DIAMINO ALCOHOL AND STRONG BASE NEUTRALIZERS FOR LOW VOC COATING COMPOSITIONS
A coating composition comprising a binder, a carrier, a pigment, cations selected from the group consisting of alkali metal cations, ammonium cations, and mixtures thereof, and at least one diamino alcohol selected from the group consisting of compounds of Formula I and compounds of Formula II. The present invention also provides a method for reducing the volatile organic compound (VOC) content of a coating composition having a binder, a carrier, and a pigment, which comprises including in the coating composition the aforesaid A) cations and B) at least one diamino alcohol. The diamino alcohol may be of Formula I: wherein R 1 and R 2 are independently C 1 -C 10 alkyl, or R 1 and R 2 , together with the carbon to which they are attached, form a C 3 -C 12 cycloalkyl ring optionally substituted with C 1 -C 6 alkyl. For example, the compound of Formula I may be 2-(2-amino-2-methylpropylamino)-2-(hydroxymethyl)propane-1,3-diol. Alternatively, the diamino alcohol may be of Formula II: or salt thereof, wherein R 1 and R 2 are independently at each occurrence C 1 -C 6 alkyl; and R 3 is independently at each occurrence H or C 1 -C 6 alkyl. For example, the compound of Formula II may be 2,2′-((2-hydroxytrimethylene)diimino)bis(2-methyl-1-propanol).
1 . A coating composition comprising a binder, a carrier, a pigment, cations selected from the group consisting of alkali metal cations, ammonium cations, and mixtures thereof, and at least one diamino alcohol selected from the group consisting of:
A) a compound of Formula I as follows:
wherein, wherein R 1 and R 2 are independently C 1 -C 10 alkyl, or R 1 and R 2 , together with the carbon to which they are attached, form a C 3 -C 12 cycloalkyl ring optionally substituted with C 1 -C 6 alkyl; and
B) a compound of Formula II as follows:
or salt thereof, wherein R 1 and R 2 are independently at each occurrence C 1 -C 6 alkyl; and R 3 is independently at each occurrence H or C 1 -C 6 alkyl.
2 . The coating composition according to claim 1 , wherein said at least one diamino alcohol is a compound of Formula I which comprises 2-((1-aminocyclohexyl)methylamino)-2-(hydroxymethyl)propane-1,3-diol.
3 . The coating composition according to claim 1 , wherein said at least one diamino alcohol is a compound of Formula II which comprises 2,2′-((2-hydroxytrimethylene)diimino)bis(2-methyl-1-propanol).
4 . The coating composition according to claim 1 , wherein said carrier comprises water and said coating composition is an aqueous paint composition.
5 . The coating composition according to claim 1 , having a volatile organic compound (VOC) content of less than 50 grams per liter of VOC, based on the total volume of said coating composition.
6 . A method for reducing the volatile organic compound (VOC) content of a coating composition having a binder, a carrier, and a pigment, said method comprising including in the coating composition:
A) cations selected from the group consisting of alkali metal cations, ammonium cations, and mixtures thereof; and
B) an effective amount of at least one diamino alcohol selected from the group consisting of:
1) a compound of Formula I as follows:
wherein, wherein R 1 and R 2 are independently C 1 -C 10 alkyl, or R 1 and R 2 , together with the carbon to which they are attached, form a C 3 -C 12 cycloalkyl ring optionally substituted with C 1 -C 6 alkyl; and
2) a compound of Formula II as follows:
or salt thereof, wherein R 1 and R 2 are independently at each occurrence C 1 -C 6 alkyl; and R 3 is independently at each occurrence H or C 1 -C 6 alkyl.
7 . The method according to claim 6 , wherein said at least one diamino alcohol is a compound of Formula I which comprises 2-((1-aminocyclohexyl)methylamino)-2-(hydroxymethyl)propane-1,3-diol.
8 . The method according to claim 6 , wherein said at least one diamino alcohol is a compound of Formula II which comprises 2,2′-((2-hydroxytrimethylene)diimino)bis(2-methyl-1-propanol).
9 . The method according to claim 6 , wherein said carrier comprises water and said coating composition is an aqueous paint composition.
10 . The method according to claim 6 , wherein the volatile organic compound (VOC) content of said coating composition is less than 50 grams per liter of VOC, based on the total volume of said coating composition.