Organic electroluminescent element
View Patent ↗Provided is an organic electroluminescent device (organic EL device) which exhibits improved luminous efficiency, ensures sufficient driving stability, and has a simple configuration. The organic electroluminescent element includes an anode, a plurality of organic layers, and a cathode laminated on a substrate, and contains a carbazole compound represented by the general formula (1) in at least one layer selected from the group consisting of a emitting layer, a hole-transporting layer, and an electron-blocking layer. In general formula (1), L represents an m-valent aromatic hydrocarbon group or aromatic heterocyclic group, R's each represent hydrogen, an alkyl group, or a cycloalkyl group, m represents an integer of 1 to 3, and n's each represent an integer of 1 to 4, provided that at least one n represents an integer of 2 to 4, and at least one specific structure represented by the formula (1a) is present in the formula.
1. An organic electroluminescent device, comprising an anode, a plurality of organic layers, and a cathode laminated on a substrate, wherein the organic electroluminescent device contains a carbazole compound represented by the general formula (1) in at least one layer selected from the group consisting of a emitting layer, a hole-transporting layer, and an electron-blocking layer:
where L represents an m-valent aromatic hydrocarbon group having 6 to 30 carbon atoms in total or aromatic heterocyclic group having 3 to 30 carbon atoms in total, but does not represent a carbazole ring-containing group, R's each independently represent hydrogen, an alkyl group having 1to 10carbon atoms, or a cycloalkyl group having, 3 to 11 carbon atoms, in represents an integer of 1 to 3, and n's each independently represent an integer of 1 to 4, provided that at least one n represents an integer of 2 to 4, and at least one specific structure represented by the formula (1 a ) is present in the formula;
where R's each have the same meaning as that in the general formula (1).
2. An organic electroluminescent device according to claim 1 , wherein in the general formula (1), m represents art integer of 1 or 2, n's each independently represent an integer of 1 to 3, and at least one n represents an integer of 2 or 3.
3. An organic electroluminescent device according to claim 2 , wherein in the general formula (1) all specific structures between carbazole rings comprise specific structures represented by the formula (1 a ) or by the formula (1 a ) and the following formula (1 b ):
where R's each have the same meaning as that in the formula (1 a ).
4. An organic electroluminescent device according to claim 1 , wherein in the general formula (1), L represents an m-valent group produced by removing m hydrogen atoms from any one of the formulae (2) to (5):
in the formulae (2) to (5), X's each independently represent CH or nitrogen and R's each independently represent hydrogen, an alkyl group having 1 to 10 carbon atoms, or a cycloalkyl group having 3 to 11 carbon atoms, in each of the formulae (3) and (5), Y represents oxygen or sulfur, and in the formula (4), p represents an integer of 0 to 2.
5. An organic electroluminescent device according to claim 4 , wherein in the general formula (1), L represents an m-valent group produced by removing m hydrogen atoms from any one of the formulae (2) to (4).
6. An organic electroluminescent device according to claim 1 , wherein in the general formula (1), a sum of n's is an integer of 2 to 6.
7. An organic electroluminescent device according to claim 1 , wherein the organic layer containing the carbazole compound is an emitting layer containing a phosphorescent light-emitting dopant.
8. An organic electroluminescent device according to claim 3 , wherein the organic layer containing the carbazole compound is an emitting layer containing a phosphorescent light-emitting dopant.
9. An organic electroluminescent device according to claim 4 , wherein the organic layer containing the carbazole compound is an emitting layer containing a phosphorescent light-emitting dopant.