Antifouling paint composition and antifouling paint
View Patent ↗Disclosed here is a method for producing an antifouling paint composition using metal-containing polymer particles, an organic solvent and acrylic polymer (P) that is soluble in the organic solvent. According to the method, an antifouling paint composition is obtained, which is useful for producing a high-solid antifouling paint having excellent storage stability along with a shorter drying time because of capillary action among the polymer particles.
1. An antifouling paint composition, comprising:
metal-containing polymer particles that are present as particles in the antifouling paint composition;
an organic solvent; and
an acrylic polymer that is dissolved in the organic solvent with no agglomeration and that is obtained by polymerizing a monomer mixture which comprises 50% by mass or more of (meth)acrylic monomer.
2. The antifouling paint composition according to claim 1 , wherein the metal-containing polymer particles comprise a divalent or higher-valent metal ester structure.
3. The antifouling paint composition according to claim 1 , wherein the metal-containing polymer particles are such polymer particles that are produced by polymerizing an ethylenically unsaturated monomer mixture comprising: (a1) 8 to 65% by mass of divalent or higher-valent metal-containing ethylenically unsaturated monomer; (a2) 0.5 to 8% by mass of carboxyl group-containing ethylenically unsaturated monomer; and (a3) 27 to 91.5% by mass of other ethylenically unsaturated monomer.
4. The antifouling paint composition according to claim 1 , wherein the mass ratio of the metal-containing polymer particles to the acrylic polymer is in a range of 10/90 to 70/30.
5. The antifouling paint composition according to claim 1 , wherein the acrylic polymer comprises a divalent metal ester structure.
6. The antifouling paint composition according to claim 5 , wherein the acrylic polymer is obtained by polymerizing an ethylenically unsaturated monomer mixture that comprises a divalent metal-containing ethylenically unsaturated monomer.
7. An antifouling paint comprising the antifouling paint composition according to claim 1 .
8. The antifouling paint composition according to claim 3 , wherein a content of the divalent or higher-valent metal-containing ethylenically unsaturated monomer in the ethylenically unsaturated monomer mixture is from 15 to 55% by mass.
9. The antifouling paint composition according to claim 3 , wherein a content of the carboxyl group-containing ethylenically unsaturated monomer in the ethylenically unsaturated monomer mixture is from 2 to 4% by mass.
10. The antifouling paint composition according to claim 3 , wherein a content of the other ethylenically unsaturated monomer in the ethylenically unsaturated monomer mixture is from 41 to 83% by mass.
11. The antifouling paint composition according to claim 1 , wherein the metal-containing polymer particles are zinc salts of acid group-containing acrylic copolymers.
12. The antifouling paint composition according to claim 1 , wherein the organic solvent includes a hydrocarbon, an ether, an ester, a ketone, or an alcohol.
13. The antifouling paint composition according to claim 1 , wherein the mass ratio of the acrylic polymer to the organic solvent is in a range of 30/70 to 80/20.
14. The antifouling paint composition according to claim 1 , wherein the mass ratio of the acrylic polymer to the organic solvent is in a range of 40/60 to 70/30.