Engine lubricant composition
View Patent ↗Lubricant compositions include: (a) one or more polyalkylene glycol base oils obtained by polymerization or copolymerization of alkylene oxides comprising from 3 to 8 carbon atoms, include at least one butylene oxide and (b) at least one detergent chosen from salicylates or phenates. The present disclosure also relates to: 1) use of a lubricant composition as engine oil, preferably as oil for the engines of petrol or diesel motor vehicles; 2) use of a group of additives for an engine lubricant comprising polyalkylene glycol bases obtained by polymerization or copolymerization of alkylene oxides comprising from 3 to 8 carbon atoms; and 3) use of at least one additive chosen from salicylates, phenates, dithiocarbamates, amine-based or phenol-based antioxidants, preferably from salicylates or phenates, for reducing the Noack volatility of the base oils of polyalkylene glycol type, obtained from alkylene oxides comprising from 3 to 8 carbon atoms.
1. A lubricant composition comprising:
(a) a single base oil of the lubricant composition consisting of:
(i) at least one polyalkylene glycol base oil obtained by reacting at least one alcohol comprising from 8 to 20 carbon atoms and a mixture of butylene oxide and propylene oxide, the mixture having a mass ratio of butylene oxide over propylene oxide comprised between 3:1 and 1:3, said polyalkylene glycol base oil having a molar mass measured according to the ASTM D2502 standard comprised between 300 and 1,000 grams per mole, and a kinematic viscosity at 100° C. measured according to the ASTM D445 standard comprised between 1 and 12 cSt,
wherein lubricant composition is devoid of a polyalkylene glycol obtained or partly obtained from ethylene oxide,
(ii) at least one oil of API group classification III, and
(iii) optionally at least one oil of API group classification I, II, or IV; and
(b) from 0.2 to 2% of at least one detergent selected from salicylates or phenates.
2. The composition according to claim 1 , wherein the polyalkylene glycol base oil (i) is such that the alcohol with which it may be obtained includes from 8 to 12 carbon atoms.
3. The composition according to claim 1 , wherein the polyalkylene glycol base oil (i) is such that the alcohol with which it may be obtained is selected from monoalcohols.
4. The composition according to claim 1 , wherein the polyalkylene base oil (i) has a mass ratio of carbon over oxygen of at least 3:1.
5. The lubricant composition according to claim 1 , wherein a Noack volatility, measured according to a CEC L 40-93 standard, is less than 15%.
6. The lubricant composition according to claim 1 , wherein the polyalkylene glycol base oil (i) is a majority component.
7. The lubricant composition according to claim 1 , comprising from 20 to 90% of polyalkylene glycol base oil (i).
8. The lubricant composition according to claim 1 comprising at least one salicylate as a detergent (b).
9. The lubricant composition according to claim 1 free of any detergent of the sulfonate type.
10. The lubricant composition according to claim 1 further comprising:
(c) at least one dithiocarbamate as an anti-wear additive.
11. The lubricant composition according to claim 1 free of anti-wear additive of the dithiophosphate type.
12. The lubricant composition according to claim 1 , further comprising an amine antioxidant and/or a phenol antioxidant.
13. The lubricant composition according to claim 1 which is motor oil.
14. A method of using at least one additive for engine oil, the method comprising:
providing the engine oil comprising an additive selected from salicylates, phenates, dithiocarbamates, amine or phenol antioxidants, for reducing the Noack volatility as measured according to a CEC L 40-93 standard, and a single base oil consisting of (a) base oils of a polyalkylene glycol type obtained by reacting at least one alcohol comprising from 8 to 20 carbon atoms and a mixture of butylene oxide and propylene oxide, the mixture having a mass ratio of butylene oxide over propylene oxide comprised between 3:1 and 1:3, said polyalkylene glycol base oil having a molar mass measured according to the ASTM D2502 standard comprised between 300 and 1,000 grams per mole, and a kinematic viscosity at 100° C. measured according to the ASTM D445 standard comprised between 1 and 12 cSt; (b) at least one oil of API group classification III; and (c) optionally at least one oil of API group classification I, II, or IV, wherein the engine oil is devoid of a polyalkylene glycol obtained or partly obtained from ethylene oxide, and
lubricating an engine with the engine oil including the additive.