Rubber composition including a functionalized thermoplastic polymer
View Patent ↗The present invention relates to a diene rubber composition reinforced with an inorganic filler comprising a thermoplastic polymer bearing, at at least one end, a silanol or silyl ether functional group. The presence of the functional thermoplastic polymer makes it possible to improve the compromise of performances, which are the handling and the grip, of a tire having a tread that is based on such a composition.
1. A reinforced rubber composition based on at least:
a diene elastomer,
a non-reinforcing filler comprising from 3 to 30 phr of a thermoplastic polymer,
a reinforcing filler comprising a reinforcing inorganic filler,
a coupling agent providing the bond between the diene elastomer and the reinforcing inorganic filler,
wherein the thermoplastic polymer has a number-average molar mass, Mn, between 500 g/mol and 20000 g/mol, contains exclusively vinylaromatic units, and bears, at least one chain end, a specific functional group selected from the group consisting of Si(OR 1 ) n R 2 ( 3-n ), Si(OH)R 1 2 or (SiR 1 2 —O) p —H, where:
R 1 , which are identical or different, each represent a monovalent hydrocarbon-based group selected from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms,
R 2 , which are identical or different, each represent a hydrogen or a monovalent hydrocarbon-based group selected from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms, the hydrocarbon-based group optionally bearing at least one functional group selected from a primary, secondary or tertiary amine, an imine and an epoxy,
n represents an integer ranging from 1 to 3,
p represents an integer ranging from 2 to 30.
2. The reinforced rubber composition according to claim 1 , wherein the number-average molar mass of the thermoplastic polymer varies from 1500 g/mol to 10000 g/mol.
3. The reinforced rubber composition according to claim 2 , wherein the number-average molar mass of the thermoplastic polymer varies from 2000 g/mol to 7000 g/mol.
4. The reinforced rubber composition according to claim 1 , wherein the thermoplastic polymer is present in a proportion ranging from 5 to 20 phr.
5. The reinforced rubber composition according to claim 1 , wherein the vinylaromatic units are derived from styrene, a styrene derivative, or a mixture thereof.
6. The reinforced rubber composition according to claim 5 , wherein the styrene derivative is a para-, ortho- or meta-substituted alkylstyrene.
7. The reinforced rubber composition according to claim 1 , wherein the thermoplastic polymer has, at at least one chain end, an SiR 2 OH functional group, where R is a C 1 -C 4 alkyl.
8. The reinforced rubber composition according to claim 1 , wherein the reinforcing filler predominantly comprises a reinforcing inorganic filler.
9. The reinforced rubber composition according to claim 8 , wherein the reinforcing inorganic filler is a silica.
10. The reinforced rubber composition according to claim 1 , wherein the diene elastomer is selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and blends of these elastomers.
11. A tire comprising at least one tread comprising a reinforced rubber composition according to claim 1 .
12. The reinforced rubber composition according to claim 1 , wherein the thermoplastic polymer is present in a proportion ranging from 8 to 15 phr.
13. The reinforced rubber composition according to claim 7 , wherein R is methyl.
14. A semi-finished rubber product comprising a reinforced rubber composition according to claim 1 .
15. The semi-finished rubber product according to claim 14 , which is a tire tread.