Aqueous 1K Coating System and Method for Improving the Appearance of Grained Wood Surfaces
The invention is directed to a one-component (1K) coating system comprising an aqueous polyurethane and/or polyurethane-polyacrylate polymer dispersion and one or more compounds of elements of sub-groups 5 and/or 6 of the periodic table in which the particular element has an oxidation state of at least +4. The invention also relates to a method for improving the appearance of grained wood surfaces, the use of a coating system according to the invention for the coating of grained wood surfaces and a grained wood surface comprising a coating obtained by applying a coating system according to the invention and subsequent drying of the coating system.
1 . A one-component coating system comprising an aqueous polyurethane and/or polyurethane-polyacrylate polymer dispersion, and at least one compound comprising
an element of sub-group 5 and/or 6 of the periodic table in which the element comprises an oxidation state of at least +4.
2 . The coating system according to claim 1 , wherein the polyurethane polymer is obtainable by reaction of a mixture comprising:
a) at least one polyisocyanate,
b) at least one polyol comprising an average molar weight M n of ≧500 g/mol to ≦6000 g/mol,
c) optionally, at least one polyol comprising an average molar weight M n of ≧62 g/mol to ≦500 g/mol,
d) at least one isocyanate-reactive, ionically or potentially ionically hydrophilicizing compound and/or isocyanate-reactive nonionically hydrophilicizing compound,
e) optionally, at least one polyamine comprising an average molecular weight of ≦500 g/mol,
f) optionally, at least one monoalcohol and/or monoamine comprising an average molar weight M n of ≦248 g/mol.
3 . The coating system according to claim 2 , wherein the mixture further comprises g) ethylenically unsaturated monomers containing no Zerewitinoff-active hydrogen atoms.
4 . The coating system according to claim 1 , wherein the polyurethane-polyacrylate polymer is obtainable by reaction of a mixture comprising at least one polyisocyanate, at least one polyol and/or at least one polyhydroxyl polyacrylate.
5 . The coating system according to claim 1 , wherein said compound of an element of sub-group 5 and/or 6 of the periodic table is selected from the group consisting of vanadium, tantalum, molybdenum and tungsten.
6 . The coating system according to claim 5 , wherein said compound of an element of sub-group 5 and/or 6 of the periodic table is selected from the group consisting of ammonium molybdate, lithium molybdate, sodium molybdate, potassium molybdate, rubidium molybdate, caesium molybdate, ammonium paramolybdate, molybdenyl-bis-acetylacetonate, molybdenum dioxide tetramethyl heptadionate, molybdenum alcoholates of 1,2-, 1,3- and/or 1,4-diols, molybdenum oxides, tetraethylammonium molybdate, magnesium molybdate and calcium molybdate.
7 . The coating system according to claim 1 , wherein said compound of an element of sub-group 5 and/or 6 of the periodic table is present in an amount of ≧0.0001 wt. % to ≦0.1 wt. % in the aqueous dispersion.
8 . A method for improving appearance of grained wood surfaces, comprising:
providing a grained wood surface; and
applying a coating system according to claim 1 to said grained wood surface.
9 . A coating system according to claim 1 , capable of being used for coating a grained wood surface.
10 . A grained wood surface comprising a coating obtained by applying a coating system according to claim 1 and subsequent drying of the coating system.