Solid electrolyte cell and positive electrode active material
View Patent ↗The present technology is able to provide a solid electrolyte cell that uses a positive electrode active material which has a high ionic conductivity in an amorphous state, and a positive electrode active material which has a high ionic conductivity in an amorphous state. The solid electrolyte cell has a stacked body, in which, a positive electrode side current collector film, a positive electrode active material film, a solid electrolyte film, a negative electrode potential formation layer and a negative electrode side current collector film are stacked, in this order, on a substrate. The positive electrode active material film is made up with an amorphous-state lithium phosphate compound that contains Li; P; an element M 1 selected from Ni, Co, Mn, Au, Ag, and Pd; and O, for example.
1. A solid electrolyte cell, comprising:
a positive electrode active material; and
a solid electrolyte;
wherein the positive electrode active material includes:
an amorphous-state lithium phosphate compound containing Li; P; an element M1 selected from Ni, Au, Ag and Pd; and O,
at least one element M2 selected from Ni, Co, Mn, Au, Ag, Pd and Cu (provided M1≠M2), and
at least one element M3 selected from B, Mg, Al, Ga, Ge, In, Sn, Sb and Bi.
2. The solid electrolyte cell according to claim 1 ,
wherein the lithium phosphate compound is represented by Li x Ni y PO 4 , and
wherein x represents the composition ratio of lithium; y represents the composition ratio of nickel; x is 0<x<8.0; and y is 2.0≦y≦10.
3. The solid electrolyte cell according to claim 1 , comprising:
a positive electrode active material layer containing the positive electrode active material; and
a solid electrolyte layer containing the solid electrolyte.
4. The solid electrolyte cell according to claim 3 , comprising:
a positive electrode side layer having the positive electrode active material layer; and
a negative electrode side layer;
the solid electrolyte layer being located between the positive electrode side layer and the negative electrode side layer.
5. The solid electrolyte cell according to claim 4 , wherein
the negative electrode side layer is made up with a negative electrode current collector layer and a negative electrode side potential formation layer, and
at the time of charging, a lithium excess layer is formed at an interface on the negative electrode side of the solid electrolyte layer.
6. The solid electrolyte cell according to claim 4 , wherein
the positive electrode side layer is made up with the positive electrode active material layer and a positive electrode current collector layer.
7. The solid electrolyte cell according to claim 4 , wherein
the negative electrode side layer is made up with a negative electrode current collector layer, and
at the time of charging, a lithium excess layer is formed at an interface on the negative electrode side layer of the solid electrolyte layer.
8. The solid electrolyte cell according to claim 4 , further comprising a substrate,
wherein a stacked body including the positive electrode side layer, the negative electrode side layer and the solid electrolyte layer are formed on the substrate.
9. The solid electrolyte cell according to claim 8 , wherein
the substrate is a resin substrate.
10. The solid electrolyte cell according to claim 4 , wherein
the positive electrode side layer, the negative electrode side layer and the solid electrolyte layer are formed by thin films.
11. The solid electrolyte cell according to claim 3 , wherein
at least the positive electrode active material layer is formed by a thin film.
12. A positive electrode active material, comprising:
a lithium phosphate compound containing Li; P; an element M1 selected from Au, Ag, and Pd; and O;
at least one element M2 selected from Ni, Co, Mn, Au, Ag, Pd and Cu (provided M1≠M2); and
at least one element M3 selected from B, Mg, Al, Ga, Ge, In, Sn, Sb and Bi,
wherein the lithium phosphate compound is in an amorphous state.