Sealant composition, method for preventing liquid crystal contamination, liquid crystal panel and display device
Disclosed is a sealant composition, a liquid crystal device and a method for preventing liquid crystal contamination using the sealant composition. The sealant composition consists of 20-30 parts by weight of an ultraviolet polymerizable double bond monomer, 15-20 parts by weight of a heat polymerization monomer, 5-20 parts by weight of a polymerizable oligomer, 0.1-5 parts by weight of a photoinitiator, 10-20 parts by weight of a heat curing agent and 0-20 parts by weight of a particulate additive, wherein said polymerizable oligomer is poly(ethylene glycol) diacrylate or derivatives thereof. Through the reaction between the polymerizable oligomers and the polymer of the ultraviolet polymerizable double bond monomers to generate a reticular high molecular polymer, the anchoring effect of the polymer on the surrounding unreacted heat polymerization monomers is effectively enhanced, thereby reducing the contamination of the crystal liquid by the sealant.
1. A sealant composition consisting of the following components:
an ultraviolet polymerizable double bond monomer, 20-30 parts by weight;
a heat polymerization monomer, 15-20 parts by weight;
a polymerizable oligomer, 5-20 parts by weight;
a photoinitiator, 0.1-5 parts by weight;
a heat curing agent, 10-20 parts by weight; and
a particulate additive, 0-20 parts by weight;
wherein said polymerizable oligomer is poly(ethylene glycol) diacrylate or derivatives thereof;
said photoinitiator is dibenzoyl peroxide, lauroyl peroxide, azobisisobutyronitrile, azobisisoheptonitrile, diisopropyl peroxydicarbonate or dicyclohexyl peroxydicarbonate.
2. The sealant composition according to claim 1 , wherein said poly(ethylene glycol) diacrylate or derivatives thereof has a weight-average molecular weight of 200-3000.
3. The sealant composition according to claim 2 , wherein said poly(ethylene glycol) diacrylate or derivatives thereof has a weight-average molecular weight of 200-1000.
4. The sealant composition according to claim 1 , wherein said ultraviolet polymerizable double bond monomer is an acrylate;
said heat polymerization monomer is heat polymerizable monomer with epoxy group;
said heat curing agent is amino curing agent; and
said particulate additive is a silicon dioxide particle.
5. The sealant composition according to claim 4 , wherein said heat polymerizable monomer with epoxy group is ethylene glycol diglycidyl ether; and
said amino curing agent is 1,8-diamino-3,6-dioxaoctane.
6. The sealant composition according to claim 4 , wherein the acrylate is methyl acrylate, methyl methacrylate, ethyl acrylate, propyl acrylate or butyl acrylate.
7. A liquid crystal panel which employs the sealant composition according to claim 1 for sealing.
8. A display device which comprises the liquid crystal panel according to claim 7 .
9. A method for preventing liquid crystal contamination using a sealant composition comprising the steps of:
a) mixing the sealant composition according to claim 1 and subjecting it to defoaming under protection from light;
b) coating the mixture obtained in step a) onto a colored film substrate and/or an array substrate, and then filling the colored film substrate and the array substrate with liquid crystal and aligning the colored film substrate and the array substrate to obtain a liquid crystal display panel;
c) irradiating the liquid crystal display panel with ultraviolet light so that the polymerizable oligomer and the polymer of the ultraviolet polymerizable double bond monomer in the sealant are polymerized; and
d) heating the liquid crystal display panel obtained in step c) so that the heat polymerization monomer in the sealant is polymerized.
10. The method according to claim 9 , wherein in the step a), the defoaming under protection from light lasts 1-5 hours.
11. The method according to claim 9 , wherein in the step c), the wavelength of the ultraviolet light is 350-380 nm, the duration of the ultraviolet light irradiation is 1-60 minute, and the intensity of the ultraviolet light irradiation is 0.1-100 mW/cm 2 .
12. The method according to claim 9 , wherein in the step d), the temperature of the heat polymerization is 50-150° C., and the reaction duration is 0.5-5 hours.