 35 mass % per 100 mass % of the fluorinated copolymer latex.
11. A binder for producing an electrode of a storage battery device, comprising:
the fluorinated copolymer latex according to claim 1 .
12. An electrode mixture for a storage battery device, comprising:
the fluorinated copolymer latex according to claim 1 ; and
an electrode active material.
13. An electrode for a storage battery device, comprising:
a current collector; and
an electrode active material layer formed on the current collector and made from the electrode mixture according to claim 12 .