IP Library Granted Patent US 10,562,048
Granted Patent B2
US 10,562,048 · App. 13/979,260 · Granted Feb 18, 2020

Electrohydrodynamic atomization nozzle emitting a liquid sheet

Inventors: Daren Chen (St. Louis, MO); Jingjie Zhang (St. Louis, MO)
Assignee: Nanocopoeia, LLC
B05B5/0533B01J2/04B05B1/044B05B1/06B05B5/0255B05B7/061B05B7/065
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Quick Facts
Patent No.
US 10,562,048
App. No.
13/979,260
Granted
Feb 18, 2020
Kind
B2
Abstract

Embodiments for producing un-agglomerated, monodisperse droplets using a liquid sheet are provided. Nozzles with exit slit openings shape a spray liquid into a thin liquid sheet as the spray liquid exits from the slit opening. Stable multi-jet operation is achieved by including notches along the edge of the slit. The notches separate the liquid sheet into multiple jets to provide anchoring and stable multi jet operation. In some embodiments, the liquid sheet electrospray techniques and nozzles described herein provide high mass throughput and versatile multiplexing spray systems while reducing the engineering effort and high manufacturing cost.

Claims (35)

1. A nozzle for electrohydrodynamic

atomization, said nozzle comprising:

an inner rod having an outer surface;

an outer tube concentrically aligned with and spaced from said inner rod, said outer tube having an inner surface and a length;

a longitudinally extending channel defined between said inner rod and said outer tube, said channel defining a circular slit, the circular slit having a width defined by said outer surface of said inner rod and said inner surface of said outer tube; and

at least one electrically chargeable notch located on said inner rod and proximate said circular slit,

wherein said inner rod extends beyond the length of the outer tube such that at least a portion of the outer surface of the inner rod is exposed to the inner surface of the outer tube, the at least one electrically chargeable notch being spaced from the outer tube.

2. A nozzle in accordance with claim 1 , wherein said inner rod comprises a central flow channel defined therethrough.

3. A nozzle in accordance with claim 2 , wherein said central flow channel is configured to facilitate flow of at least one of a stabilizing gas and a stabilizing liquid therethrough.

4. A nozzle in accordance with claim 1 , wherein said outer tube is free of electrically chargeable notches.

5. A nozzle in accordance with claim 1 , wherein said inner rod comprises a center piece at the spray end of said nozzle and said outer tube comprises an end portion at the spray end of said nozzle, said center piece extended with respect to said end portion.

6. A nozzle in accordance with claim 1 , wherein said at least one electrically chargeable notch comprises a plurality of electrically chargeable notches, each notch of said plurality of electrically chargeable notches being spaced a distance apart from one another.

7. A system for electrohydrodynamic atomization, said system comprising:

a nozzle comprising:

a source end;

a spray end;

a first component comprising a first surface;

a second component comprising a second surface and being aligned with said first component, said second surface being spaced from said first surface of said first component;

longitudinally extending fluid channel defined between said first surface and said second surface, said fluid channel defining an exit slit, said exit slit being continuous and having a width defined by said first surface of said first component and said second surface of said second component;

at least one electrically chargeable notch located on said first component proximate said exit slit;

a voltage source electrically coupled to said nozzle and configured to supply a voltage to said at least one electrically chargeable notch; and

a pump in flow communication with said source end of said nozzle, said pump configured to provide a spray liquid through said nozzle,

wherein said first component extends beyond the length of the second component such that at least a portion of the outer surface of the first component is exposed from the inner surface of the second component, the at least one electrically chargeable notch being spaced from the second component.

8. A system according to claim 7 , wherein said first component comprises a first plate and said second component comprises a second plate, such that said fluid channel is substantially planar.

9. A system according to claim 7 , further comprising a nozzle means for emitting a liquid sheet.

10. A system in accordance with claim 7 , further comprising notch means comprising a plurality of the electrically chargeable notches for separating a liquid sheet emitted from said nozzle into multiple, discrete jets.

11. A system in accordance with claim 7 , further comprising means for maintaining a shape of a liquid sheet emitted from said nozzle.

12. A system in accordance with claim 7 , wherein said at least one electrically chargeable notch comprises a first notch and a second notch, said first and second notches spaced a distance apart from one another such that when a voltage is supplied to said first and second notches, an electric field produced by said first notch does not interfere with an electric field produced by said second notch.

13. A method for electrohydrodynamic atomization, said method comprising:

providing a nozzle comprising an inner rod having an outer surface, an outer tube concentrically aligned with and spaced from the inner rod, the outer tube having an inner surface and a length, a longitudinally extending channel defined between the inner rod and the outer tube, the channel defining a slit, the slit having a width defined by the outer surface of the inner rod and the inner surface of the outer tube, and a plurality of notches located on at least the inner rod and proximate the circular slit wherein said inner rod extends beyond the length of the outer tube such that at least a portion of the outer surface of the inner rod is exposed from the inner surface of the outer rod, the plurality of notches being spaced from the outer tube;

supplying a voltage to the plurality of notches; and

pumping the spray liquid to the annular channel of the nozzle.

14. A method in accordance with claim 13 , wherein the inner rod includes a central flow channel defined therethrough, said method further comprising pumping a stabilizing gas through the central flow channel.

15. A method in accordance with claim 13 , wherein the inner rod includes a central flow channel defined therethrough, said method further comprising pumping a stabilizing liquid through the central flow channel.

16. A method in accordance with claim 13 , wherein supplying a voltage comprises supplying a voltage such that a jet of spray liquid is formed at each of the plurality of notches.

Assignments (8)
CHANGE OF NAME Recorded May 5, 2025
From: PXMMI, LLC
To: FLEX PHARMA, LLC
Reel/Frame 071181/0369 →
NUNC PRO TUNC ASSIGNMENT Recorded Apr 24, 2025
From: NANOCOPOEIA, LLC
To: PXMMI, LLC
Reel/Frame 070939/0374 →
SECURITY INTEREST Recorded Mar 27, 2025
From: PXMMI, LLC
To: DAVID R. FRAUENSHUH, SOLELY IN HIS CAPACITY AS TRUSTEE OF THE DAVID R. FRAUENSHUH REVOCABLE TRUST DATED MARCH 16, 1990
Reel/Frame 070666/0179 →
AFFIDAVIT RE: ASSGNMENT FOR THE BENEFIT OF CREDITORS (MINNESOTA STATE COURT FILE NO. 62-CV-24-5879) Recorded Mar 11, 2025
From: NANOCOPOEIA, LLC
To: LIGHTHOUSE MANAGEMENT GROUP, INC.
Reel/Frame 070733/0519 →
AFFIDAVIT RE: ASSGNMENT FOR THE BENEFIT OF CREDITORS (MINNESOTA STATE COURT FILE NO. 62-CV-24-5879) Recorded Mar 11, 2025
From: LIGHTHOUSE MANAGEMENT GROUP, INC.
To: NANOCOPOEIA, LLC
Reel/Frame 070908/0001 →
CHANGE OF ADDRESS Recorded Sep 14, 2021
From: NANOCOPOEIA, LLC
To: NANOCOPOEIA, LLC
Reel/Frame 057500/0557 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 19, 2019
From: WASHINGTON UNIVERSITY
To: NANOCOPOEIA, LLC
Reel/Frame 050430/0557 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 18, 2013
From: CHEN, DA-REN; ZHANG, JINGJIE
To: WASHINGTON UNIVERSITY
Reel/Frame 030825/0840 →
Continuity (2)
Provisional Application 61434249 · Jan 19, 2011
Related Publication 20140158787A1 · Jun 12, 2014
Cited By (6)
US 12,398,360 US 12,433,891 US 12,465,606 US 12,478,625 US 12,544,376 US 12,558,355