Anode containing active material-coated graphene sheets and lithium-ion batteries containing same
View Patent ↗The present invention provides an anode electrode of a lithium-ion battery, comprising an anode active material-coated graphene sheet, wherein the graphene sheet has two opposed parallel surfaces and at least 50% area of one of the surfaces is coated with an anode active material and wherein the graphene material is in an amount of from 0.1% to 99.5% by weight and the anode active material is in an amount of at least 0.5% by weight (preferably at least 60%), all based on the total weight of the graphene material and the anode active material combined.
1. An anode electrode of a lithium-ion battery, comprising an anode active material-coated graphene sheet, wherein said graphene sheet has two opposed parallel surfaces and at least 50% area of one of said surfaces is coated with an anode active material coating wherein said graphene sheet is used as a supporting substrate and a primary surface of said anode active material coating is completely supported by said graphene sheet, and wherein said graphene material is in an amount of from 0.1% to 99.5% by weight and said anode active material is in an amount of at least 0.5% by weight, all based on the total weight of said graphene material and said anode active material combined and wherein said graphene sheet is selected from a single-layer graphene or few-layer graphene having up to 10 graphene planes or 5 nm in thickness and said graphene material is selected from pristine graphene, graphene fluoride, graphene bromide, graphene iodide, boron-doped graphene, nitrogen-doped graphene, chemically functionalized graphene, a combination thereof, or a combination thereof with graphene oxide or reduced graphene oxide and wherein said active material coating has a thickness from 1 nm to 20 nm, wherein said anode active material-coated graphene sheet is a part of a secondary particle.
2. The anode electrode of claim 1 , wherein at least 80% area of one of said surfaces is coated with an anode active material.
3. The anode electrode of claim 1 , wherein said coated graphene sheet contains from 60% to 90% by weight or by volume of said anode active material based on the total weight of said coated graphene sheet.
4. The anode electrode of claim 1 , wherein said coated graphene sheet contains at least 90% by weight or by volume of said anode active material based on the total weight of said coated graphene sheet.
5. The anode electrode of claim 1 , wherein said anode active material is in an amount from 60% to 80% by weight.
6. The anode electrode of claim 1 , wherein said anode active material is in an amount of at least 80% by weight.
7. The anode electrode of claim 1 , wherein said anode active material is selected from the group consisting of:
(A) silicon (Si), germanium (Ge), tin (Sn), lead (Pb), antimony (Sb), bismuth (Bi), zinc (Zn), aluminum (Al), titanium (Ti), nickel (Ni), cobalt (Co), and cadmium (Cd);
(B) alloys or intermetallic compounds of Si, Ge, Sn, Pb, Sb, Bi, Zn, Al, Ti, Ni, Co, or Cd with other elements;
(C) oxides, carbides, nitrides, sulfides, phosphides, selenides, and tellurides of Si, Ge, Sn, Pb, Sb, Bi, Zn, Al, Ti, Fe, Ni, Co, or Cd, and their mixtures, composites, or lithium-containing composites;
(D) salts and hydroxides of Sn;
(E) lithium titanate, lithium manganate, lithium aluminate, lithium-containing titanium oxide, lithium transition metal oxide; and
(F) combinations thereof.
8. The anode electrode of claim 1 , wherein said graphene material is selected from pristine graphene, graphene oxide, reduced graphene oxide, graphene fluoride, graphene bromide, graphene iodide, boron-doped graphene, nitrogen-doped graphene, chemically functionalized graphene, or a combination thereof, and said graphene material comprises single-layer or less than 10 graphene planes.
9. The anode electrode of claim 1 , wherein said anode active material comprises Sn or Si as a primary element with Si or Sn content no less than 20% by weight based on the total weight of the anode active material.
10. The anode electrode of claim 1 , wherein said anode active material comprises an element selected from Si, Ge, Sn, Cd, Sb, Pb, Bi, Zn, Al, Co, Ni, or Ti.
11. The anode electrode of claim 1 , wherein said anode active material coating has a thickness less than 20 nm.
12. The anode electrode of claim 1 , further comprising a carbon or graphite material therein.
13. The anode electrode of claim 12 , wherein said carbon or graphite material is selected from polymeric carbon, amorphous carbon, chemical vapor deposition carbon, coal tar pitch, petroleum pitch, meso-phase pitch, carbon black, coke, acetylene black, activated carbon, fine expanded graphite particle with a dimension smaller than 100 nm, artificial graphite particle, natural graphite particle, or a combination thereof.
14. A lithium-ion battery containing an anode electrode of claim 1 , a cathode electrode, a porous separator and/or electrolyte in contact with said anode electrode and said cathode electrode.
15. The lithium-ion battery of claim 14 , further comprising an anode current collector and/or a cathode current collector.
16. A process for producing an anode electrode of claim 1 , said process comprising:
(a) providing a continuous film of a graphene material into a deposition zone;
(b) introducing vapor or atoms of a precursor anode active material into said deposition zone and depositing said vapor or atoms onto a surface of said graphene material to form a coated film of an anode active material-coated graphene material; and
(c) mechanically breaking said coated film into multiple pieces of anode active material-coated graphene sheets; and
(d) combining multiple pieces of anode active material-coated graphene sheets with an optional binder resin to form said anode electrode.
17. An anode electrode of a lithium-ion battery, comprising multiple anode active material-coated graphene sheets constituting one or multiple secondary particles, wherein each of said graphene sheets has two opposed parallel surfaces and at least 50% area of one of said surfaces is coated with an anode active material coating wherein said graphene sheet is used as a supporting substrate and a primary surface of said anode active material coating is completely supported by said graphene sheet, and wherein said graphene material is in an amount of from 0.1% to 99.5% by weight and said anode active material is in an amount of at least 0.5% by weight, all based on the total weight of said graphene material and said anode active material combined and wherein said graphene sheet is selected from a single-layer graphene or few-layer graphene having up to 10 graphene planes or 5 nm in thickness and said active material coating has a thickness from 1 nm to 20 nm, wherein said one or multiple secondary particles is ellipsoidal in shape with a major axis less than 10 μm.
18. An anode electrode of a lithium-ion battery, comprising multiple secondary particles each consisting essentially of multiple anode active material-coated graphene sheets, an optional resin binder, and an optional conductive filler, wherein each of said graphene sheets has two opposed parallel surfaces and at least 50% area of one of said surfaces is coated with an anode active material coating wherein said graphene sheet is used as a supporting substrate and a primary surface of said anode active material coating is completely supported by said graphene sheet, and wherein said graphene material is in an amount of from 0.1% to 99.5% by weight and said anode active material is in an amount of at least 0.5% by weight, all based on the total weight of said graphene material and said anode active material combined and wherein said graphene sheet is selected from a single-layer graphene or few-layer graphene having up to 10 graphene planes or 5 nm in thickness and said active material coating has a thickness from 1 nm to 20 nm.