Microporous film, methods for making such film, and use for such film as battery separator film
View Patent ↗A microporous membrane includes a low melting polypropylene, the low melting polypropylene being a polypropylene homopolymer or copolymer having an MFR≧2.0×10 2 , a Tm of 85.0° C. to 130.0° C., and a Te-Tm≦10° C.
1. A microporous membrane comprising a low melting polypropylene, wherein the low melting polypropylene is (i) a polypropylene homopolymer having a number average molecular weight (Mn) of 1.0×10 4 to 5.0×10 4 , a molecular weight distribution (MWD, defined Mw/Mn, where Mn is the number average molecular weight and Mw is weight average molecular weight) of 1.5 to 5.0, a melt flow rate (MFR)≧2.0×10 2 , a peak melting point (Tm) of 85.0° C. to 130.0° C., and a difference between melting end point (Te) and Tm (Te-Tm)≦10° C. and/or (ii) a propylene copolymer of propylene and ≦10.0 mol. % of one or more α-olefin comonomers, having a Mn of 1.0×10 4 to 5.0×10 4 , a MWD of 1.8 to 3.5, a MFR≧2.0×10 2 , a Tm of 85.0° C. to 130.0° C., and a Te-Tm≦10° C.
2. The microporous membrane of claim 1 , wherein the membrane has a normalized air permeability ≦7.5×10 2 seconds/100 cm 3 /20 μm and a shutdown temperature ≦130.5° C.
3. The microporous membrane according to claim 1 , wherein the membrane comprises from 5.0 to 30.0 wt % of the low melting polypropylene, based on the weight of the membrane.
4. The microporous membrane according to claim 1 , wherein the membrane further optionally comprises one or more of a first polyethylene having a Tm≧131.0° C. and a Mn of 1.0×10 5 to 9.0×10 5 , and a second polyethylene having a Mn>1.0×10 6 .
5. The microporous membrane according to claim 1 , wherein the low melting polypropylene is a propylene copolymer of propylene and ≦3.0 mol. % to 15.0 mol. % comonomer selected from a group comprising ethylene and C 4 -C 12 α-olefins.
6. The microporous membrane according to claim 5 , where in the C 4 -C 12 α-olefin is hexene and/or octene.
7. The microporous membrane according to claim 1 , wherein the Tm of the propylene copolymer is 100.0° C. to 126.0° C., and the Te-Tm of the propylene copolymer is 2.0° C. to 4.0° C.
8. The microporous membrane according to claim 1 , wherein the membrane further comprises one or more of a first polyethylene having a Tm≧131.0° C. and a Mn of 1.0×10 5 to 9.0×10 5 , and a second polyethylene having a Mn>1.0×10 6 , wherein the amount of combined first and second polyethylene in the membrane is in the range of 70 wt. % to 95 wt. %, based on the weight of the membrane.