IP Library Granted Patent US 8,834,836
Granted Patent B2
US 8,834,836 · App. 13/980,765 · Granted Sep 16, 2014

Method for producing MTW-type zeolite

Inventors: Keiji Itabashi (Tokyo, JP); Yoshihiro Kamimura (Tokyo, JP); Tatsuya Okubo (Tokyo, JP)
Assignee: Unizeo Co., Ltd
C01B39/46C01B39/42
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Quick Facts
Patent No.
US 8,834,836
App. No.
13/980,765
Granted
Sep 16, 2014
Kind
B2
Abstract

Provided is a method for producing an MTW-type zeolite. The reaction mixture contains a silica source, an alumina source, an alkali source, and water is reacted with a seed crystal of a zeolite to produce an MTW-type zeolite. The reaction mixture has a composition, which makes a synthesized zeolite contain an MFI-type zeolite when the zeolite is synthesized solely from the reaction mixture, is used. As the seed crystal, a beta-type zeolite which has a ratio of SiO 2 /Al 2 O 3 of 8 to 50 and does not contain a structure direction agent is used. The seed crystal is added to the reaction mixture, in a proportion of 0.1% by mass to 20% by mass based on a silica component in the reaction mixture. The reaction mixture to which the seed crystal has been added is heated at 100° C. to 200° C. in a sealed state.

Claims (21)

1. A method for producing a MTW-type zeolite, comprising:

providing a reaction mixture containing a silica source, an alumina source, an alkali source, and water with a seed crystal of a zeolite, wherein the reaction mixture does not contain a structure directing agent; wherein the seed crystal is added to the reaction mixture in a proportion of 0.1% by mass to 20% by mass based on a silica component in the reaction mixture; and

heating the reaction mixture at 100° C. to 200° C. in a sealed state,

wherein without the seed crystal, the reaction mixture produces a MFI-type zeolite, and

wherein the seed crystal is a beta-type zeolite that has a molar ratio of SiO 2 /Al 2 O 3 of 8 to 50 and does not contain a structure directing agent.

2. The method according to claim 1 ,

wherein the reaction mixture has a composition represented by the following molar ratio;

SiO 2 /Al 2 O 3 =10 to 150

Na 2 O/SiO 2 =0.075 to 0.23

H 2 O/SiO 2 =5 to 50.

3. The method according to claim 2 ,

wherein the reaction mixture has a composition represented by the following molar ratio:

SiO 2 /Al 2 O 3 =30 to 120

Na 2 O/SiO 2 =0.1 to 0.2

H 2 O/SiO 2 =8 to 20.

4. The method according to claim 1 ,

wherein the reaction mixture to which the seed crystal has been added is heated at 120° C. to 180° C. in a sealed state.

5. The method according to claim 1 ,

wherein the reaction mixture is matured at 20° C. to 100° C. before being heated.

6. The method according to claim 1 ,

wherein the reaction mixture is stirred during heating in a sealed state.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 23, 2018
From: UNIZEO CO., LTD.
To: MITSUI MINING & SMELTING CO., LTD.; THE UNIVERSITY OF TOKYO
Reel/Frame 045127/0009 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 6, 2014
From: NIPPON CHEMICAL INDUSTRIAL CO., LTD.
To: UNIZEO CO., LTD.
Reel/Frame 032369/0028 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 10, 2013
From: ITABASHI, KEIJI; KAMIMURA, YOSHIHIRO; OKUBO, TATSUYA
To: NIPPON CHEMICAL INDUSTRIAL CO., LTD.; THE UNIVERSITY OF TOKYO
Reel/Frame 031175/0586 →
Priority Claims (1)
JP 2011-014808 · Jan 27, 2011 · national
Continuity (1)
Related Publication 20130343986A1 · Dec 26, 2013