Polymerizable compound-containing liquid crystal composition and liquid crystal display device using the same
A polymerizable compound-containing liquid crystal composition of the present invention relates to a liquid crystal composition containing a polymerizable compound represented by general formula (I) and a compound represented by general formula (II) and can be used for a liquid crystal display device imparted with liquid crystal aligning ability by polymerization. The polymerizable liquid crystal composition is required to cause no precipitation in a wide temperature range and have a low viscosity corresponding to fast switching, and a liquid crystal display device using the composition is required to have more stable alignment after polymerization and to cause no defect in display characteristics. In the present invention, the problems can be solved using a specified compound.
1. A polymerizable compound-containing liquid crystal composition comprising, as a first component, at least one polymerizable compound represented by general formula (I-1),
in the general formula (I-1), R 1 and R 2 each independently represent any of formulae (R-1) to (R-15) below,
and, as a second component, at least one compound represented by general formula (II-A) and at least one compound represented general formula (II-B),
in the general formulae (II-A) and (II-B) R 5 , R 6 , R 7 and R 8 , respectively, represents an alkyl group having 1 to 10 carbon atoms or an alkenyl group having 2 to 10 carbon atoms, wherein at least one hydrogen atom present in the group may be substituted by a fluorine atom.
2. The polymerizable compound-containing liquid crystal composition according to claim 1 , wherein the polymerizable compound represented by general formula (I-1) is the first component.
3. The polymerizable compound-containing liquid crystal composition according to claim 1 , wherein in the general formula (I-1) to the general formula (I-4), R 1 and R 2 are each independently formula (R-1) or (R-2).
4. The polymerizable compound-containing liquid crystal composition according to claim 1 , wherein in the general formula (I-1) to the general formula (I-4), R 1 and R 2 are each formula (R-2).
5. The polymerizable compound-containing liquid crystal composition according to claim 1 , comprising, as a third component, at least one compound represented by general formula (III),
in the formula, R 9 represents alkyl group having 1 to 10 carbon atoms or an alkenyl group having 2 to 10 carbon atoms, wherein at least one hydrogen atom present in the group may be substituted by a fluorine atom, and R 10 represents alkyl group or alkoxyl group having 1 to 10 carbon atoms or an alkenyl group or alkenyloxy group having 2 to 10 carbon atoms, wherein at least one hydrogen atom present in the group may be substituted by a fluorine atom.
6. The polymerizable compound-containing liquid crystal composition according to claim 5 , wherein the general formula (III) is general formula (III-A),
in the formula, R 11 and R 12 each independently alkyl group having 1 to 10 carbon atoms or an alkenyl group having 2 to 10 carbon atoms, wherein at least one hydrogen atom present in the group may be substituted by a fluorine atom.
7. The polymerizable compound-containing liquid crystal composition according claim 1 , comprising at least one compound represented by general formula (IV-1) to general formula (IV-7),
in the formulae (IV-1) through (IV-7), R 3 represents alkyl group having 1 to 10 carbon atoms or an alkenyl group having 2 to 10 carbon atoms, wherein at least one hydrogen atom present in the group may be substituted by a fluorine atom, and R 4 represents alkyl group or alkoxyl group having 1 to 10 carbon atoms or an alkenyl group or alkenyloxy group having 2 to 10 carbon atoms, wherein at least one hydrogen atom present in the group may be substituted by a fluorine atom.
8. The polymerizable compound-containing liquid crystal composition according to claim 1 , wherein the content of the compound represented by the general formula (I-1) to the general formula (I-4) is 0.01% by mass to 2.0% by mass.
9. The polymerizable compound-containing liquid crystal composition according claim 1 , wherein the content of the compound represented by the general formula (II) is 5% by mass to 35% by mass.
10. The polymerizable compound-containing liquid crystal composition according to claim 1 , wherein the content of the compound represented by the general formula (III) is 5% by mass to 35% by mass.
11. The polymerizable compound-containing liquid crystal composition according to claim 1 , comprising the polymerizable compound represented by the general formula (I-1);
and compounds represented by general formulae (II-A) and (II-B) as follows,
in the general formulae (II-A) and (II-B), R 5 , R 6 , R 7 , and R 8 each independently alkyl group having 1 to 10 carbon atoms or an alkenyl group having 2 to 10 carbon atoms, wherein at least one hydrogen atom present in the group may be substituted by a fluorine atom;
and general formula (III-A) as follows,
in the general formula (III-A), R 11 and R 12 each independently alkyl group having 1 to 10 carbon atoms or an alkenyl group having 2 to 10 carbon atoms, wherein at least one hydrogen atom present in the group may be substituted by a fluorine atom.
12. The polymerizable compound-containing liquid crystal composition according to claim 1 , wherein a dielectric constant anisotropy Δ∈ at 25° C. is in a range of −6.0 to −2.0, a refractive index anisotropy Δn at 25° C. is in a range of 0.08 to 0.13, a viscosity (η) at 20° C. is in a range of 10 to 30 mPa·s, and a nematic-isotropic liquid phase transition temperature (T ni ) is in a range of 60° C. to 120° C.
13. A liquid crystal display device comprising the polymerizable compound-containing liquid crystal composition according to claim 1 .
14. The liquid crystal display device according to claim 13 , wherein the liquid crystal display device is an active matrix drive liquid crystal device.
15. The liquid crystal display device according to claim 13 , wherein the liquid crystal display device is of a PSA mode, a PSVA mode, a VA mode, an IPS mode, or an ECB mode.
16. The liquid crystal display device according to claim 13 , wherein a pretilt angle is 85 to 89.9 degrees.