Positive electrode for non-aqueous electrolyte secondary battery, non-aqueous electrolyte secondary battery and battery module
View Patent ↗The present invention provides a positive electrode for a non-aqueous electrolyte secondary battery in which the charge/discharge rate of a secondary battery is increased by increasing the discharge/discharge rate of the positive electrode as a result of increasing the rate of incorporation and release of lithium ions in olivine-type phosphorous complex compound particles, a non-aqueous electrolyte secondary battery provided with this positive electrode for a non-aqueous electrolyte secondary battery, and a battery module provided with this non-aqueous electrolyte secondary battery. The positive electrode for a non-aqueous electrolyte secondary battery of the present invention is a positive electrode for a non-aqueous electrolyte secondary battery containing olivine-type lithium complex compound particles having a carbonaceous film formed on the surface thereof as a positive electrode active material, in which the coverage factor of the carbonaceous film relative to the surface area of the olivine-type lithium complex compound particles is preferably 95% or more, and the packed density of the olivine-type lithium complex compound particles in this positive electrode for a non-aqueous electrolyte secondary battery is preferably 0.90 g/cm 3 to 1.09 g/cm 3 .
1. A positive electrode for a non-aqueous electrolyte secondary battery containing a positive electrode active material layer, wherein the positive electrode active material layer comprises a binder, a conductive material, and olivine-type lithium complex compound particles, wherein:
a carbonaceous film is formed on the surface of the particles,
the coverage factor of the carbonaceous film relative to the surface area of the olivine-type lithium complex compound particles is 95% or more, and the coverage factor is measured after a uniform mixture of the binder, the conductive material and the olivine-type lithium complex compound particles is prepared to form the positive electrode active material layer,
the carbonaceous film consists of amorphous carbon, and
the packed density of the olivine-type lithium complex compound particles in the layer is 0.90 g/cm 3 to 1.09 g/cm 3 , wherein the packed density is a value obtained by the following formula:
packed density of olivine-type lithium complex compound particles in the layer =(weight of the olivine-type lithium complex compound particles in the layer) / (volume of the layer).
2. A non-aqueous electrolyte secondary battery provided with the positive electrode for a non-aqueous electrolyte secondary battery according to claim 1 .
3. A battery module provided with the non-aqueous electrolyte secondary battery according to claim 2 .
4. A non-aqueous electrolyte secondary battery that uses a positive electrode containing a carbon-coated, olivine-type lithium complex compound as a positive electrode active material, wherein the positive electrode has a positive electrode active material layer containing 4 parts by weight to 6 parts by weight of a conductive material and 4 parts by weight to 8 parts by weight of a binder based on 100 parts by weight of the positive electrode active material, and the carbon coverage area ratio of the carbon-coated, olivine-type complex compound particles is 95% or more, and wherein the coverage area is measured after a uniform mixture of the binder, the conductive material and the olivine-type lithium complex compound particles is prepared to form the positive electrode active material layer;
the packed density of the olivine-type lithium complex compound particles in the layer is 0.90 g/cm 3 to 1.09 g/cm 3 , wherein the packed density is a value obtained by the following formula:
packed density of olivine-type lithium complex compound particles in the layer =(weight of the olivine-type lithium complex compound particles in the layer) / (volume of the layer).
5. A battery module comprising connecting a plurality of the non-aqueous electrolyte secondary batteries according to claim 4 .
6. A battery module provided with the non-aqueous electrolyte secondary battery according to claim 2 .
7. A battery module comprising a plurality of the non-aqueous electrolyte secondary batteries according to claim 2 .
8. The positive electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the coverage factor is measured with a scanning electron microscope or energy-dispersive X-ray spectroscopy using observation samples, wherein the observation samples are obtained by:
immersing a portion of the positive electrode active material layer in a solvent to dissolve the binder and separate particles of the positive electrode active material as the observation samples, or
removing a portion of the positive electrode active material layer to extract particles of the positive electrode active material as the observation samples.