Conformable materials containing heat transfer nanoparticles and devices made using same
View Patent ↗In one aspect, a method of forming a shape conforming material is disclosed that in one non-limiting embodiment may include: providing a base shape memory material having a glass transition temperature; and adding a selected amount of heat transfer nanoparticles to the base shape conforming material to provide the shape conforming material. In one aspect, the heat transfer nanoparticles include a core and a shell, wherein the core has a melting point below the glass transition temperature of the base shape memory material and the melting point of the shell.
1. A method of making a shape conforming material for use in a wellbore, comprising:
providing a shape memory material having a glass transition temperature that is above a temperature of the wellbore; and
adding a selected amount of heat transfer nanoparticles to the shape memory material to provide the shape conforming material, wherein the heat transfer nanoparticles include a core and a shell, wherein the core stores heat energy when the shape memory material is heated by a heat source above its glass transition temperature and supplies heat to the shape memory material for expansion of the shape memory material after the heat source is removed.
2. The method of claim 1 , wherein the core has a melting point below the glass transition temperature of the shape memory material and the melting point of the shell.
3. The method of claim 2 , wherein the core includes a material selected from a group consisting of: bismuth; a eutectic salt; a polymer; tin; lead; a salt hydrate; a metallic material; a wax; an oil; a fatty acid; and a polyglycol.
4. The method of claim 2 , wherein the shell includes a material selected from a group consisting of: a metal; carbon; silica; graphene; graphite; a diamond-like carbon; carbon nitride; boron nitride; iron; nickel; cobalt and zinc; a metal oxide; a nitride; a carbide; and a polymer.
5. The method of claim 2 , wherein the core size is between 1 nm and 40 nm and thickness of the shell is at least 0.05 nm.
6. A method of forming an apparatus for use in a wellbore, comprising:
providing a shape conforming material that contains a base shape memory material having a glass transition temperature above a wellbore temperature and a selected amount of heat transfer nanoparticles, wherein the heat transfer nanoparticles have a core and a shell, wherein the core stores heat energy when heat is applied to the shape memory material from a heat source and supplies heat to the shape memory material for expansion of the shape memory material after the heat source is removed; and
forming the apparatus for use in the wellbore by heating the shape conforming material above the glass transition temperature.
7. The method of claim 6 , wherein the apparatus is selected from a group consisting of: a packer; a sand screen; and an inflow control device.
8. The method of claim 6 further comprising incorporating the apparatus into a string for deployment into the wellbore for performing an operation selected from a group consisting of: production of a fluid from a formation surrounding the wellbore; and treating a formation surrounding the wellbore.
9. The method of claim 6 , wherein the core has a melting point below the glass transition temperature.
10. The method of claim 6 , wherein forming the apparatus comprises:
heating the shape conforming material to or above the glass transition temperature to expand the shape conforming material to attain an expanded shape;
compressing the shape conforming material from the expanded shape to a compressed shape; and
reducing the temperature of the compressed shape to a temperature below the melting point of the core.
11. The method of claim 6 , wherein the core includes a material selected from a group consisting of: bismuth; a eutectic salt; a polymer, tin, lead, a salt hydrate, a metallic material; a wax, an oil, a fatty acid; a polyglycol; and a combination thereof.
12. The method of claim 6 , wherein the shell includes a material selected from a group consisting of a metal; carbon; a polymer; silica; graphene; graphite; a diamond-like carbon; carbon nitride; boron nitride; iron; nickel; cobalt and zinc; a metal oxide; a nitride; a carbide; and a polymer that is stable at a selected temperature.
13. An apparatus for use in a wellbore, comprising:
a device having a shape memory member that includes a base shape memory material having a glass transition temperature above a wellbore temperature and a selected amount heat transfer nanoparticles, wherein each nanoparticle includes a shell and a core therein that is configured to melt within the shell to store heat energy when heat is applied to the shape memory material from a heat source and to supply heat to the shape memory material for expansion of the shape memory material after the heat source is removed, and wherein the shape conforming material in the device is in a compressed shape previously obtained by compressing the shape conforming material from an expanded shape at or above the glass transition temperature.
14. The apparatus of claim 13 , wherein:
the shape memory material expands to the expanded shape when heated to or above the glass transition temperature; and
the core melts within the shell at a temperature below the glass transition temperature of the shape memory material to store heat energy.
15. The apparatus of claim 13 , wherein:
the core includes a material selected from a group consisting of: bismuth; a eutectic salt; a polymer; tin; lead; a salt hydrate; a metallic material; a wax; an oil; a fatty acid; a polyglycol; and a combination thereof; and
the shell includes a material selected from a group consisting of: a metal; carbon; a polymer; silica; graphene; graphite; a diamond-like carbon; carbon nitride; boron nitride; iron; nickel; cobalt and zinc; a metal oxide; a nitride; a carbide; and a polymer that is stable at a selected temperature.
16. The apparatus of claim 13 , wherein the selected amount of the heat transfer nanoparticles is between 1% to 20% by weight or volume of the base shape memory material.
17. The apparatus of claim 13 , wherein the device is carried by a tubular member of a string for deployment of the device into a wellbore.
18. The apparatus of claim 13 , wherein the device is one of a: packer; sand screen; a flow control device for controlling flow of a fluid therethrough and a combination thereof.
19. A system for use in a wellbore, comprising:
a string containing a tubular and a device for performing an operation in the wellbore, wherein the device includes a shape conforming member that includes a base shape memory material having a glass transition temperature above a temperature of the wellbore and a selected amount of heat transfer nanoparticles, wherein each nanoparticle includes a shell and a core therein that is configured to melt within the shell to store heat energy when heat is applied to the shape memory material from a heat source and to supply heat to the shape memory material for expansion of the shape memory material after the heat source is removed, and wherein the shape conforming material in the device is in a compressed shape obtained by compressing the shape conforming material from an expanded shape at or above the glass transition temperature prior to placing the device in the wellbore.
20. A method of making a shape conforming device, comprising:
providing a base material that expands when exposed to a heated fluid;
adding a selected amount of heat transfer nanoparticles to the base shape memory material to provide a shape conforming material, wherein each heat transfer nanoparticle includes a shell and a core, wherein the core melts within the shell to store heat energy when heat is applied to the shape memory material from a heat source and to supply heat to the shape memory material for expansion of the shape memory material after the heat source is removed; and
using the shape conforming material to form the shape conforming device.