Elastomer formulations
View Patent ↗This present invention relates to carbon nanotubes as fillers in composites with materials such as elastomers, thermosets and thermoplastics. A further feature of this invention relates to the development of a concentrate of carbon nanotubes with an elastomer wherein the concentrate can be further diluted with an elastomer and other polymers and fillers using conventional melt mixing.
1. A composition comprising a cured elastomer containing discrete carbon nanotubes, wherein the discrete carbon nanotubes have an aspect ratio of 10 or more, are double wall or multiwall, are present in the range of 0.1 to 30% by weight based on the total weight, and are functionalized.
2. A composition according to claim 1 , wherein the cured elastomer is cured by free radical or ionization agents.
3. A composition according to claim 2 , wherein the cured elastomer is vulcanized during fabrication and/or form fixing.
4. An article made from a composition according to claim 1 .
5. An article according to claim 4 , which is selected from a fire, a gum chafer, a tire sidewall, a tire tread or casing, a hose, a belt, a seal, an automotive anti-vibration part, a windshield wiper blade, and a tank track pad, wheel, bushings or backer plate components.
6. An article according to claim 5 , which is a tire for off-road and passenger car applications, which tire contains rubber and reinforcing fillers including carbon black and/or silica.
7. A method for adjusting the wear resistance, the strength and/or the stiffness of elastomeric articles comprising providing a composition according to claim 1 .
8. A method for adjusting the wear resistance, the strength and/or the stiffness of a tire or part thereof including a gum chafer, a tire sidewall, a tire tread or casing, the method comprising providing a composition according to claim 1 .
9. The method according to claim 8 , wherein the tire tread has a concentration of discrete carbon nanotubes in the range of 0.7 vol. % and 30 vol. % and a concentration of reinforcing filler in the range of 0 to 30 vol. %.
10. The composition of claim 1 wherein the discrete carbon nanotubes are functionalized on the nanotube ends, sidewalls, or both.
11. The composition of claim 1 wherein the discrete carbon nanotubes are functionalized via covalent bonding, ionic bonding, chemisorption, intercalation, surfactant interactions, polymer wrapping, cutting, solvation, or a combination thereof.
12. The composition of claim 1 wherein the discrete carbon nanotubes are functionalized before being separated.
13. The composition of claim 1 wherein the discrete carbon nanotubes are functionalized during separation.
14. The composition of claim 1 wherein the discrete carbon nanotubes are functionalized after being separated.